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CaCl_(2)-DTPA法提取土壤有效态砷的条件优化
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作者 王雨 宋庆瑞 《粮食加工》 2022年第6期63-67,共5页
CaCl_(2)-DTPA提取法是目前已用较多的土壤有效态元素的浸提方法,通常适用于中性、酸性和石灰性土壤中有效锌、铁、铜、锰、镉和汞等元素的提取,而对有效态砷的提取方法则鲜有企及。本实验采用原子荧光法测定农用地土壤有效态砷,对土液... CaCl_(2)-DTPA提取法是目前已用较多的土壤有效态元素的浸提方法,通常适用于中性、酸性和石灰性土壤中有效锌、铁、铜、锰、镉和汞等元素的提取,而对有效态砷的提取方法则鲜有企及。本实验采用原子荧光法测定农用地土壤有效态砷,对土液比、振荡时间、振荡速度进行了正交实验设计,以找出CaCl_(2)-DTPA提取剂测定土壤有效砷的最优提取条件。试验结果表明:CaCl_(2)-DTPA作为土壤有效砷的提取剂时,最优的提取条件为土液比1:10,振荡时间90 min,振荡速度200 r/min。 展开更多
关键词 土壤 有效态砷 cacl_(2)-DPTA 提取条件
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Chemical forms of cobalt and nickel extracted by M1,M3 and CaCl_(2)-DTPA
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作者 Wen Bei Qian Jin +1 位作者 Chen Bin Shan Xiaoquan 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 1997年第2期47-57,共11页
Mehlich 1(M1), mehlich 3(M3) and CaCl 2 DTPA have been used to predict the available micronutrient in soil. However, the forms of micronutrient extractable by these extractants are not known. In the present study, t... Mehlich 1(M1), mehlich 3(M3) and CaCl 2 DTPA have been used to predict the available micronutrient in soil. However, the forms of micronutrient extractable by these extractants are not known. In the present study, ten soils, collected from five provinces and the capital of China, representing a wide range of chemical and physical properties, were analyzed by sequential extraction to isolate five forms of cobalt and nickel, they are exchangeable, carbonate bound, Fe Mn oxide bound, organically bound and residual forms. The chemical forms extracted by M1, M3 and CaCl 2 DTPA were also investigated. The results show strong correlation between the carbonate bound or organically bound forms of Co or Ni and the amounts of extractable by any of the above three extractants. The main forms extracted by these extractants are carbonate and organically bound forms. The ranking of these three extractants for extraction of Co and Ni are M1>M3=CaCl 2 DTPA and M1=M3>CaCl 2 DTPA, respectively. 展开更多
关键词 M1 M3 cacl 2 dtpa sequential extraction cobalt and nickel.
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AB-DTPA法对上海典型土壤元素有效态含量测定的适用性分析 被引量:5
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作者 孙鸣镝 郝冠军 方海兰 《上海农业学报》 CSCD 2015年第5期47-50,共4页
采用AB-DTPA浸提剂联合电感耦合等离子体发射光谱法测定了上海地区48个典型土壤样品中8种元素的有效态含量,并与经典的土壤测定方法进行比较。结果显示:AB-DTPA法能提取出土壤中大部分有效磷和速效钾,提取率分别为93.0%和98.4%,与经典... 采用AB-DTPA浸提剂联合电感耦合等离子体发射光谱法测定了上海地区48个典型土壤样品中8种元素的有效态含量,并与经典的土壤测定方法进行比较。结果显示:AB-DTPA法能提取出土壤中大部分有效磷和速效钾,提取率分别为93.0%和98.4%,与经典测定方法达到了极显著相关,相关系数分别为0.917和0.981;无论是土壤营养元素还是污染重金属,AB-DTPA法测定的有效态含量均高于CaCl_2-DTPA法;其中AB-DTPA法测定的Fe、Mn、Cu、Zn、Cd等5种元素的有效态含量与CaCl_2-DTPA法均达到极显著相关;AB-DTPA法提取的有效Pb与CaCl_2-DTPA法测定结果也达到了显著相关,但相关系数只有0.325。总体而言,AB-DTPA法适用于上海典型土壤中多种元素的有效态含量分析,但除P、K外,其他元素的评价指标应相应提高。 展开更多
关键词 AB-dtpa 经典方法 cacl2-dtpa 上海典型土壤 有效态含量
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