为实现对于电导率的准确测量,研究Van Der Pauw原理及其应用于电导率绝对测量的理论依据,设计径轴二维可调的四电极结构.分析电极的对称性、电导池的封闭性对测量结果的影响,实验结果证明对称性好、结构封闭的Van Der Pauw法电导率计,...为实现对于电导率的准确测量,研究Van Der Pauw原理及其应用于电导率绝对测量的理论依据,设计径轴二维可调的四电极结构.分析电极的对称性、电导池的封闭性对测量结果的影响,实验结果证明对称性好、结构封闭的Van Der Pauw法电导率计,对溶液电导率具有较高的测量精度,并能够实现绝对测量.基于Van Der Pauw法的电导池常数κ仅与电极长度有关的原则,设计几种不同电极长度的电极,开展多种不同电导率溶液的测量实验,得出不同电导池常数κ的最佳测量范围.运用电导池常数为0.1cm-1的电极,对电导率为20~500μS/cm内的多个实际水样进行测量,相对误差小于1.0%.结果表明该新型电导率测量方法具有很好的应用前景和推广价值.展开更多
In order to explore the influence of soil resistivity on stray current in power supply system of urban rail transit,we establish an equivalent circuit model of the rail-to-ground structure based on resistance network ...In order to explore the influence of soil resistivity on stray current in power supply system of urban rail transit,we establish an equivalent circuit model of the rail-to-ground structure based on resistance network method first.After measuring the soil resistivity of a real subway system,a simulation model is established in Matlab to obtain the stray currents at different soil resistivities.Then the influence of soil resistivity on stray current is analyzed.Afterwards,to verify the rationality and reliability of the simulation model,we design a test circuit to measure the stray current and rail-to-ground voltage in a real subway system,and a comparison of the experimentally measured results and simulation results is presented.The results show that the stray current is the maximum when the soil resistivity is 211.57Ω·m;when the soil resistivity is 768.47Ω·m,the stray current is the minimum,that is,the smaller the soil resistivity,the greater the stray current.Therefore,the resistivity should be increased as much as possible when ramming the track foundation in urban rail transit system.展开更多
A novel idea of in-cell iR compensation was proposed by using a four-electrode electrochemical system, which was consisted of two working electrodes, one reference electrode （RE） and one auxiliary electrode （AE）. ...A novel idea of in-cell iR compensation was proposed by using a four-electrode electrochemical system, which was consisted of two working electrodes, one reference electrode （RE） and one auxiliary electrode （AE）. One of the two working electrodes was called the auxiliary working electrode （AWE）, which was directly connected to the ground. Another working electrode was used as a regular working electrode （WE） for electrochemical testing. The reference electrode was set in a frit close to the AWE for potential sampling. The other electrodes, WE, RE and AE, were connected to a conventional potentiostat of three-electrode system for electrochemical measurements. A linear narrow electrochemical cell was designed for setting AE at one end and AWE with RE at another end, and setting WE in between AE and AWE. In this way, a positive feedback potential was generated at the working electrode from the solution resistance and the current flow in the solution. An formal iR compensation over 100%, as high as 500%, had been achieved without potential oscillation. The electrochemical cell design, the principle of the in-cell iR compensation, and the preliminary voltammetric characterization by using the redox reaction of ferrocyanide anions were reported.展开更多
A soil electrical conductivity(EC)measurement system based on direct digital synthesizer(DDS)and digital oscilloscope was developed.The system took the“current-voltage four-electrode method”as the design principal a...A soil electrical conductivity(EC)measurement system based on direct digital synthesizer(DDS)and digital oscilloscope was developed.The system took the“current-voltage four-electrode method”as the design principal and adopted a six-pin structure of the probe,two center pins to measure the soil EC in shallow layer,two outside pins to measure the soil EC in deep layer,and two middle pins for inputting the driving current.A signal generating circuit using DDS technology was adopted to generate sine signals,which was connected with the two middle pins.A digital oscilloscope was used to record and store the two soil output signals with noises in microseconds,which were from the two center pins and two outside pins,respectively.Then a digital bandpass filter was used to filter the soil output signals recorded by the digital oscilloscope.Compared with the traditional analog filter circuit,the digital filter could filter out the noises of all frequency except for the frequency of the excitation source.It could improve the effect of filtering and the accuracy of the soil EC measurement system.The DDS circuit could provide more stable sine signals with larger amplitudes.The use of digital oscilloscope enables us to analyze the soil output signals in microseconds and measure the soil EC more accurately.The new soil EC measurement system based on DDS and digital oscilloscope can provide a new effective tool for soil sensing in precision agriculture.展开更多
Based on the circuit principle of 1186 Electro Chemical Interface preduced by Solartron Electronic Group Ltd., a precise electro chemical interface (ECI) unit, which can provide the interfacing requirements for the co...Based on the circuit principle of 1186 Electro Chemical Interface preduced by Solartron Electronic Group Ltd., a precise electro chemical interface (ECI) unit, which can provide the interfacing requirements for the control and measurement of characteristics of electro chemical cell, was developed by means of some essential improvements. Not only can it be used to control and measure the steady and non-steady state characteristics, but also it can be directly connected with Solartron 1170 series or 1250 Frequency Response Analysers (FRA) to measure the AC impedance. Besides,the EC1 can also be connected with two- or three-electrode electro chemical cell systems to test convenlently and correctly their DC and AC characteristics, and used as a four-electrode potentlostat combined with four-electrode electro chernical cell system which contains two reference electrodes (RES) for researches on the electro chemical characteristics of oil-water interface, etc.展开更多
文摘为实现对于电导率的准确测量,研究Van Der Pauw原理及其应用于电导率绝对测量的理论依据,设计径轴二维可调的四电极结构.分析电极的对称性、电导池的封闭性对测量结果的影响,实验结果证明对称性好、结构封闭的Van Der Pauw法电导率计,对溶液电导率具有较高的测量精度,并能够实现绝对测量.基于Van Der Pauw法的电导池常数κ仅与电极长度有关的原则,设计几种不同电极长度的电极,开展多种不同电导率溶液的测量实验,得出不同电导池常数κ的最佳测量范围.运用电导池常数为0.1cm-1的电极,对电导率为20~500μS/cm内的多个实际水样进行测量,相对误差小于1.0%.结果表明该新型电导率测量方法具有很好的应用前景和推广价值.
