A1 doped SmFeO3 （SmFel_xmlxO3; 0.0〈x〈0.15; step 0.05） were prepared by double sintering ceramic technique. The obtained samples were crystallized in single phase structure except the sample with x=0.15. The unit c...A1 doped SmFeO3 （SmFel_xmlxO3; 0.0〈x〈0.15; step 0.05） were prepared by double sintering ceramic technique. The obtained samples were crystallized in single phase structure except the sample with x=0.15. The unit cell volume was found to decrease with increasing AI substitution in orthoferrite. The effective magnetic moment （μeff） and the Curie constant （C） were calculated from the reciprocal of the molar magnetic susceptibility （Z-1） versus absolute temperature plot and found to attain maximum value for the parent sample. The magnetic behavior showed two different magnetic transitions, viz, N6el temperature （TN） and spin reorientation （TsR） transitions. The M-H hysteresis loop of the parent sample took butterfly-shape as a result of different contributions anisotropies. From the magnetic properties measurements, it was obviously found that B-site cation dilution resulted in a drastic decrease in the magnetization. Surprisingly large value of the coercive field was obtained for the undoped sample;Hc=6198.80e. Based on the mentioned results, one can recommend the use of such orthoferrite in magnetic recording media and as pining layer in spin valve for spin- tronic applications.展开更多
The effects of Al substitution for Fe on the structure, magnetics, magnetostriction, anisotropy and spin reorientation of a series of Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 alloys (x=0.05, 0.1, 0.15, 0.2, 0.25, 0.3) at room te...The effects of Al substitution for Fe on the structure, magnetics, magnetostriction, anisotropy and spin reorientation of a series of Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 alloys (x=0.05, 0.1, 0.15, 0.2, 0.25, 0.3) at room temperature have been investigated. The alloys of Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 substantially retain MgCu2-type C-15 cubic Laves phase structure when x【0.2. The mixed phases appear with x = 0.2, and cubic Laves phase decreases with increasing x. The magnetostriction of the Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 alloys decreases drastically with increasing x and the giant magnetostrictive effect disappears for x 】 0.15. Fortunately, a small amount of Al substitution is beneficial to a decrease in the magnetocrystalline anisotropy. The spin reorientation temperature decreases with increasing x. The analysis of the Mssbauer spectra indicates that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the increase of Al concentration x, namely, spin reorientation, resulting in the change of macroscopical magnetic properties and magnetostriction. The hyperfine field decreases, but the isomer shifts increases with Al concentration increasing and the quadruple splitting QS shows a weak concentration dependence.展开更多
The magnetic properties of commercial polycrystalline Nd2Fe14B （N50M,N45H,N40SH,N35EH） and Sm2Co17（XG30/20,XG26/25,XG22/20） magnets at cryogenic temperatures were tested by using a comprehensive physical propertie...The magnetic properties of commercial polycrystalline Nd2Fe14B （N50M,N45H,N40SH,N35EH） and Sm2Co17（XG30/20,XG26/25,XG22/20） magnets at cryogenic temperatures were tested by using a comprehensive physical properties measurement system （PPMS）. The results show that the spin tilt temperature Tst of Nd2Fe14B magnets is closely related to intrinsic coercivity Hci , N50M and N45H with smaller Hci show a residual magnetization jump at 235K and 225K, respectively. For Sm2Co17 magnets, in 50-300 K, with temperature decreasing, residual magnetization Mrc shows a nearly linear increase, while in 10-50 K, Mrc has little change. The research results provide a reference for cryogenic undulators and other high-precision cryogenic devices.展开更多
