甲醇制烯烃技术(DMTO,Dimethylether/Methanol to Olefin)是中科院大连化学物理研究所与中石化洛阳工程有限公司和新兴能源科技公司合作开发的具有自主知识产权的低碳烯烃生产新技术。2010年8月采用DMTO技术的世界上首套甲醇制烯烃工业...甲醇制烯烃技术(DMTO,Dimethylether/Methanol to Olefin)是中科院大连化学物理研究所与中石化洛阳工程有限公司和新兴能源科技公司合作开发的具有自主知识产权的低碳烯烃生产新技术。2010年8月采用DMTO技术的世界上首套甲醇制烯烃工业装置在神华包头投料开车成功;2013年2月宁波禾元的DMTO工业装置也投入运行。这两套装置的甲醇进料量均为1.80 Mt/a,烯烃产量为600 kt/a。本文对DMTO工艺机理、工程设计特点和投料运行进行了介绍。DMTO工业装置运行结果表明,DMTO专用催化剂具有非常好的活性、选择性及抗磨损性能;采用大型浅层密相流化床反应器可以发挥催化剂性能,保障反应床层恒温及提高运行可靠性。为了减少开工阶段喷燃烧油可能对催化剂带来的不利影响,两套工业装置的投料开车均采用首创的利用反应热来进行再生器和反应器升温的方法。DMTO工业装置稳定运行时甲醇转化率接近100%,双烯选择性达到80%。72 h标定结果显示,生产1 t烯烃所需要的甲醇原料约为2.97 t。展开更多
Due to increasingly stringent environmental pollution norms,there is a need for alternate combustion techniques and alternate fuels to keep up with changing trends.One of the viable solutions for India is the adaptati...Due to increasingly stringent environmental pollution norms,there is a need for alternate combustion techniques and alternate fuels to keep up with changing trends.One of the viable solutions for India is the adaptation of methanol as a fuel for automotive sector.Therefore,in this study a functional two-wheeler prototype was developed,which uses M85(85%v/v methanol and 15%v/v gasoline)in an electronic control unit(ECU)controlled port fuel injected(PFI)engine.This study included comparative investigations of simulated on-road two-wheeler performance on chassis dynamometer using a gasoline-fuelled motorcycle with stock ECU vis-a-vis M85-fuelled motorcycle using recalibrated ECU.ECU recalibration exhibited that M85-fuelled vehicle was operated at relatively more advanced spark timing compared to baseline gasoline-fuelled vehicle.Performance results showed that M85-fuelled motorcycle produced relatively higher engine power and higher maximum vehicle speed compared to gasoline-fuelled motorcycle.Relatively superior acceleration characteristics(especially at higher speeds)of M85-fuelled motorcycle was another important finding of this study,indicating that M85 provided superior throttle response compared to gasoline.Comparative analysis of raw tailpipe emissions showed that modified M85-fuelled motorcycle emitted relatively higher hydrocarbon(HC),carbon monoxide(CO)and oxides of nitrogen(NO_x)emissions compared to stock gasoline-fuelled motorcycle.However,these emissions can be controlled by using adaptation of suitable after-treatment systems.展开更多
文摘Due to increasingly stringent environmental pollution norms,there is a need for alternate combustion techniques and alternate fuels to keep up with changing trends.One of the viable solutions for India is the adaptation of methanol as a fuel for automotive sector.Therefore,in this study a functional two-wheeler prototype was developed,which uses M85(85%v/v methanol and 15%v/v gasoline)in an electronic control unit(ECU)controlled port fuel injected(PFI)engine.This study included comparative investigations of simulated on-road two-wheeler performance on chassis dynamometer using a gasoline-fuelled motorcycle with stock ECU vis-a-vis M85-fuelled motorcycle using recalibrated ECU.ECU recalibration exhibited that M85-fuelled vehicle was operated at relatively more advanced spark timing compared to baseline gasoline-fuelled vehicle.Performance results showed that M85-fuelled motorcycle produced relatively higher engine power and higher maximum vehicle speed compared to gasoline-fuelled motorcycle.Relatively superior acceleration characteristics(especially at higher speeds)of M85-fuelled motorcycle was another important finding of this study,indicating that M85 provided superior throttle response compared to gasoline.Comparative analysis of raw tailpipe emissions showed that modified M85-fuelled motorcycle emitted relatively higher hydrocarbon(HC),carbon monoxide(CO)and oxides of nitrogen(NO_x)emissions compared to stock gasoline-fuelled motorcycle.However,these emissions can be controlled by using adaptation of suitable after-treatment systems.
