This paper reports on the photol spectra of ZnSe single crystal with trace chlorine excited by the femtosecond laser pulse. Three emission bands, including second-harmonic-generation, two-photon-excited peak and a bro...This paper reports on the photol spectra of ZnSe single crystal with trace chlorine excited by the femtosecond laser pulse. Three emission bands, including second-harmonic-generation, two-photon-excited peak and a broad band at 500-700nm, were detected. The thermal strain induced by femtosecond pulse strongly influences the photoluminescence of ZnSe crystal. The corresponding strain ~ in ZnSe crystal is estimated to be about 8.8× 10^-3 at room temperature. The zinc-vacancy, as the main point defect induced by femtosecond pulse, is successfully used to interpret the broad emission at 500-700nm. The research shows that self-activated luminescence possesses the recombination mechanism of donor-vacancy pair, and it is also influenced by a few selenium defects and the temperature. The rapid decrease in photol intensity of two-photon-excited fluorescence and second-harmonic generation emission at lower temperature is attributed to the fact that more point defects result in the thermal activation of the two-photo-absorption energy converting to the stronger recombination emission of chlorine-zinc vacancy in 500-700nm. The experimental results indicate that the femtosecond exciting photoluminescence shows a completely different emission mechanism to that of He-Cd exciting luminescence in ZnSe single crystal. The femtosecond laser exhibits a higher sensitive to the impurity in crystal materials, which can be recommended as an efficient way to estimate the trace impurity in high quality crystals.展开更多
基金National Natural Science Foundation of China(50772125,50732002)the Science and Technology Commission of Shanghai Municipality(08JC1420700)National High Technology Research and Development Program of China(2008AA03Z303)
基金Project supported by the National Natural Science Foundation of China （Grant Nos 50502028 and 50336040） and the China Postdoctoral Science Foundation （Grant No 2004036139）.
文摘This paper reports on the photol spectra of ZnSe single crystal with trace chlorine excited by the femtosecond laser pulse. Three emission bands, including second-harmonic-generation, two-photon-excited peak and a broad band at 500-700nm, were detected. The thermal strain induced by femtosecond pulse strongly influences the photoluminescence of ZnSe crystal. The corresponding strain ~ in ZnSe crystal is estimated to be about 8.8× 10^-3 at room temperature. The zinc-vacancy, as the main point defect induced by femtosecond pulse, is successfully used to interpret the broad emission at 500-700nm. The research shows that self-activated luminescence possesses the recombination mechanism of donor-vacancy pair, and it is also influenced by a few selenium defects and the temperature. The rapid decrease in photol intensity of two-photon-excited fluorescence and second-harmonic generation emission at lower temperature is attributed to the fact that more point defects result in the thermal activation of the two-photo-absorption energy converting to the stronger recombination emission of chlorine-zinc vacancy in 500-700nm. The experimental results indicate that the femtosecond exciting photoluminescence shows a completely different emission mechanism to that of He-Cd exciting luminescence in ZnSe single crystal. The femtosecond laser exhibits a higher sensitive to the impurity in crystal materials, which can be recommended as an efficient way to estimate the trace impurity in high quality crystals.
