Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and in...Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and inflexible structures,in a sense present major limitations in developing next-generation smart patterned surfaces.In this work,a facile and general patterning strategy is proposed to endow insensitive metal surfaces with controllable spontaneous topologies and dynamic performance by exquisitely introducing an essential photosensitive interlayer.The arresting anthracene-containing photocrosslinking interlayer can selectively predetermine the anisotropic property of compliant bilayers without damaging metals’homogeneous properties,and realize a changeable stiff/soft layer.Furthermore,the mechanical transition mechanism of the self-adaptive wrinkling modes in metalbased trilayer systems is revealed to pave the pathway for regulating functional wrinkled metal surfaces.This photodriven metal patterning strategy can promote the development of brand-new methods for tuning the instability of multilayered materials,and be potentially applied in smart optical devices with dynamic reflectance,including light gratings and"magic"mirrors.展开更多
Smart-controlled surface wettability from superhydrophilicity to superhydrophobicity has been extensively explored,and stimulus-responsive strategies have been widely accepted as a useful method to realize reversibili...Smart-controlled surface wettability from superhydrophilicity to superhydrophobicity has been extensively explored,and stimulus-responsive strategies have been widely accepted as a useful method to realize reversibility.However,achieving smart and precise wetting control remains challenging because most previous studies focused on stimulating single surface chemistry or microstructures.Herein,a dualstimulus-responsive strategy that can synergistically stimulate surface chemistry and microstructures is demonstrated on the pH-responsive molecule poly(2-(diisopropylamino)ethyl methacrylate(PDPAEMA)-modified temperature-triggered shape memory polymer(SMP)arrays.The responsive PDPAEMA and SMP can provide the surface with tunable surface chemistry and microstructures,respectively.Thus,the wetting of the surface between various states can be reversibly and precisely controlled from superhydrophilicity to superhydrophobicity with contact angle(CA)differences of less than 15° under the cooperative effect between the adjustable surface microstructure and chemistry.The surface is further utilized as a platform to create gradient wettings based on its excellent controllability.Therefore,this work presents a strategy for surface wetting control by combining tunable surface microstructures and chemistry.The prepared samples with a special wetting controllability can be applied to numerous fields,including adaptive liquid microlenses,accurate drug release,and selective catalysis.This work also proposes novel expectations in designing smart functional surfaces.展开更多
紧凑型输电线路的相间舞动一直是影响线路安全运行的因素之一,舞动跳闸的重合成功率较低,造成线路停运的几率大。特别是500 k V紧凑型线路,一旦发生舞动事故,将对系统造成很大影响,严重影响供电可靠性。目前,安装相间间隔棒是紧凑型线...紧凑型输电线路的相间舞动一直是影响线路安全运行的因素之一,舞动跳闸的重合成功率较低,造成线路停运的几率大。特别是500 k V紧凑型线路,一旦发生舞动事故,将对系统造成很大影响,严重影响供电可靠性。目前,安装相间间隔棒是紧凑型线路最直接最有效的防舞措施,但现阶段相间间隔棒采取绞链式+球窝联结,该种联结金具是非标产品,联结金具长度调节范围小,安装和调整较为困难,且容易造成相间间隔棒球头部位受到集中应力,引起相间间隔棒球头断裂。针对500 k V紧凑型线路相间间隔棒球头断裂的情况,通过开展相间间隔棒联接方式的研究,研制了相间间隔棒配套用4点连接子导线间隔棒,并在数条500 k V紧凑型线路挂网试运行,效果良好。展开更多
基金supported by the National Key R&D Program of China(2021YFB4001100)the National Natural Science Foundation of China(52025032,52103144,12032015,12121002,and 12172216)Science and Technology Innovation Action Plan of Shanghai(21190760100)。
文摘Regulating metal surfaces with micro-/nanoscale structures is of great significance for both material science and potential applications.However,the intrinsic properties of metals,such as fixed isotropic moduli and inflexible structures,in a sense present major limitations in developing next-generation smart patterned surfaces.In this work,a facile and general patterning strategy is proposed to endow insensitive metal surfaces with controllable spontaneous topologies and dynamic performance by exquisitely introducing an essential photosensitive interlayer.The arresting anthracene-containing photocrosslinking interlayer can selectively predetermine the anisotropic property of compliant bilayers without damaging metals’homogeneous properties,and realize a changeable stiff/soft layer.Furthermore,the mechanical transition mechanism of the self-adaptive wrinkling modes in metalbased trilayer systems is revealed to pave the pathway for regulating functional wrinkled metal surfaces.This photodriven metal patterning strategy can promote the development of brand-new methods for tuning the instability of multilayered materials,and be potentially applied in smart optical devices with dynamic reflectance,including light gratings and"magic"mirrors.
基金supported by the National Natural Science Foundation of China(21674030,22075061 and 51790502)the Funding of Key Laboratory of Bioinspired Materials and Interfacial Science,the Technical Institute of Physics and Chemistry,Chinese Academy of Sciences,China National Postdoctoral Program for Innovative Talents(BX20200106)。
文摘Smart-controlled surface wettability from superhydrophilicity to superhydrophobicity has been extensively explored,and stimulus-responsive strategies have been widely accepted as a useful method to realize reversibility.However,achieving smart and precise wetting control remains challenging because most previous studies focused on stimulating single surface chemistry or microstructures.Herein,a dualstimulus-responsive strategy that can synergistically stimulate surface chemistry and microstructures is demonstrated on the pH-responsive molecule poly(2-(diisopropylamino)ethyl methacrylate(PDPAEMA)-modified temperature-triggered shape memory polymer(SMP)arrays.The responsive PDPAEMA and SMP can provide the surface with tunable surface chemistry and microstructures,respectively.Thus,the wetting of the surface between various states can be reversibly and precisely controlled from superhydrophilicity to superhydrophobicity with contact angle(CA)differences of less than 15° under the cooperative effect between the adjustable surface microstructure and chemistry.The surface is further utilized as a platform to create gradient wettings based on its excellent controllability.Therefore,this work presents a strategy for surface wetting control by combining tunable surface microstructures and chemistry.The prepared samples with a special wetting controllability can be applied to numerous fields,including adaptive liquid microlenses,accurate drug release,and selective catalysis.This work also proposes novel expectations in designing smart functional surfaces.
文摘紧凑型输电线路的相间舞动一直是影响线路安全运行的因素之一,舞动跳闸的重合成功率较低,造成线路停运的几率大。特别是500 k V紧凑型线路,一旦发生舞动事故,将对系统造成很大影响,严重影响供电可靠性。目前,安装相间间隔棒是紧凑型线路最直接最有效的防舞措施,但现阶段相间间隔棒采取绞链式+球窝联结,该种联结金具是非标产品,联结金具长度调节范围小,安装和调整较为困难,且容易造成相间间隔棒球头部位受到集中应力,引起相间间隔棒球头断裂。针对500 k V紧凑型线路相间间隔棒球头断裂的情况,通过开展相间间隔棒联接方式的研究,研制了相间间隔棒配套用4点连接子导线间隔棒,并在数条500 k V紧凑型线路挂网试运行,效果良好。
