A novel type of composite electrode based on sheet like cobalt oxide particles has been used in supercapacitors. Cobalt oxide cathodically deposited from Co（NO3）2 solution with carbon nanotubes as matrix exhibited l...A novel type of composite electrode based on sheet like cobalt oxide particles has been used in supercapacitors. Cobalt oxide cathodically deposited from Co（NO3）2 solution with carbon nanotubes as matrix exhibited large pseudo-capacitance of 322 F·g^-1 in 6 mol·L^-1 KOH. A sol-gel process for the preparation of ultrafine RuO2 particles was developed to design electrodes with large surface area. The composite electrodes were developed by the deposition of RuO： on the surface of carbon nanotubes. A specific capacitance of 785 F·g^-1 can be achieved with the 20% carbon nanotubes loaded. To characterize the metal oxide nanocomposite electrode, a cyclic voltammetry and AC impedance test are executed. This study also reports a hybrid capacitor, which consists of cobalt oxide composite as a cathode and ruthenium oxide composite as an anode. The electrochemical performance of the hybrid capacitor is characterized by a dc charge/discharge test and cyclic voltammograms. The hybrid capacitor shows capacitor behavior with an extended operating voltage of 1.4 V. The maximum energy density and specific power density of the cell reach the value of 23.7 and 8.1 kW·g^-1 respectively. The hybrid capacitor exhibits high-energy density and stable power characteristics.展开更多
PbO_2/activated carbon（AC） hybrid supercapacitor in H_2SO_4 with a carbon foam current collector is studied.The PbO_2/AC hybrid is designed with electrodeposited PbO_2 thin film as positive electrode to match with A...PbO_2/activated carbon（AC） hybrid supercapacitor in H_2SO_4 with a carbon foam current collector is studied.The PbO_2/AC hybrid is designed with electrodeposited PbO_2 thin film as positive electrode to match with AC negative electrode.The discharge curve shows capacitive characteristics between 1.88 V and 0.65 V.The hybrid system exhibits excellent energy and power performance,with specific energy of 43.6 Wh/kg at a power density of 654.2 W/kg.The use of carbon foam current collector ensures stability of the PbO_2 electrode in H_2SO_4 environment.After 2600 deep cycles at 15 C high rate of charge/discharge,the capacity remains nearly unchanged from its initial value.展开更多
The controllable construction of two-dimensional(2D)metal–organic framework(MOF)nanosheets with favorable electrochemical performances is greatly challenging for energy storage.Here,we design an in situ induced growt...The controllable construction of two-dimensional(2D)metal–organic framework(MOF)nanosheets with favorable electrochemical performances is greatly challenging for energy storage.Here,we design an in situ induced growth strategy to construct the ultrathin carboxylated carbon nanotubes(C-CNTs)interpenetrated nickel MOF(Ni-MOF/C-CNTs)nanosheets.The deliberate thickness and specific surface area of novel 2D hybrid nanosheets can be effectively tuned via finely controlling C-CNTs involvement.Due to the unique microstructure,the integrated 2D hybrid nanosheets are endowed with plentiful electroactive sites to promote the electrochemical performances greatly.The prepared Ni-MOF/C-CNTs nanosheets exhibit superior specific capacity of 680 C g^−1 at 1 A g^−1 and good capacity retention.The assembled hybrid device demonstrated the maximum energy density of 44.4 Wh kg^−1 at a power density of 440 W kg^−1.Our novel strategy to construct ultrathin 2D MOF with unique properties can be extended to synthesize various MOF-based functional materials for diverse applications.展开更多