The crystal structures, magnetization, and spontaneous magnetostriction of ferromagnetic Laves phase Pr1-xTbxFe1.9 compounds are investigated in a temperature range between 5 K and 300 K. High resolution synchrotron x...The crystal structures, magnetization, and spontaneous magnetostriction of ferromagnetic Laves phase Pr1-xTbxFe1.9 compounds are investigated in a temperature range between 5 K and 300 K. High resolution synchrotron x-ray diffraction(XRD) analysis shows that different proportions of Tb in Pr1-xTbxFe1.9 alloys can result in different easy magnetization directions(EMD) below 70 K, i.e., [100] with x = 0.0, and [111] with x ≥ 0.1. This indicates Tb substitution can lead the EMD to change from [100] to [111] with x rising from 0.0 up to 0.1. The Tb substitution for Pr reduces the saturation magnetization Ms and the magnetostriction to their minimum value when x = 0.6, but it can increase low-field(0 ≤ H ≤9 kOe, the unit 1 Oe = 79.5775 A·m-1) magnetostriction when x = 0.8 and 1.0 at 5 K. This can be attributed to the larger magnetostriction of PrFe1.9 than that of TbFe1.9, as well as the decrease of the resulting anisotropy due to Tb substitution at low temperatures.展开更多
The effect of Pr substitution for Dy on the magnetic and magnetostrictive properties, anisotropy, spin reorientation and Mssbauer effect of a series of Tb0.3Dy0.7-xPrx(Fe0.9Al0.1)1.95 (x=0,0.1,0.20,0.25,0.30,0.35) a...The effect of Pr substitution for Dy on the magnetic and magnetostrictive properties, anisotropy, spin reorientation and Mssbauer effect of a series of Tb0.3Dy0.7-xPrx(Fe0.9Al0.1)1.95 (x=0,0.1,0.20,0.25,0.30,0.35) alloys at room temperature have been investigated. It was found that a small amount of Pr substitution is beneficial to a decrease in the magnetocrystalline anisotropy for the Tb0.3Dy0.7-xPrx(Fe0.9Al0.1)1.95 alloys. The magnetostriction decreases drastically with increasing x and the magnetostrictive effect disappears for x>0.2. However, the magnetostriction exhibits a slightly bigger value at x=0.1 than the free alloys and is saturated more easily with the magnetic field H. The saturation magnetization and Curie temperature decrease monotonously, but the spontaneous magnetostriction increases linearly with increasing x, whereas the spin reorientation temperature increases first, then decreases rapidly and reaches the maximum at x=0.1. The analysis of Mssbauer spectra indicated that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the Pr concentration x, namely spin reorientation. Compared with Al substitution for Fe, the effect of Pr substitution for Dy on spin reorientation is relatively small. The hyperfine field increases with Pr concentration increasing, and the isomer shifts and the quadrupole splitting (QS) show weak concentration dependence.展开更多
NdMn_(6-x)CoxSn_6(x=0,0.2,0.4,0.6,0.8,1,1.5) were found to crystallize in the YCoeGe6 type structure.The magnetic ordering temperature(Curie temperature) and the saturation magnetization at room temperature decreases ...NdMn_(6-x)CoxSn_6(x=0,0.2,0.4,0.6,0.8,1,1.5) were found to crystallize in the YCoeGe6 type structure.The magnetic ordering temperature(Curie temperature) and the saturation magnetization at room temperature decreases with increasing Co content in NdMn_(6-x)Co_xSn_6 compounds.The spin reorientation process appears in all compounds.The spin orientation temperature increases with increasing Co content for NdMn_(3-x)Co_xSn_6.展开更多
Multiferroic properties in a polycrystalline terbium orthoferrite are investigated. Different thermomagnetic behaviors are observed in different magnetic fields, which is attributed to the suppression of the low tempe...Multiferroic properties in a polycrystalline terbium orthoferrite are investigated. Different thermomagnetic behaviors are observed in different magnetic fields, which is attributed to the suppression of the low temperature magnetic phase by an external magnetic field. Further studies reveal that the ferroelectricity originates from the spin configuration below 3.5 K. In addition, the magnetic field control of electric polarization and dielectric constant is observed, which suggests a magnetoelectric effect in TbFeO3. The origin of ferroelectricity in this rare-earth orthoferrite is discussed.展开更多
