The role of biophysical variables in constructing community structure changes with the time since fire.The major objective of this study is to verify the transition stage and its underlying variables for the postfire ...The role of biophysical variables in constructing community structure changes with the time since fire.The major objective of this study is to verify the transition stage and its underlying variables for the postfire forest and soil microbial function in the boreal forested area of China.A 50-year fire chronosequence was presented,and biomass of forbs,shrubs and woody plants was separately weighted to assess their contribution to the whole community with the year since fire(YSF).Simultaneously,soil biophysical properties were measured for stands in different time periods after fire.Soil microbial functions,i.e.growth efficiency(GE)and carbon use efficiency(CUE),were calculated based on ecoenzymatic and soil nutrient stoichiometry.In terms of vegetative structure,forbs’proportion decreased from 75%to 1.5%,but the proportion of woody plants increased from 0.04%to 70%across this fire chronosequence.GE and CUE of soil microorganisms averaged 0.242 and 0.236 and were significantly higher in 9,15 and 31 YSF than in 2 and 3 YSF.Soil metal content was significantly increased at the late stage of this fire chronosequence,and soil calcium content showed a positive correlation with woody plant biomass and a negative correlation with soil microbial function.Overall,the present work highlights that the time period of 15 and 31 YSF is a hallmark stage for aboveground vegetative structure and soil microbial function to change in different trends and that the calcium content may partly account for these two divergent trajectories.展开更多
Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiomet...Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.展开更多
The reclamation of tidal fiats has been one of the important approaches to replenish the arable lands in the coastal areas; pollution status of reclaimed soils has received wide attention recently, especially for the ...The reclamation of tidal fiats has been one of the important approaches to replenish the arable lands in the coastal areas; pollution status of reclaimed soils has received wide attention recently, especially for the study of heavy metals due to the relative high pollutant concentrations in wetlands. To understand the impact of land use change on heavy metal and arsenic (As) geochemistry by the reclamation of wetlands for agriculture, surface soils and soil profiles were collected from the agricultural land reclaimed in the 1990s and the intertidal flat wetland at Dongtan on Chongming Island in the Yangtze River Estuary, China. The soil samples were analyzed for total concentrations and chemical speciation of chromium (Cr), zinc (Zn), copper (Cu), lead (Pb), nickel (Ni), cadmium (Cd) and As using inductively coupled plasma mass spectrometry (ICP-MS). Results showed that soil properties (salinity, total organic carbon and grain-size distribution) and the concentrations of heavy metals and As in the soils differed under the different land use types. The conversion of wetland to forest had caused obvious losses of all the measured heavy metals. In paddy field and dryland with frequent cultivation, the concentrations of Cr, Zn, Cu, Ni and As were higher when compared to forest land which was disturbed rarely by human activities. Speciation analysis showed that Cr, Zn, Cu, Ni and As were predominated by the immobile residual fraction, while Pb and Cd showed relatively higher mobility. In general, metal (except Ni) and As mobility decreased in the following order: wetland 〉 dryland 〉 paddy field 〉 forest land, which suggested that the reclaimed soils had lower metal and As mobility than the intertidal fiat wetland. The results of this study contribute to a better understanding of the effects of land use on heavy metals and As in the reclaimed soils of the study area and other similar coastal areas.展开更多
Soil quality is a major concern in the management of urban parks. In this study, the soils at 0–3, 3–13, and 13–23 cm depths were sampled from six urban parks, differing in reconstruction intensity(mainly changes m...Soil quality is a major concern in the management of urban parks. In this study, the soils at 0–3, 3–13, and 13–23 cm depths were sampled from six urban parks, differing in reconstruction intensity(mainly changes made during conversion of natural forests into parklands), in the Pearl River Delta, China to determine how reconstruction intensity influenced the extent of acidification and heavy metal levels in the soils of urban parks in a humid subtropical environment. High reconstruction intensity(HRI) was practiced in three parks and low reconstruction intensity(LRI) in three other parks. The LRI soils were strongly to extremely acidic(with low exchangeable Ca, Mg, and K concentrations) while the HRI soils were much less acidic. Both total and extractable concentrations of soil heavy metals were related to the specific management practices and age of the park, but did not differ significantly between LRI and HRI parks or among soil depths. Soil p H was significantly related to soil exchangeable cation concentrations and base saturation but was weakly related or unrelated to soil heavy metal levels. Our results suggest that high intensity but not low intensity reconstruction significantly reduces the extent of soil acidification in the urban parks in a humid subtropical environment.展开更多