基金National Natural Science Foundation of China(Nos.51476073,51266004)Natural Science Foundation of Gansu Province(No.1308RJZA199)。
文摘In order to explore the influence of soil resistivity on stray current in power supply system of urban rail transit,we establish an equivalent circuit model of the rail-to-ground structure based on resistance network method first.After measuring the soil resistivity of a real subway system,a simulation model is established in Matlab to obtain the stray currents at different soil resistivities.Then the influence of soil resistivity on stray current is analyzed.Afterwards,to verify the rationality and reliability of the simulation model,we design a test circuit to measure the stray current and rail-to-ground voltage in a real subway system,and a comparison of the experimentally measured results and simulation results is presented.The results show that the stray current is the maximum when the soil resistivity is 211.57Ω·m;when the soil resistivity is 768.47Ω·m,the stray current is the minimum,that is,the smaller the soil resistivity,the greater the stray current.Therefore,the resistivity should be increased as much as possible when ramming the track foundation in urban rail transit system.
文摘A novel idea of in-cell iR compensation was proposed by using a four-electrode electrochemical system, which was consisted of two working electrodes, one reference electrode （RE） and one auxiliary electrode （AE）. One of the two working electrodes was called the auxiliary working electrode （AWE）, which was directly connected to the ground. Another working electrode was used as a regular working electrode （WE） for electrochemical testing. The reference electrode was set in a frit close to the AWE for potential sampling. The other electrodes, WE, RE and AE, were connected to a conventional potentiostat of three-electrode system for electrochemical measurements. A linear narrow electrochemical cell was designed for setting AE at one end and AWE with RE at another end, and setting WE in between AE and AWE. In this way, a positive feedback potential was generated at the working electrode from the solution resistance and the current flow in the solution. An formal iR compensation over 100%, as high as 500%, had been achieved without potential oscillation. The electrochemical cell design, the principle of the in-cell iR compensation, and the preliminary voltammetric characterization by using the redox reaction of ferrocyanide anions were reported.
基金This study was supported by the Chinese National Key Research and Development Plan(2016YFD0700300-2016YFD0700304)the National Natural Science Foundation of China(31801265).
文摘A soil electrical conductivity(EC)measurement system based on direct digital synthesizer(DDS)and digital oscilloscope was developed.The system took the“current-voltage four-electrode method”as the design principal and adopted a six-pin structure of the probe,two center pins to measure the soil EC in shallow layer,two outside pins to measure the soil EC in deep layer,and two middle pins for inputting the driving current.A signal generating circuit using DDS technology was adopted to generate sine signals,which was connected with the two middle pins.A digital oscilloscope was used to record and store the two soil output signals with noises in microseconds,which were from the two center pins and two outside pins,respectively.Then a digital bandpass filter was used to filter the soil output signals recorded by the digital oscilloscope.Compared with the traditional analog filter circuit,the digital filter could filter out the noises of all frequency except for the frequency of the excitation source.It could improve the effect of filtering and the accuracy of the soil EC measurement system.The DDS circuit could provide more stable sine signals with larger amplitudes.The use of digital oscilloscope enables us to analyze the soil output signals in microseconds and measure the soil EC more accurately.The new soil EC measurement system based on DDS and digital oscilloscope can provide a new effective tool for soil sensing in precision agriculture.
文摘Based on the circuit principle of 1186 Electro Chemical Interface preduced by Solartron Electronic Group Ltd., a precise electro chemical interface (ECI) unit, which can provide the interfacing requirements for the control and measurement of characteristics of electro chemical cell, was developed by means of some essential improvements. Not only can it be used to control and measure the steady and non-steady state characteristics, but also it can be directly connected with Solartron 1170 series or 1250 Frequency Response Analysers (FRA) to measure the AC impedance. Besides,the EC1 can also be connected with two- or three-electrode electro chemical cell systems to test convenlently and correctly their DC and AC characteristics, and used as a four-electrode potentlostat combined with four-electrode electro chernical cell system which contains two reference electrodes (RES) for researches on the electro chemical characteristics of oil-water interface, etc.
