本文以4-氨基安替吡啉,香草醛和吗啉为原料首次合成了4-氨基安替吡啉缩吗啉香草醛(Q-2),并通过FT-IR、MS、1 H NMR对其结构进行了表征.采用紫外-可见光谱法和荧光猝灭法考察了Q-2与牛血清白蛋白(BSA)的相互作用机理.基于热力学方程计算...本文以4-氨基安替吡啉,香草醛和吗啉为原料首次合成了4-氨基安替吡啉缩吗啉香草醛(Q-2),并通过FT-IR、MS、1 H NMR对其结构进行了表征.采用紫外-可见光谱法和荧光猝灭法考察了Q-2与牛血清白蛋白(BSA)的相互作用机理.基于热力学方程计算出相应的ΔH、ΔG和ΔS值,推断出氢键和范德华力为两者之间作用力的主要类型;并基于Frster非辐射能量转移理论,计算出Q-2与牛血清白蛋白在不同温度下的结合距离;根据Stern-Volmer方程判断其猝灭过程主要为静态猝灭.展开更多
The effect of vanillin and P hydroxybenzoic acid on Chinese fir (Cunninghamia lanceolata) woodland soil and Schima superba woodland soil was studied in pot culture experiment.The results showed that contents of nitrog...The effect of vanillin and P hydroxybenzoic acid on Chinese fir (Cunninghamia lanceolata) woodland soil and Schima superba woodland soil was studied in pot culture experiment.The results showed that contents of nitrogen,potassium and organic matter were lower than the control and their change scope were 21.8%,2.8% and 8.2% respectively.The content of available phosphorus were higher and the change scope was 23.7%.In addition,both changes became more significant with increase of phenolic concentration.These results showed that allelochemicals released by plant may affect content of nutrition in soil,and give rise to nutrition deficiency,and then affect Chinese fir growth.展开更多
文摘本文以4-氨基安替吡啉,香草醛和吗啉为原料首次合成了4-氨基安替吡啉缩吗啉香草醛(Q-2),并通过FT-IR、MS、1 H NMR对其结构进行了表征.采用紫外-可见光谱法和荧光猝灭法考察了Q-2与牛血清白蛋白(BSA)的相互作用机理.基于热力学方程计算出相应的ΔH、ΔG和ΔS值,推断出氢键和范德华力为两者之间作用力的主要类型;并基于Frster非辐射能量转移理论,计算出Q-2与牛血清白蛋白在不同温度下的结合距离;根据Stern-Volmer方程判断其猝灭过程主要为静态猝灭.
文摘The effect of vanillin and P hydroxybenzoic acid on Chinese fir (Cunninghamia lanceolata) woodland soil and Schima superba woodland soil was studied in pot culture experiment.The results showed that contents of nitrogen,potassium and organic matter were lower than the control and their change scope were 21.8%,2.8% and 8.2% respectively.The content of available phosphorus were higher and the change scope was 23.7%.In addition,both changes became more significant with increase of phenolic concentration.These results showed that allelochemicals released by plant may affect content of nutrition in soil,and give rise to nutrition deficiency,and then affect Chinese fir growth.