作为大规模储能系统的重要组成,混合型超级电容器的荷电状态(state of charge,SOC)估计是能量管理系统必不可少的部分。该文提出一种基于动态容值修正的超级电容器SOC预估方法。首先,利用参数辨识方法求解超级电容器实时电动势,定义不...作为大规模储能系统的重要组成,混合型超级电容器的荷电状态(state of charge,SOC)估计是能量管理系统必不可少的部分。该文提出一种基于动态容值修正的超级电容器SOC预估方法。首先,利用参数辨识方法求解超级电容器实时电动势,定义不同初始电压放电至相同终止电压的容值为动态容值。其次,设计不同温度、不同电流倍率的实验得到超级电容器不同工况下特性。再次,建立基于动态容值修正的全工况预测模型,修正电动势归一化和电荷再分配现象导致的SOC估计的误差。最后,通过多个温度下的随机变电流放电实验数据,将基于动态容值修正的SOC估计值和电流Ah积分法得到的SOC参考值进行对比,证明该SOC估计方法的准确性。展开更多
文摘A novel type of composite electrode based on sheet like cobalt oxide particles has been used in supercapacitors. Cobalt oxide cathodically deposited from Co（NO3）2 solution with carbon nanotubes as matrix exhibited large pseudo-capacitance of 322 F·g^-1 in 6 mol·L^-1 KOH. A sol-gel process for the preparation of ultrafine RuO2 particles was developed to design electrodes with large surface area. The composite electrodes were developed by the deposition of RuO： on the surface of carbon nanotubes. A specific capacitance of 785 F·g^-1 can be achieved with the 20% carbon nanotubes loaded. To characterize the metal oxide nanocomposite electrode, a cyclic voltammetry and AC impedance test are executed. This study also reports a hybrid capacitor, which consists of cobalt oxide composite as a cathode and ruthenium oxide composite as an anode. The electrochemical performance of the hybrid capacitor is characterized by a dc charge/discharge test and cyclic voltammograms. The hybrid capacitor shows capacitor behavior with an extended operating voltage of 1.4 V. The maximum energy density and specific power density of the cell reach the value of 23.7 and 8.1 kW·g^-1 respectively. The hybrid capacitor exhibits high-energy density and stable power characteristics.
基金the financial support of this research work from Natural Science Foundation of China(No 20663005)
文摘PbO_2/activated carbon（AC） hybrid supercapacitor in H_2SO_4 with a carbon foam current collector is studied.The PbO_2/AC hybrid is designed with electrodeposited PbO_2 thin film as positive electrode to match with AC negative electrode.The discharge curve shows capacitive characteristics between 1.88 V and 0.65 V.The hybrid system exhibits excellent energy and power performance,with specific energy of 43.6 Wh/kg at a power density of 654.2 W/kg.The use of carbon foam current collector ensures stability of the PbO_2 electrode in H_2SO_4 environment.After 2600 deep cycles at 15 C high rate of charge/discharge,the capacity remains nearly unchanged from its initial value.
基金supported by National Natural Science Foundation of China(21878062)
文摘The controllable construction of two-dimensional(2D)metal–organic framework(MOF)nanosheets with favorable electrochemical performances is greatly challenging for energy storage.Here,we design an in situ induced growth strategy to construct the ultrathin carboxylated carbon nanotubes(C-CNTs)interpenetrated nickel MOF(Ni-MOF/C-CNTs)nanosheets.The deliberate thickness and specific surface area of novel 2D hybrid nanosheets can be effectively tuned via finely controlling C-CNTs involvement.Due to the unique microstructure,the integrated 2D hybrid nanosheets are endowed with plentiful electroactive sites to promote the electrochemical performances greatly.The prepared Ni-MOF/C-CNTs nanosheets exhibit superior specific capacity of 680 C g^−1 at 1 A g^−1 and good capacity retention.The assembled hybrid device demonstrated the maximum energy density of 44.4 Wh kg^−1 at a power density of 440 W kg^−1.Our novel strategy to construct ultrathin 2D MOF with unique properties can be extended to synthesize various MOF-based functional materials for diverse applications.
基金supported by Ningbo Municipal 3315 Talent Scheme by Ningbo Science and Technology BureauZhejiang Provincial Natural Science Foundation of China(LQ23F010016 and LR19F010001)。
文摘作为大规模储能系统的重要组成,混合型超级电容器的荷电状态(state of charge,SOC)估计是能量管理系统必不可少的部分。该文提出一种基于动态容值修正的超级电容器SOC预估方法。首先,利用参数辨识方法求解超级电容器实时电动势,定义不同初始电压放电至相同终止电压的容值为动态容值。其次,设计不同温度、不同电流倍率的实验得到超级电容器不同工况下特性。再次,建立基于动态容值修正的全工况预测模型,修正电动势归一化和电荷再分配现象导致的SOC估计的误差。最后,通过多个温度下的随机变电流放电实验数据,将基于动态容值修正的SOC估计值和电流Ah积分法得到的SOC参考值进行对比,证明该SOC估计方法的准确性。
