Radiation induced grafting of various polymers with different monomers proved to be an attractive means to modify the physical or chemical properties of polymeric materials or textile fabrics. In the present work, rad...Radiation induced grafting of various polymers with different monomers proved to be an attractive means to modify the physical or chemical properties of polymeric materials or textile fabrics. In the present work, radiation induced grafting of viscose rayon fabrics, consisting mainly of cellulose fibers, with acrylic acid monomer has been carried out. The grafting yields have been thoroughly studied as a function of different applied experimental parameters. The impact of the graft yield on the physical properties of the fabrics such as tensile strength, elongation, swelling, moisture absorption, crease recovery angle and also the dyeing properties of the fabrics has been studied. The effect of increasing the contact time of the fabric and monomer solution, at room temperature, after stopping irradiation has been studied in detail as well as the effect of temperature on the irradiated samples also after stopping irradiation. The best grafting yield was obtained on irradiating viscose rayon fabric in methanol-water solvent containing acrylic acid monomer, at a dose 20 kGys, then heating for 7 hours at 80℃ and finally keeping the samples at room temperature for about 20 hours. That treatment significantly increased the final graft yield.展开更多
JIS L1030-2:2012中给出了用次氯酸钠分析某些蛋白质纤维与某些非蛋白质纤维的定量分析方法,但在实际应用中,用标准中给出的试验条件溶解粘胶和丝的混合物发现了粘胶受损的情况,与标准中规定的粘胶质量变化修正系数1.00不符,本文探讨了...JIS L1030-2:2012中给出了用次氯酸钠分析某些蛋白质纤维与某些非蛋白质纤维的定量分析方法,但在实际应用中,用标准中给出的试验条件溶解粘胶和丝的混合物发现了粘胶受损的情况,与标准中规定的粘胶质量变化修正系数1.00不符,本文探讨了一种通用性较强的试验条件,减少了粘胶的受损、有效提升了测试精度。展开更多
Radiation induced grafting of viscose rayon fabrics, consisting mainly of cellulose fibers, with some acrylic acid derivatives, namely methyl acrylate, acrylamide and acrylonitrile, and also styrene, has been studied....Radiation induced grafting of viscose rayon fabrics, consisting mainly of cellulose fibers, with some acrylic acid derivatives, namely methyl acrylate, acrylamide and acrylonitrile, and also styrene, has been studied. The resultant graft yields have been determined as a function of the applied different experimental parameters. The impact of the graft yields on the physicochemical properties of viscose rayon fabrics such as swelling, moisture absorption, tensile strength, elongation at break, crease recovery angle and also dyeing ability of the grafted fabrics, has been also studied.展开更多
Fibre bundle testing is different from single-fibre measurement, not only in testing methods and instruments, but in the results obtained. For wool fibres, Sirolan-TENSOR can supply fibre-bundle tenacity (BS) and bund...Fibre bundle testing is different from single-fibre measurement, not only in testing methods and instruments, but in the results obtained. For wool fibres, Sirolan-TENSOR can supply fibre-bundle tenacity (BS) and bundle extension (BE), but has some limitations on the analysis of the measured tensile curves of fibre bundles. It has not only raised new parameters,such as initial modulus (BM) and specific work of rupture (BW), as well as the specific work before or after the peak-point(WBP or WAP) and the ratios of WAP/WBP and WAP/BW, but also compared the tensile behaviour of different fibre-bundles, e.g. wool,polyester and viscose rayon fibre- bundles. The experimental results from 32 lots of wool tops show that there are correlations between bundle tensile properties,such as BS-BE, BS-BM, BS-BW, BE-BW and BM-BW.However, the variables of coefficients of variance (CV)are almost independent of each other and have no correlation with the average values of fibre bundle tensile parameters, except for BS-CVBM and CVBM-BW.展开更多
文摘Radiation induced grafting of various polymers with different monomers proved to be an attractive means to modify the physical or chemical properties of polymeric materials or textile fabrics. In the present work, radiation induced grafting of viscose rayon fabrics, consisting mainly of cellulose fibers, with acrylic acid monomer has been carried out. The grafting yields have been thoroughly studied as a function of different applied experimental parameters. The impact of the graft yield on the physical properties of the fabrics such as tensile strength, elongation, swelling, moisture absorption, crease recovery angle and also the dyeing properties of the fabrics has been studied. The effect of increasing the contact time of the fabric and monomer solution, at room temperature, after stopping irradiation has been studied in detail as well as the effect of temperature on the irradiated samples also after stopping irradiation. The best grafting yield was obtained on irradiating viscose rayon fabric in methanol-water solvent containing acrylic acid monomer, at a dose 20 kGys, then heating for 7 hours at 80℃ and finally keeping the samples at room temperature for about 20 hours. That treatment significantly increased the final graft yield.
文摘Radiation induced grafting of viscose rayon fabrics, consisting mainly of cellulose fibers, with some acrylic acid derivatives, namely methyl acrylate, acrylamide and acrylonitrile, and also styrene, has been studied. The resultant graft yields have been determined as a function of the applied different experimental parameters. The impact of the graft yields on the physicochemical properties of viscose rayon fabrics such as swelling, moisture absorption, tensile strength, elongation at break, crease recovery angle and also dyeing ability of the grafted fabrics, has been also studied.
基金the key research project of the Ministry of Education P.R.C.(No.00058)
文摘Fibre bundle testing is different from single-fibre measurement, not only in testing methods and instruments, but in the results obtained. For wool fibres, Sirolan-TENSOR can supply fibre-bundle tenacity (BS) and bundle extension (BE), but has some limitations on the analysis of the measured tensile curves of fibre bundles. It has not only raised new parameters,such as initial modulus (BM) and specific work of rupture (BW), as well as the specific work before or after the peak-point(WBP or WAP) and the ratios of WAP/WBP and WAP/BW, but also compared the tensile behaviour of different fibre-bundles, e.g. wool,polyester and viscose rayon fibre- bundles. The experimental results from 32 lots of wool tops show that there are correlations between bundle tensile properties,such as BS-BE, BS-BM, BS-BW, BE-BW and BM-BW.However, the variables of coefficients of variance (CV)are almost independent of each other and have no correlation with the average values of fibre bundle tensile parameters, except for BS-CVBM and CVBM-BW.
