Routine testing and evaluation of denitration catalyst performance are important approaches for effective operation and management of flue gas denitration system. A selective catalytic reduction (SCR) denitration cata...Routine testing and evaluation of denitration catalyst performance are important approaches for effective operation and management of flue gas denitration system. A selective catalytic reduction (SCR) denitration catalyst used in a power plant in Xiamen was investigated in this study. The surface activity, microscopic properties and surface deposit of the catalyst were tested. It was found that: the activity (K/K 0) of the catalyst was 0.72 after 25 144 hours of operation. Almost no pores in the used catalyst had a channel diameter less than 3.5 nm. The specific surface area reduced significantly to 13.5% 17.7%. Loss of VO X compound was observed. Crystal particles showed some degree of conglomeration. Further study found that the concentrations of Ca 2+ , Na + , K + and P deposited on the surface of the used catalyst were 4.5 5, 115 140, 4.6 5.7, and 7.4 7.9 times of that on fresh catalyst, respectively. Accumulation of Arsenic (As) on the catalyst was also found. The research methods adopted in this study and the results of the experiments are useful for developing catalyst testing and evaluation program in China. They may play an important role in optimizing the operation of flue gas De-NO X system, selection of regeneration process, increase of catalyst life time, and reduction of operation cost.展开更多
Copper-cerium-zirconium catalysts loaded on Ti02 prepared by a wet impregnation method were investigated for NHz-selective catalytic reduction （SCR） of NOx. The reaction mechanism was proposed on the basis of result...Copper-cerium-zirconium catalysts loaded on Ti02 prepared by a wet impregnation method were investigated for NHz-selective catalytic reduction （SCR） of NOx. The reaction mechanism was proposed on the basis of results from in situ diffuse reflectance infrared transform spectroscopy （DRIFT）. When NH3 is introduced, ammonia bonded to Lewis acid sites is more stable over CuCe0.25Zr0.75/TiO2 at high temperature, while Brensted acid sites are more important than Lewis acid sites at low temperature. For the NH3＋NO＋O2 co-adsorption, NH3 species occupy most of activity sites on CuCe0.25Zr0.75/TiO2 catalyst, and mainly exist in the forms of NH4＋ （at low temperature） and NH3 coordinated （at high temperature）, playing a crucial role in the NHz-SCR process. Two different reaction routes, the L-H mechanism at low temperature （〈 200℃） and the E-R mechanism at high temperature （〉200℃）, are presented for the SCR reaction over C uCe0.25Zr0.75/TiO2 catalyst.展开更多
In order to reduce oxides of nitrogen （NOx） emanated from a diesel engine, a comprehensive urea selective catalyst reduction （SCR） DeNOx catalyst was modeled in which numerical simulations were used as a complemen...In order to reduce oxides of nitrogen （NOx） emanated from a diesel engine, a comprehensive urea selective catalyst reduction （SCR） DeNOx catalyst was modeled in which numerical simulations were used as a complementary tool for the experimental investigations to make the design decisions, and hence shorten the de- velopment process. In this approach, relevant conversion reactions were studied in 1D model, and the parame- ters obtained in this way were transferred to 3D simulations. According to the results of the study, the conver- sion of NO and NO2 increased with the increase in monolith solid temperature. With the increase in the ratio of NO2/NOx the conversion of NO, NO2 and NOx increased resulting in maximum reduction of NOxat the ratio of 1; beyond this ratio, the conversion of NO2 and NOx decreased; however, NO continued to be converted till the ratio was 1.8. The conversion of NOx decreased with the increase in space velocity.展开更多
文摘Routine testing and evaluation of denitration catalyst performance are important approaches for effective operation and management of flue gas denitration system. A selective catalytic reduction (SCR) denitration catalyst used in a power plant in Xiamen was investigated in this study. The surface activity, microscopic properties and surface deposit of the catalyst were tested. It was found that: the activity (K/K 0) of the catalyst was 0.72 after 25 144 hours of operation. Almost no pores in the used catalyst had a channel diameter less than 3.5 nm. The specific surface area reduced significantly to 13.5% 17.7%. Loss of VO X compound was observed. Crystal particles showed some degree of conglomeration. Further study found that the concentrations of Ca 2+ , Na + , K + and P deposited on the surface of the used catalyst were 4.5 5, 115 140, 4.6 5.7, and 7.4 7.9 times of that on fresh catalyst, respectively. Accumulation of Arsenic (As) on the catalyst was also found. The research methods adopted in this study and the results of the experiments are useful for developing catalyst testing and evaluation program in China. They may play an important role in optimizing the operation of flue gas De-NO X system, selection of regeneration process, increase of catalyst life time, and reduction of operation cost.
文摘Copper-cerium-zirconium catalysts loaded on Ti02 prepared by a wet impregnation method were investigated for NHz-selective catalytic reduction （SCR） of NOx. The reaction mechanism was proposed on the basis of results from in situ diffuse reflectance infrared transform spectroscopy （DRIFT）. When NH3 is introduced, ammonia bonded to Lewis acid sites is more stable over CuCe0.25Zr0.75/TiO2 at high temperature, while Brensted acid sites are more important than Lewis acid sites at low temperature. For the NH3＋NO＋O2 co-adsorption, NH3 species occupy most of activity sites on CuCe0.25Zr0.75/TiO2 catalyst, and mainly exist in the forms of NH4＋ （at low temperature） and NH3 coordinated （at high temperature）, playing a crucial role in the NHz-SCR process. Two different reaction routes, the L-H mechanism at low temperature （〈 200℃） and the E-R mechanism at high temperature （〉200℃）, are presented for the SCR reaction over C uCe0.25Zr0.75/TiO2 catalyst.
基金Sponsored by Postdoctoral Science Foundation of China(2007042031)
文摘In order to reduce oxides of nitrogen （NOx） emanated from a diesel engine, a comprehensive urea selective catalyst reduction （SCR） DeNOx catalyst was modeled in which numerical simulations were used as a complementary tool for the experimental investigations to make the design decisions, and hence shorten the de- velopment process. In this approach, relevant conversion reactions were studied in 1D model, and the parame- ters obtained in this way were transferred to 3D simulations. According to the results of the study, the conver- sion of NO and NO2 increased with the increase in monolith solid temperature. With the increase in the ratio of NO2/NOx the conversion of NO, NO2 and NOx increased resulting in maximum reduction of NOxat the ratio of 1; beyond this ratio, the conversion of NO2 and NOx decreased; however, NO continued to be converted till the ratio was 1.8. The conversion of NOx decreased with the increase in space velocity.
