Plastic thermo-electrochemical ceils （thermocells） involving aqueous potassium ferricyanide/ferrocyanide electrolyte have been investigated as an alternative to conventional thermoelectrics for thermal energy harves...Plastic thermo-electrochemical ceils （thermocells） involving aqueous potassium ferricyanide/ferrocyanide electrolyte have been investigated as an alternative to conventional thermoelectrics for thermal energy harvesting. Plastic thermocells that consist of all pliable materials such as polyethylene terephthalate （PET）, fabrics, and wires are flexible enough to be wearable on the human body and to be wrapped around cylindrical shapes. The performance of the thermocells is enhanced by incorporating carbon nanotubes into activated carbon textiles, due to improved charge transfer at the interface. In cold weather conditions （a surrounding temperature of 5 ℃）, the thermocell generates a short-circuit current density of 0.39 A/m2 and maximum power density of 0.46 mW/m2 from body heat （temperature of 36℃）. For practical use, we have shown that the thermocell charges up a capacitor when worn on a T-shirt by a person. We also have demonstrated that the electrical energy generated from waste pipe heat using a serial array of the thermocells and voltage converters can power a typical commercial light emitting diode （LED）.展开更多
Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The s...Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The simulation experiments of accelerated thermal cycling test were performed by ANSYS software. Based on orthogonal array experiments, a back-propagation artificial neural network (BPNN) was used to establish the nonlinear multivariate relationship between thermo-mechanical fatigue reliability and control factors. Then, PSO was applied to obtaining the optimal levels of control factors by using the output of BPNN as the affinity measure. The results show that the control factors, such as print circuit board (PCB) size, PCB thickness, substrate size, substrate thickness, PCB coefficient of thermal expansion (CTE), substrate CTE, silicon die CTE, and solder joint CTE, have a great influence on thermo-mechanical fatigue reliability of PBGA solder joints. The ratio of signal to noise of ANN-PSO method is 51.77 dB and its error is 33.3% less than that of Taguchi method. Moreover, the running time of ANN-PSO method is only 2% of that of the BPNN. These conclusions are verified by the confirmative experiments.展开更多
Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was stu...Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was studied. The results show that both the absolute value of the molar enthalpy change and the internal resistance of evolution hydrogen reaction are less than that of absorption hydrogen reaction at the same state of charge. The molar reaction enthalpy change of absorption and evolution of hydride electrode change contrarily with the enhancement of filling degree of hydrogen in hydride electrode. The relation curve of molar reaction enthslpy change to state of charge, both absorption and evolution hydrogen reaction, is close to a constant when the state of charge is 10%- 60%, and during state of charge below 10% or state of charge above 60%, the molar reaction enthalpy change varies sharply. Meanwhile, the internal resistance of electrode reaction has an ascending trend with the enhancement on filling degree of hydrogen in hydride electrode in both absorption and evolution hydrogen reaction.展开更多
文摘Plastic thermo-electrochemical ceils （thermocells） involving aqueous potassium ferricyanide/ferrocyanide electrolyte have been investigated as an alternative to conventional thermoelectrics for thermal energy harvesting. Plastic thermocells that consist of all pliable materials such as polyethylene terephthalate （PET）, fabrics, and wires are flexible enough to be wearable on the human body and to be wrapped around cylindrical shapes. The performance of the thermocells is enhanced by incorporating carbon nanotubes into activated carbon textiles, due to improved charge transfer at the interface. In cold weather conditions （a surrounding temperature of 5 ℃）, the thermocell generates a short-circuit current density of 0.39 A/m2 and maximum power density of 0.46 mW/m2 from body heat （temperature of 36℃）. For practical use, we have shown that the thermocell charges up a capacitor when worn on a T-shirt by a person. We also have demonstrated that the electrical energy generated from waste pipe heat using a serial array of the thermocells and voltage converters can power a typical commercial light emitting diode （LED）.
基金Project(60371046) supported by the National Natural Science Foundation of ChinaProject(9140C0301060C03001) supported by the National Defense Science and Technology Foundation of Key Laboratory, China
文摘Based on a method combined artificial neural network (ANN) with particle swarm optimization (PSO) algorithm, the thermo-mechanical fatigue reliability of plastic ball grid array (PBGA) solder joints was studied. The simulation experiments of accelerated thermal cycling test were performed by ANSYS software. Based on orthogonal array experiments, a back-propagation artificial neural network (BPNN) was used to establish the nonlinear multivariate relationship between thermo-mechanical fatigue reliability and control factors. Then, PSO was applied to obtaining the optimal levels of control factors by using the output of BPNN as the affinity measure. The results show that the control factors, such as print circuit board (PCB) size, PCB thickness, substrate size, substrate thickness, PCB coefficient of thermal expansion (CTE), substrate CTE, silicon die CTE, and solder joint CTE, have a great influence on thermo-mechanical fatigue reliability of PBGA solder joints. The ratio of signal to noise of ANN-PSO method is 51.77 dB and its error is 33.3% less than that of Taguchi method. Moreover, the running time of ANN-PSO method is only 2% of that of the BPNN. These conclusions are verified by the confirmative experiments.
基金Project(2001AA501433) supported by the National High Technology Research and Development Programof China
文摘Application of thermal electrochemical equation to metal-hydride half-cell system was investigated, and the influence of state of charge on the thermal electrochemical performance of hydrogen storage materials was studied. The results show that both the absolute value of the molar enthalpy change and the internal resistance of evolution hydrogen reaction are less than that of absorption hydrogen reaction at the same state of charge. The molar reaction enthalpy change of absorption and evolution of hydride electrode change contrarily with the enhancement of filling degree of hydrogen in hydride electrode. The relation curve of molar reaction enthslpy change to state of charge, both absorption and evolution hydrogen reaction, is close to a constant when the state of charge is 10%- 60%, and during state of charge below 10% or state of charge above 60%, the molar reaction enthalpy change varies sharply. Meanwhile, the internal resistance of electrode reaction has an ascending trend with the enhancement on filling degree of hydrogen in hydride electrode in both absorption and evolution hydrogen reaction.