文摘A1 doped SmFeO3 （SmFel_xmlxO3; 0.0〈x〈0.15; step 0.05） were prepared by double sintering ceramic technique. The obtained samples were crystallized in single phase structure except the sample with x=0.15. The unit cell volume was found to decrease with increasing AI substitution in orthoferrite. The effective magnetic moment （μeff） and the Curie constant （C） were calculated from the reciprocal of the molar magnetic susceptibility （Z-1） versus absolute temperature plot and found to attain maximum value for the parent sample. The magnetic behavior showed two different magnetic transitions, viz, N6el temperature （TN） and spin reorientation （TsR） transitions. The M-H hysteresis loop of the parent sample took butterfly-shape as a result of different contributions anisotropies. From the magnetic properties measurements, it was obviously found that B-site cation dilution resulted in a drastic decrease in the magnetization. Surprisingly large value of the coercive field was obtained for the undoped sample;Hc=6198.80e. Based on the mentioned results, one can recommend the use of such orthoferrite in magnetic recording media and as pining layer in spin valve for spin- tronic applications.
基金supported by the National Natural Science Foundation of China (Grant No. 10574059)the Natural Science Foundation of Gansu Province (Grant No. 0710RJZA074)+2 种基金the Scientific Research Project of Bureau of Education of Gansu Province (Grant No. 0711B-04)the Key Project of the Science and Technology Research of Ministry of Education (Grant No. 209127)the "Qing Lan" Talent Engineering Funds of Lanzhou Jiaotong University
文摘The effects of Al substitution for Fe on the structure, magnetics, magnetostriction, anisotropy and spin reorientation of a series of Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 alloys (x=0.05, 0.1, 0.15, 0.2, 0.25, 0.3) at room temperature have been investigated. The alloys of Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 substantially retain MgCu2-type C-15 cubic Laves phase structure when x【0.2. The mixed phases appear with x = 0.2, and cubic Laves phase decreases with increasing x. The magnetostriction of the Tb0.3Dy0.6Pr0.1(Fe1-xAlx)1.95 alloys decreases drastically with increasing x and the giant magnetostrictive effect disappears for x 】 0.15. Fortunately, a small amount of Al substitution is beneficial to a decrease in the magnetocrystalline anisotropy. The spin reorientation temperature decreases with increasing x. The analysis of the Mssbauer spectra indicates that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the increase of Al concentration x, namely, spin reorientation, resulting in the change of macroscopical magnetic properties and magnetostriction. The hyperfine field decreases, but the isomer shifts increases with Al concentration increasing and the quadruple splitting QS shows a weak concentration dependence.
基金the Natural Science Foundation of Shanghai,China(Grant No.11ZR1445500)the National Natural Science Foundation of China(Grant No.11175238)
文摘The magnetic properties of commercial polycrystalline Nd2Fe14B （N50M,N45H,N40SH,N35EH） and Sm2Co17（XG30/20,XG26/25,XG22/20） magnets at cryogenic temperatures were tested by using a comprehensive physical properties measurement system （PPMS）. The results show that the spin tilt temperature Tst of Nd2Fe14B magnets is closely related to intrinsic coercivity Hci , N50M and N45H with smaller Hci show a residual magnetization jump at 235K and 225K, respectively. For Sm2Co17 magnets, in 50-300 K, with temperature decreasing, residual magnetization Mrc shows a nearly linear increase, while in 10-50 K, Mrc has little change. The research results provide a reference for cryogenic undulators and other high-precision cryogenic devices.