Mine tailing soils created from the copper extraction in Touro Mine (Northwest Spain) are very degraded both physically and chemically. Three plots in this mine tailing were amended with Technosols in different prop...Mine tailing soils created from the copper extraction in Touro Mine (Northwest Spain) are very degraded both physically and chemically. Three plots in this mine tailing were amended with Technosols in different proportions in each one to know if this mixture improved the physico-chemical characteristics of the mine soil and contaminated it with heavy metals. The Technosols were made of organic wastes, including mussel residues, wood fragments, sewage sludges and paper mill ashes. An unamended area was used as a control soil. Pseudototal and diethylenetriaminepentaacetic acid (DTPA)-extractable contents of A1, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined in soil samples. The untreated soil had significant limitations for vegetation growth. All the Technosols improved the properties of the mine soil by increasing organic carbon and pH value, but they added Ni, Pb or Zn to the soil. It is advisable to check whether the heavy metal concentrations of the wastes are hazardous or not before adding to soils. It is also necessary to study the effect of these wastes over time and in more areas to conclude if they are actually favourable to restore degraded mine soils.展开更多
基金supported jointly by the Key Project of National Key Research and Development Plan(grant no.2017YFC0504002)the Fundamental Research Funds for the Central University(grant no.2015ZCQ-LX-03).
文摘The role of biophysical variables in constructing community structure changes with the time since fire.The major objective of this study is to verify the transition stage and its underlying variables for the postfire forest and soil microbial function in the boreal forested area of China.A 50-year fire chronosequence was presented,and biomass of forbs,shrubs and woody plants was separately weighted to assess their contribution to the whole community with the year since fire(YSF).Simultaneously,soil biophysical properties were measured for stands in different time periods after fire.Soil microbial functions,i.e.growth efficiency(GE)and carbon use efficiency(CUE),were calculated based on ecoenzymatic and soil nutrient stoichiometry.In terms of vegetative structure,forbs’proportion decreased from 75%to 1.5%,but the proportion of woody plants increased from 0.04%to 70%across this fire chronosequence.GE and CUE of soil microorganisms averaged 0.242 and 0.236 and were significantly higher in 9,15 and 31 YSF than in 2 and 3 YSF.Soil metal content was significantly increased at the late stage of this fire chronosequence,and soil calcium content showed a positive correlation with woody plant biomass and a negative correlation with soil microbial function.Overall,the present work highlights that the time period of 15 and 31 YSF is a hallmark stage for aboveground vegetative structure and soil microbial function to change in different trends and that the calcium content may partly account for these two divergent trajectories.
基金Project supported by the National Natural Science Foundation of China (No. 40571130)the Natural Science Foundation of Shanghai, China (No. 07ZR14032)
文摘Concentrations of Iron (Fe), As, and Cu in soil samples from the fields near the Baoshan Mine in Hunan Province, China, were analyzed and soil spectral reflectance was measured with an ASD FieldSpec FR spectroradiometer (Analytical Spectral Devices, Inc., USA) under laboratory condition. Partial least square regression (PLSR) models were constructed for predicting soil metal concentrations. The data pre-processing methods, first and second derivatives (FD and SD), baseline correction (BC), standard normal variate (SNV), multiplicative scatter correction (MSC), and continuum removal (CR), were used for the spectral reflectance data pretreatments. Then, the prediction results were evaluated by relative root mean square error (RRMSE) and coefficients of determination (R 2 ). According to the criteria of minimal RRMSE and maximal R 2 , the PLSR models with the FD pretreatment (RRMSE = 0.24, R 2 = 0.61), SNV pretreatment (RRMSE = 0.08, R 2 = 0.78), and BC-pretreatment (RRMSE = 0.20, R 2 = 0.41) were considered as the final models for predicting As, Fe, and Cu, respectively. Wavebands at around 460, 1 400, 1 900, and 2 200 nm were selected as important spectral variables to construct final models. In conclusion, concentrations of heavy metals in contaminated soils could be indirectly assessed by soil spectra according to the correlation between the spectrally featureless components and Fe; therefore, spectral reflectance would be an alternative tool for monitoring soil heavy metals contamination.
