通过扫描电镜/能谱、X射线衍射以及金相分析,针对含0.3%Fe(质量分数)的Al Mg Si Cu铝合金,研究了Mn含量对其结晶相的影响。研究表明:合金在铸造过程中形成的结晶相为Al1.9CuMg4.1Si3.3,Al5(FeMn)Si,Al8(FeMn)2Si以及少量的Mg2Si;增大含M...通过扫描电镜/能谱、X射线衍射以及金相分析,针对含0.3%Fe(质量分数)的Al Mg Si Cu铝合金,研究了Mn含量对其结晶相的影响。研究表明:合金在铸造过程中形成的结晶相为Al1.9CuMg4.1Si3.3,Al5(FeMn)Si,Al8(FeMn)2Si以及少量的Mg2Si;增大含Mn量,合金中AlFeMnSi型结晶相数量增多;对合金进行均匀化处理时,Al1.9CuMg4.1Si3.3相完全溶解,发生Al5(FeMn)Si向Al8(FeMn)2Si相的转变;对合金进行轧制及最终热处理后,结晶相碎化且沿轧向呈纤维状分布,但结晶相的类型不变。展开更多
The effects of Sm additions （0, 0.5 wt.%, 1.0 wt.%and 1.5 wt.%） on the eutectic Si and β-Al5FeSi phases of ADC12 as-cast alloys were studied by optical microscopy （OM）, scanning electron microscopy （SEM） and di...The effects of Sm additions （0, 0.5 wt.%, 1.0 wt.%and 1.5 wt.%） on the eutectic Si and β-Al5FeSi phases of ADC12 as-cast alloys were studied by optical microscopy （OM）, scanning electron microscopy （SEM） and differential thermal analysis （DTA）. The experimental results showed that Sm was an effective modifying agent for the eutectic Si of ADC12 alloy, when 1.0 wt.%-1.5 wt.%Sm was added to the alloy, the coarse acicular eutectic Si was modified into fine particle or short rod structure. Moreover, the appropriate addition of Sm （about 1.0 wt.%） had marked effects on shortening the length of needle-likeβ-Al5FeSi phase. Whereas, Sm was less effective on modifying the needle-likeβ-iron to the Chinese script or sphericalα-iron phase. The modification mecha-nism was also discussed.展开更多
Ytterbium aluminum garnet(Yb3Al5O12)is considered as a promising thermal barrier material.However,the main limitations of Yb3Al5O12 for thermal barrier applications are relative low thermal expansion coefficient and h...Ytterbium aluminum garnet(Yb3Al5O12)is considered as a promising thermal barrier material.However,the main limitations of Yb3Al5O12 for thermal barrier applications are relative low thermal expansion coefficient and high thermal conductivity.In order to overcome these obstacles,herein,a new high entropy(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 ceramic was designed,and then powders and bulk were prepared through solid-state reaction method and spark plasma sintering(SPS),respectively.The thermal expansion coefficient of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 is(8.54±0.29)×10^-6 K^-1 at 673 K–1273 K,which is about 9%higher than that of Yb3Al5O12.The thermal conductivity of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 ceramic is 3.81 W·m^-1 K^-1 at 300 K,which is about 18%lower than that of Yb3Al5O12.Moreover,there is no reaction between HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 and thermally grown(TG)Al2O3 even at 1600℃.After annealing at 1590℃for 18 h,the average grain size of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 increases only from 1.56μm to 2.27μm.Close thermal expansion coefficient to TG Al2O3,low thermal conductivity,good phase stability,excellent chemical compatibility with TG Al2O3 and slow grain growth rate make HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 promising for thermal barrier applications.展开更多
文摘通过扫描电镜/能谱、X射线衍射以及金相分析,针对含0.3%Fe(质量分数)的Al Mg Si Cu铝合金,研究了Mn含量对其结晶相的影响。研究表明:合金在铸造过程中形成的结晶相为Al1.9CuMg4.1Si3.3,Al5(FeMn)Si,Al8(FeMn)2Si以及少量的Mg2Si;增大含Mn量,合金中AlFeMnSi型结晶相数量增多;对合金进行均匀化处理时,Al1.9CuMg4.1Si3.3相完全溶解,发生Al5(FeMn)Si向Al8(FeMn)2Si相的转变;对合金进行轧制及最终热处理后,结晶相碎化且沿轧向呈纤维状分布,但结晶相的类型不变。
基金Project supported by National Natural Science Foundation of China(51165032,51364035)Department of Education of JiangxiProvince(GJJ13203)+2 种基金Innovative Group of Science and Technology of College of Jiangxi Province(00008713)Jiangxi Province Education Commission Foundation(GJJ13203)University-industry Cooperation Plan of Non-party Experts and Doctor of Nanchang (2012-CYH-DW-XCL-002) for financial support
文摘The effects of Sm additions （0, 0.5 wt.%, 1.0 wt.%and 1.5 wt.%） on the eutectic Si and β-Al5FeSi phases of ADC12 as-cast alloys were studied by optical microscopy （OM）, scanning electron microscopy （SEM） and differential thermal analysis （DTA）. The experimental results showed that Sm was an effective modifying agent for the eutectic Si of ADC12 alloy, when 1.0 wt.%-1.5 wt.%Sm was added to the alloy, the coarse acicular eutectic Si was modified into fine particle or short rod structure. Moreover, the appropriate addition of Sm （about 1.0 wt.%） had marked effects on shortening the length of needle-likeβ-Al5FeSi phase. Whereas, Sm was less effective on modifying the needle-likeβ-iron to the Chinese script or sphericalα-iron phase. The modification mecha-nism was also discussed.
基金financial supported by the National Natural Science Foundation of China(Nos.51672064 and U1435206)。
文摘Ytterbium aluminum garnet(Yb3Al5O12)is considered as a promising thermal barrier material.However,the main limitations of Yb3Al5O12 for thermal barrier applications are relative low thermal expansion coefficient and high thermal conductivity.In order to overcome these obstacles,herein,a new high entropy(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 ceramic was designed,and then powders and bulk were prepared through solid-state reaction method and spark plasma sintering(SPS),respectively.The thermal expansion coefficient of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 is(8.54±0.29)×10^-6 K^-1 at 673 K–1273 K,which is about 9%higher than that of Yb3Al5O12.The thermal conductivity of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 ceramic is 3.81 W·m^-1 K^-1 at 300 K,which is about 18%lower than that of Yb3Al5O12.Moreover,there is no reaction between HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 and thermally grown(TG)Al2O3 even at 1600℃.After annealing at 1590℃for 18 h,the average grain size of HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 increases only from 1.56μm to 2.27μm.Close thermal expansion coefficient to TG Al2O3,low thermal conductivity,good phase stability,excellent chemical compatibility with TG Al2O3 and slow grain growth rate make HE(Y0.2Yb0.2Lu0.2Eu0.2Er0.2)3Al5O12 promising for thermal barrier applications.
