The presence of alkali metals in exhaust gas from stationary resources causes a grand challenge for the practical application of selective catalytic reduction(SCR)of NO_(x) with NH_(3).Here,alkali-resistant NO_(x) red...The presence of alkali metals in exhaust gas from stationary resources causes a grand challenge for the practical application of selective catalytic reduction(SCR)of NO_(x) with NH_(3).Here,alkali-resistant NO_(x) reduction has been successfully implemented via tailoring the electron transfer over Fe and V species on FeVO_(4)/TiO_(2)catalysts.The strong interaction between Fe and V induced electron transfer from V to Fe and strengthened the adsorption and activation of NH_(3)and NO over active VO_(x) sites.In the presence of K_(2)O,the strong electron withdrawing effect of Fe offset the electron donating effect of K on the VO_(x) species,thus protecting the active species VO_(x) to maintain the NO_(x) reduction ability.The enhanced adsorption and activation of NH_(3) allowed SCR reaction to proceed via E-R mechanism even after K_(2)O poisoning.This work elucidated the electronic effects on the alkali metals resistance of traditional ferric vanadate SCR catalysts and provided a promising strategy to design SCR catalysts with superior alkali resistance.展开更多
Developing a selective hydrogenation strategy over a low-cost electrocatalyst,especially with an inexpensive and safe hydrogen source for efficient synthesis of aminoareneswith fragile functional groups,is extremely d...Developing a selective hydrogenation strategy over a low-cost electrocatalyst,especially with an inexpensive and safe hydrogen source for efficient synthesis of aminoareneswith fragile functional groups,is extremely desirable.Herein,using H_(2)O as the hydrogen source,Ti mesh-supported Co_(3)S_(4)ultrathin nanosheets with sulfur vacancies(denoted as Co_(3)S_(4−x)NS)have been demonstrated to be a highly efficient cathode for selective transfer hydrogenation of nitroarenes to corresponding aminoarenes at low potential.D_(2)O-labeling experiments confirmed the hydrogen origin.Without sulfur vacancies,the products were a mixture of aminoarenes and azoxyareneswith lowselectivity.This method can deliver a variety of aminoarenes with outstanding selectivity and excellent functional group compatibility with highly reducible groups(e.g.,C–I,C–Br,C=O,C=C,C=N,C≡N,and C≡C).The experimental and theoretical results have revealed that sulfur vacancies can enhance the selective specific adsorption of the nitro group and promote intrinsic activity to form active hydrogen from water electrolysis,thus resulting in high selectivity and outstanding fragile functional groups tolerance.展开更多
This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five...This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five different channel shapes (circle, regular triangle, rectangle, square and hexagon), was investigated to make a comprehensive comparison of their pressure drop, heat transfer Nu number, mass transfer Sh number and N2O conversion. It was found that monolith catalysts have a much lower pressure drop than that of traditional packed bed, and for monolith catalysts with different channel shapes, pressure drop decreases in the order of regular triangle > rectangle > square > hexagon > circle. The order of Nu is in regular triangle > rectangle ≈ square > hexagon > circle, similar to that of Sh. N2O conversion follows the order of regular triangle > rectangular ≈ square ≈ circle > hexagon. The results indicate that chemical reaction including internal diffusion is the controlling step in the selective catalytic reduction of N2O removal with CO. In addition, channel size and gas velocity also have influence on N2O conversion and pressure drop.展开更多
Stretchable electronics have found widespread applications in various fields such as wearable electronics,soft robots,and bioelectronics.As an important promising alternative of traditional rigid conductors,liquid met...Stretchable electronics have found widespread applications in various fields such as wearable electronics,soft robots,and bioelectronics.As an important promising alternative of traditional rigid conductors,liquid metals have demonstrated immense potential to provide high conductivity and stretchability for the stretchable electronic systems.However,limited by their fluidity and high surface tension,challenges remain in achieving liquid metal patterns with low-cost,high-precision,large-scale,and complex geometry.Here,a fabrication technique was proposed based on laser-induced