基金supported by the National Natural Science Foundation of China (Nos. 41271466 and 40871216)
文摘The reclamation of tidal fiats has been one of the important approaches to replenish the arable lands in the coastal areas; pollution status of reclaimed soils has received wide attention recently, especially for the study of heavy metals due to the relative high pollutant concentrations in wetlands. To understand the impact of land use change on heavy metal and arsenic (As) geochemistry by the reclamation of wetlands for agriculture, surface soils and soil profiles were collected from the agricultural land reclaimed in the 1990s and the intertidal flat wetland at Dongtan on Chongming Island in the Yangtze River Estuary, China. The soil samples were analyzed for total concentrations and chemical speciation of chromium (Cr), zinc (Zn), copper (Cu), lead (Pb), nickel (Ni), cadmium (Cd) and As using inductively coupled plasma mass spectrometry (ICP-MS). Results showed that soil properties (salinity, total organic carbon and grain-size distribution) and the concentrations of heavy metals and As in the soils differed under the different land use types. The conversion of wetland to forest had caused obvious losses of all the measured heavy metals. In paddy field and dryland with frequent cultivation, the concentrations of Cr, Zn, Cu, Ni and As were higher when compared to forest land which was disturbed rarely by human activities. Speciation analysis showed that Cr, Zn, Cu, Ni and As were predominated by the immobile residual fraction, while Pb and Cd showed relatively higher mobility. In general, metal (except Ni) and As mobility decreased in the following order: wetland 〉 dryland 〉 paddy field 〉 forest land, which suggested that the reclaimed soils had lower metal and As mobility than the intertidal fiat wetland. The results of this study contribute to a better understanding of the effects of land use on heavy metals and As in the reclaimed soils of the study area and other similar coastal areas.
基金supported by the Agricultural and Forestry Promotion Fund of Nanhai Agro-forestry Extension Centre,Guangdong Province,China(No.08-4101001)the Guangdong Provincial Natural Science Foundation of China(No.8151065005000016)the Research Fund of South China Botanical Garden,China(No.201307)
文摘Soil quality is a major concern in the management of urban parks. In this study, the soils at 0–3, 3–13, and 13–23 cm depths were sampled from six urban parks, differing in reconstruction intensity(mainly changes made during conversion of natural forests into parklands), in the Pearl River Delta, China to determine how reconstruction intensity influenced the extent of acidification and heavy metal levels in the soils of urban parks in a humid subtropical environment. High reconstruction intensity(HRI) was practiced in three parks and low reconstruction intensity(LRI) in three other parks. The LRI soils were strongly to extremely acidic(with low exchangeable Ca, Mg, and K concentrations) while the HRI soils were much less acidic. Both total and extractable concentrations of soil heavy metals were related to the specific management practices and age of the park, but did not differ significantly between LRI and HRI parks or among soil depths. Soil p H was significantly related to soil exchangeable cation concentrations and base saturation but was weakly related or unrelated to soil heavy metal levels. Our results suggest that high intensity but not low intensity reconstruction significantly reduces the extent of soil acidification in the urban parks in a humid subtropical environment.
文摘Mine tailing soils created from the copper extraction in Touro Mine (Northwest Spain) are very degraded both physically and chemically. Three plots in this mine tailing were amended with Technosols in different proportions in each one to know if this mixture improved the physico-chemical characteristics of the mine soil and contaminated it with heavy metals. The Technosols were made of organic wastes, including mussel residues, wood fragments, sewage sludges and paper mill ashes. An unamended area was used as a control soil. Pseudototal and diethylenetriaminepentaacetic acid (DTPA)-extractable contents of A1, Cr, Cu, Fe, Mn, Ni, Pb and Zn were determined in soil samples. The untreated soil had significant limitations for vegetation growth. All the Technosols improved the properties of the mine soil by increasing organic carbon and pH value, but they added Ni, Pb or Zn to the soil. It is advisable to check whether the heavy metal concentrations of the wastes are hazardous or not before adding to soils. It is also necessary to study the effect of these wastes over time and in more areas to conclude if they are actually favourable to restore degraded mine soils.