Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_（24）Cl_（13）（1） and MgCsV_2O_6Cl（2）,were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm（No. 123）,with a = 14.801（2）,c = 12....Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_（24）Cl_（13）（1） and MgCsV_2O_6Cl（2）,were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm（No. 123）,with a = 14.801（2）,c = 12.341（3） ？,V = 2703.5（8） ？~3,Z = 2,Mr = 3015.56,F（000） = 2640,μ = 11.044 mm-1,Dc = 3.704 g/cm3,the final R = 0.0380 and wR = 0.0937 for 1654 observed reflections with I 〉 2σ（I）. 2 crystallizes in a monoclinic space group C2/c（No. 15） with a = 11.128（2）,b = 10.540（2）,c = 6.9892（14） ？,β = 118.38（3）°,V = 721.2（2） ？~3,Z = 4,M_r = 390.55,F（000） = 712,μ = 7.997 mm-1,D_c = 3.597 g/cm^3,the final R = 0.0537 and w R = 0.1363 for 740 observed reflections with I 〉 2σ（I）. 1 exhibits a novel 8-membered-ring [V_8O_（24）] consisting of 8 corner-shared VO_4 tetrahetra,but in 2,an infinite ladder-like [VO_3]_∞ chain is formed by VO_5 square pyramids through sharing the edges.展开更多
1 Results Sub-and super-critical water is an attractive reaction medium for organic transformation because of their unique properties such as low viscosity,high density,low polarity,high solubility to organic compound...1 Results Sub-and super-critical water is an attractive reaction medium for organic transformation because of their unique properties such as low viscosity,high density,low polarity,high solubility to organic compounds,and,of course,the greenness of the medium[1-3]. We report herein some unique reactions of unsaturated compounds in sub-and super-critical water.When allylbenzene was treated in supercritical water (SCW: 380 ℃,10 min,water density=0.35 g/mL),double bond migrated to give a mixture of allylb...展开更多
基金supported by the National Natural Science Foundation of China(No.21541009)
文摘Two new crystals of chlorovanadates,Ba_8Cs_5V_8O_（24）Cl_（13）（1） and MgCsV_2O_6Cl（2）,were grown in the molten salt media. 1 crystallizes in tetragonal,space group P4/mmm（No. 123）,with a = 14.801（2）,c = 12.341（3） ？,V = 2703.5（8） ？~3,Z = 2,Mr = 3015.56,F（000） = 2640,μ = 11.044 mm-1,Dc = 3.704 g/cm3,the final R = 0.0380 and wR = 0.0937 for 1654 observed reflections with I 〉 2σ（I）. 2 crystallizes in a monoclinic space group C2/c（No. 15） with a = 11.128（2）,b = 10.540（2）,c = 6.9892（14） ？,β = 118.38（3）°,V = 721.2（2） ？~3,Z = 4,M_r = 390.55,F（000） = 712,μ = 7.997 mm-1,D_c = 3.597 g/cm^3,the final R = 0.0537 and w R = 0.1363 for 740 observed reflections with I 〉 2σ（I）. 1 exhibits a novel 8-membered-ring [V_8O_（24）] consisting of 8 corner-shared VO_4 tetrahetra,but in 2,an infinite ladder-like [VO_3]_∞ chain is formed by VO_5 square pyramids through sharing the edges.
文摘1 Results Sub-and super-critical water is an attractive reaction medium for organic transformation because of their unique properties such as low viscosity,high density,low polarity,high solubility to organic compounds,and,of course,the greenness of the medium[1-3]. We report herein some unique reactions of unsaturated compounds in sub-and super-critical water.When allylbenzene was treated in supercritical water (SCW: 380 ℃,10 min,water density=0.35 g/mL),double bond migrated to give a mixture of allylb...
