The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay ...The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy （EIS） analysis.展开更多
The performances of CMIP5 atmospheric general circulation models （AGCMs） in simulating the western North Pacific subtropical high （WNPSH） in El Nino decaying summers are examined in this study. Results show that m...The performances of CMIP5 atmospheric general circulation models （AGCMs） in simulating the western North Pacific subtropical high （WNPSH） in El Nino decaying summers are examined in this study. Results show that most models can reproduce the spatial pattern of both climatological and anomalous circulation associated with the WNPSH in El Nino decaying summers. Most CMIP5 AGCMs can capture the westward shift of the WNPSH in El Nino decaying summers compared with the climatological location. With respect to the sub-seasonal variation of the WNPSH, the performances of these AGCMs in reproducing the northward jump of the WNPSH are better than simulating the eastward retreat of the WNPSH from July to August. Twenty-one out of twenty-two （20 out of 22） models can reasonably reproduce the northward jump of the WNPSH in El Nino decaying summers （climatology）, while only 7 out of 22 （8 out of 22） AGCMs can reasonably reproduce the eastward retreat of the WNPSH in El Nino decaying summers （climatology）. In addition, there is a close connection between the climatological WNPSH location bias and that in El Nino decaying summers.展开更多
基金Project(RDCPJ346365-06)supported by the Natural Sciences and Engineering Research Council of CanadaProject(51208193)supported by the National Natural Science Foundation of ChinaProject(11jj6034)supported by the Hunan Provincial Natural Science Foundation
文摘The effect of MnO4- and silver content on electrochemical behaviour of five commercial Pb-Ag alloy anodes was studied in acid zinc sulphate electrolyte with and without MnO4- ions at 38 °C during potential decay periods. When the anodes were immersed into acid zinc sulphate electrolyte without MnO4- ions, the Pb-0.72%Ag anode entered complete passivation state in the shortest time among the five anodes, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by measurement of open circuit potential. During immersion of the anodes, MnO4 ions accelerated the passivation and increased the corrosion current density of the anodes. After immersion in zinc electrolyte with MnO4-, the anode Pb-0.72%Ag had the best corrosion resistance, followed by anodes Pb-0.67%Ag, Pb-0.60%Ag, then the close anodes Pb-0.58%Ag and Pb-0.29%Ag-0.1%Ca by the electrochemical impedance spectroscopy （EIS） analysis.
基金supported by the National Natural Science Foundation of China[grant numbers 41475052,41405058]China Postdoctoral Science Foundation[grant number 2015M571095]Strategic Priority Research Program of the Chinese Academy of Sciences[grant number XDA11010403]
文摘The performances of CMIP5 atmospheric general circulation models （AGCMs） in simulating the western North Pacific subtropical high （WNPSH） in El Nino decaying summers are examined in this study. Results show that most models can reproduce the spatial pattern of both climatological and anomalous circulation associated with the WNPSH in El Nino decaying summers. Most CMIP5 AGCMs can capture the westward shift of the WNPSH in El Nino decaying summers compared with the climatological location. With respect to the sub-seasonal variation of the WNPSH, the performances of these AGCMs in reproducing the northward jump of the WNPSH are better than simulating the eastward retreat of the WNPSH from July to August. Twenty-one out of twenty-two （20 out of 22） models can reasonably reproduce the northward jump of the WNPSH in El Nino decaying summers （climatology）, while only 7 out of 22 （8 out of 22） AGCMs can reasonably reproduce the eastward retreat of the WNPSH in El Nino decaying summers （climatology）. In addition, there is a close connection between the climatological WNPSH location bias and that in El Nino decaying summers.