基金Project supported by the National Natural Science Foundation of China(Grant No.51901052)the Science Foundation of Guangxi Zhuang Autonomous Region,China(Grant No.2018GXNSFAA281294)
文摘The crystal structures, magnetization, and spontaneous magnetostriction of ferromagnetic Laves phase Pr1-xTbxFe1.9 compounds are investigated in a temperature range between 5 K and 300 K. High resolution synchrotron x-ray diffraction(XRD) analysis shows that different proportions of Tb in Pr1-xTbxFe1.9 alloys can result in different easy magnetization directions(EMD) below 70 K, i.e., [100] with x = 0.0, and [111] with x ≥ 0.1. This indicates Tb substitution can lead the EMD to change from [100] to [111] with x rising from 0.0 up to 0.1. The Tb substitution for Pr reduces the saturation magnetization Ms and the magnetostriction to their minimum value when x = 0.6, but it can increase low-field(0 ≤ H ≤9 kOe, the unit 1 Oe = 79.5775 A·m-1) magnetostriction when x = 0.8 and 1.0 at 5 K. This can be attributed to the larger magnetostriction of PrFe1.9 than that of TbFe1.9, as well as the decrease of the resulting anisotropy due to Tb substitution at low temperatures.
基金Supported by the National Natural Science Foundation of China (Grant No.10574059)the Natural Science Foundation of Gansu Province (Grant No.0710RJZA074)+1 种基金the Second Scientific Research Project of Bureau of Gansu Education‘Qing Lan’ Talent Engineering Funds of Lanzhou Jiaotong University
文摘The effect of Pr substitution for Dy on the magnetic and magnetostrictive properties, anisotropy, spin reorientation and Mssbauer effect of a series of Tb0.3Dy0.7-xPrx(Fe0.9Al0.1)1.95 (x=0,0.1,0.20,0.25,0.30,0.35) alloys at room temperature have been investigated. It was found that a small amount of Pr substitution is beneficial to a decrease in the magnetocrystalline anisotropy for the Tb0.3Dy0.7-xPrx(Fe0.9Al0.1)1.95 alloys. The magnetostriction decreases drastically with increasing x and the magnetostrictive effect disappears for x>0.2. However, the magnetostriction exhibits a slightly bigger value at x=0.1 than the free alloys and is saturated more easily with the magnetic field H. The saturation magnetization and Curie temperature decrease monotonously, but the spontaneous magnetostriction increases linearly with increasing x, whereas the spin reorientation temperature increases first, then decreases rapidly and reaches the maximum at x=0.1. The analysis of Mssbauer spectra indicated that the easy magnetization direction in the {110} plane deviates slightly from the main axis of symmetry with the Pr concentration x, namely spin reorientation. Compared with Al substitution for Fe, the effect of Pr substitution for Dy on spin reorientation is relatively small. The hyperfine field increases with Pr concentration increasing, and the isomer shifts and the quadrupole splitting (QS) show weak concentration dependence.
文摘NdMn_(6-x)CoxSn_6(x=0,0.2,0.4,0.6,0.8,1,1.5) were found to crystallize in the YCoeGe6 type structure.The magnetic ordering temperature(Curie temperature) and the saturation magnetization at room temperature decreases with increasing Co content in NdMn_(6-x)Co_xSn_6 compounds.The spin reorientation process appears in all compounds.The spin orientation temperature increases with increasing Co content for NdMn_(3-x)Co_xSn_6.
基金supported by the National Basic Research Program of China(Grant Nos.2012CB932304 and 2014AA032904)the National Natural ScienceFoundation of China(Grant Nos.11174130 and U1232210)
文摘Multiferroic properties in a polycrystalline terbium orthoferrite are investigated. Different thermomagnetic behaviors are observed in different magnetic fields, which is attributed to the suppression of the low temperature magnetic phase by an external magnetic field. Further studies reveal that the ferroelectricity originates from the spin configuration below 3.5 K. In addition, the magnetic field control of electric polarization and dielectric constant is observed, which suggests a magnetoelectric effect in TbFeO3. The origin of ferroelectricity in this rare-earth orthoferrite is discussed.
