Herein,a series of carbazolyl cyanobenzene(CCB)-based organic photocatalysts with a broad range of photoredox capabilities were designed and synthesized,allowing precise control of the photocatalytic reactivity for th...Herein,a series of carbazolyl cyanobenzene(CCB)-based organic photocatalysts with a broad range of photoredox capabilities were designed and synthesized,allowing precise control of the photocatalytic reactivity for the controllable reduction of aryl halides via a metal-free process.The screened-out CCB(5CzBN),a metal-free,low-cost,scalable and sustainable photocatalyst with both strong oxidative and reductive ability,exhibits superior performance for both dehalogenation and C—C bond-forming arylation reactions.展开更多
Organic electrochemistry has a rich history in organic synthesis and has been considered as a promising alternative to traditional chemical oxidants and reductants because it obviates the use of stoichiometric amount ...Organic electrochemistry has a rich history in organic synthesis and has been considered as a promising alternative to traditional chemical oxidants and reductants because it obviates the use of stoichiometric amount of dangerous and toxic reagents. In particular, the electrochemical C-H bonds functionalization is one of the most desirable approaches for the construction of carbon-carbon （C-C） and carbon-heteroatom （C-X） bonds. This review summarizes the substantial progress made in the last few years in C-H functionalization via organic electrochemistry. It is divided into sections on C-C, C-N, C-O, C-S, C-Halogen and C-P bond formation.展开更多
Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the ...Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the construction new C—P bond has therefore gained great interests in synthetic organic chemistry. Because of their intrinsic sustainability and green chemistry character, visible light-induced photoredox catalysis has been widely applied in the construction of new chemical bonds, including the formation of C—P bond. In this review, we summarized recent achievements in C—P bond formation reactions initiated by visible light-induced photoredox catalysis, which mainly focusing on the discussion of reaction design and the mechanism.展开更多
基金the National Natural Scie nce Foundation of China(No.21972094)Guangdong Special Support Program+2 种基金Pengcheng Scholar programShenzhen Peacock Plan(Nos.KQJSCX20170727100802505,KQTD2016053112042971)the Educational Commission of Guangdong Province(No.2016KTSCX126)。
文摘Herein,a series of carbazolyl cyanobenzene(CCB)-based organic photocatalysts with a broad range of photoredox capabilities were designed and synthesized,allowing precise control of the photocatalytic reactivity for the controllable reduction of aryl halides via a metal-free process.The screened-out CCB(5CzBN),a metal-free,low-cost,scalable and sustainable photocatalyst with both strong oxidative and reductive ability,exhibits superior performance for both dehalogenation and C—C bond-forming arylation reactions.
文摘Organic electrochemistry has a rich history in organic synthesis and has been considered as a promising alternative to traditional chemical oxidants and reductants because it obviates the use of stoichiometric amount of dangerous and toxic reagents. In particular, the electrochemical C-H bonds functionalization is one of the most desirable approaches for the construction of carbon-carbon （C-C） and carbon-heteroatom （C-X） bonds. This review summarizes the substantial progress made in the last few years in C-H functionalization via organic electrochemistry. It is divided into sections on C-C, C-N, C-O, C-S, C-Halogen and C-P bond formation.
基金supported by the National Natural Science Foundation of China(21702001)Open fund for Institute of Physical Science and Information Technology,Anhui University and the Start-up Grant from Anhui University
文摘Organophosphorus compounds have attracted continuous attention in materials science, agrochemical and pharmaceutical fields due to their unique bioactivities. Thus, the development of novel and robust manners for the construction new C—P bond has therefore gained great interests in synthetic organic chemistry. Because of their intrinsic sustainability and green chemistry character, visible light-induced photoredox catalysis has been widely applied in the construction of new chemical bonds, including the formation of C—P bond. In this review, we summarized recent achievements in C—P bond formation reactions initiated by visible light-induced photoredox catalysis, which mainly focusing on the discussion of reaction design and the mechanism.
