Relaxor ferroelectric single crystals PMNT with the size of φ40 mm×80 mm have been grown by a modified Bridgman method and their ferroelectric and piezoelectric properties have been characterized. The properties...Relaxor ferroelectric single crystals PMNT with the size of φ40 mm×80 mm have been grown by a modified Bridgman method and their ferroelectric and piezoelectric properties have been characterized. The properties varied with the compositions and cut types. On the (001) cut, PMNT76/24 single crystals exhibited a dielectric constant ε of about 3 400, a dielectric loss of tanδ 【0.7%, a piezoelectric constant d33 of 980 pC/N, an electromechanical coupling factor kt of 0.55 and Tc of about 110℃. whereas the properties of PMNT67/33 single crystals on (001) cut were betler: e of about 5 300, tan5 【0.6%, d33 up to 3 000 pC/N, kt 0.64, K33 0.93 and Tc of about 150℃. The piezoelectric properties on other cuts such as (110) and (111) were much lower than those on the (001) cut. The rhombohedral PMNT crystals grown by this method showed more excellent piezoelectric properties than those grown by high temperature solution method and higher value of kt than the rhombohedral PZNT single crystals. it has also展开更多
The Ba（0.96）Ca（0.04）Ti（0.90）Sn（0.10）O3-xNd2 O3（x = 0-0.08%） ceramics were prepared via traditional solid-state sintering method. The influences of Nd3＋ substitution on the phase structure, dielectric proper...The Ba（0.96）Ca（0.04）Ti（0.90）Sn（0.10）O3-xNd2 O3（x = 0-0.08%） ceramics were prepared via traditional solid-state sintering method. The influences of Nd3＋ substitution on the phase structure, dielectric properties,piezoelectric and ferroelectric properties of the ceramics were investigated. All the samples possess pure BaTiO3-type perovskite structure. MPB with orthorhombic and tetragonal phase coexist at around x = 0.03-0.04. Nd^（3＋） doping decreases both Tc and T（O-T） to lower temperature. All the samples exhibit an intermediate state with the coexistence of ferroelectric and diffuse relaxor ferroelectric behavior with the addition of Nd^（3＋）. The electric properties of the ceramics were optimized at x = 0.03 with d33, Kp, εr and Pr values of 545 pC/N, 51.9%, 24,412 and 10.74 μC/cm^2.展开更多
文摘Relaxor ferroelectric single crystals PMNT with the size of φ40 mm×80 mm have been grown by a modified Bridgman method and their ferroelectric and piezoelectric properties have been characterized. The properties varied with the compositions and cut types. On the (001) cut, PMNT76/24 single crystals exhibited a dielectric constant ε of about 3 400, a dielectric loss of tanδ 【0.7%, a piezoelectric constant d33 of 980 pC/N, an electromechanical coupling factor kt of 0.55 and Tc of about 110℃. whereas the properties of PMNT67/33 single crystals on (001) cut were betler: e of about 5 300, tan5 【0.6%, d33 up to 3 000 pC/N, kt 0.64, K33 0.93 and Tc of about 150℃. The piezoelectric properties on other cuts such as (110) and (111) were much lower than those on the (001) cut. The rhombohedral PMNT crystals grown by this method showed more excellent piezoelectric properties than those grown by high temperature solution method and higher value of kt than the rhombohedral PZNT single crystals. it has also
基金supported by the National Natural Science Foundation of China(51702024)Sci-Tech Support Plan-Social Development of Changzhou City(CE20175041)the Priority Academic Program Development of Jiangsu Higher Education Institutions(15KJA43002)
文摘The Ba（0.96）Ca（0.04）Ti（0.90）Sn（0.10）O3-xNd2 O3（x = 0-0.08%） ceramics were prepared via traditional solid-state sintering method. The influences of Nd3＋ substitution on the phase structure, dielectric properties,piezoelectric and ferroelectric properties of the ceramics were investigated. All the samples possess pure BaTiO3-type perovskite structure. MPB with orthorhombic and tetragonal phase coexist at around x = 0.03-0.04. Nd^（3＋） doping decreases both Tc and T（O-T） to lower temperature. All the samples exhibit an intermediate state with the coexistence of ferroelectric and diffuse relaxor ferroelectric behavior with the addition of Nd^（3＋）. The electric properties of the ceramics were optimized at x = 0.03 with d33, Kp, εr and Pr values of 545 pC/N, 51.9%, 24,412 and 10.74 μC/cm^2.