graphene(LIG)stamps to enable liquid metal self-selectively adhere to substrates.Liquid metal patterns could thus be achieved in different designed geometries and could be transferred onto stretchable substrates.The liquid metal patterns exhibit exceptional electrical conductivity(3.24×10^(6)S/m even under 1000%strain),high stretchability(1000%strain,maximum of 2500%),small resistance changes under significant deformations(with a quality factor of 62.5 under 1000%strain),and high resolution(down to 50μm).Utilizing the patterned liquid metals,a stretchable integrated multifunctional optoelectronic system was demonstrated,encompassing a stretchable display matrix,a pressure sensor array,a wireless powering coil,and cardiovascular sensors,which further highlight the remarkable application potential of liquid metals in optoelectronic user-interaction and advanced physiological monitoring.展开更多
The secondary solar heat gain,defined as the heat flows from glazing to indoor environment through longwave radiation and convection,grows with the increasing of glazing absorption.With the rapid development and appli...The secondary solar heat gain,defined as the heat flows from glazing to indoor environment through longwave radiation and convection,grows with the increasing of glazing absorption.With the rapid development and application of spectrally selective glazing,the secondary solar heat gain becomes the main way of glazing heat transfer and biggest proportion,and indicates it should not be simplified calculated conventionally.Therefore,a dynamic secondary solar heat gain model is developed with electrochromic glazing system in this study,taking into account with three key aspects,namely,optical model,heat transfer model,and outdoor radiation spectrum.Compared with the traditional K-Sc model,this new model is verified by on-site experimental measurements with dynamic outdoor spectrum and temperature.The verification results show that the root mean square errors of the interior and exterior glass surface temperature are 3.25°C and 3.33°C,respectively,and the relative error is less than 10.37%.The root mean square error of the secondary heat gain is 13.15 W/m2,and the dynamic maximum relative error is only 13.2%.The simulated and measured results have a good agreement.In addition,the new model is further extended to reveal the variation characteristics of secondary solar heat gain under different application conditions(including orientations,locations,EC film thicknesses and weather conditions).In summary,based on the outdoor spectrum and window spectral characteristics,the new model can accurately calculate the increasing secondary solar heat gain in real time,caused by spectrally selective windows,and will provide a computational basis for the evaluation and development of spectrally selective glazing materials.展开更多
Nitrogen-doped carbon(N-C)materials have demonstrated exceptional performances in activating peroxymonosulfate(PMS)for environmental remediation.However,accommodating higher nitrogen contents remains challenging in N-...Nitrogen-doped carbon(N-C)materials have demonstrated exceptional performances in activating peroxymonosulfate(PMS)for environmental remediation.However,accommodating higher nitrogen contents remains challenging in N-C due to the thermodynamic instability of C-N skeleton.In this study,we proposed an innovative epitaxial growth approach to synthesize two-dimensional N-C nanosheets.Leveraging the abundant amino groups supplied by the polymer dots as growing sites,we successfully attained a high nitrogen level and spontaneously introduced abundant structural defects in the carbon framework.The resulting N-C nanosheets exhibited outstanding catalytic activity for the activation of PMS toward selective oxidation of diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate(1,4-DHP)into diethyl2,6-dimethylpyridine-3,5-dicarboxylate,which serves as a valuable intermediate in the synthesis of various pharmaceutical compounds.Comprehensive experimental and characterization investigations verified that the nitrogen sites and defects are the primary active sites for PMS activation and selective oxidation of 1,4-DHP.This work offered an efficient approach for the fabrication of high-nitrogen-loading carbon materials for catalytic oxidation reactions.展开更多
Based on a mechanism analogous to the serine/threonine ligation, the aspartic acid ligation, which is facilitated by the γ-amino alcohol based ligation and oxidation, is developed and applied to the synthesis of cycl...Based on a mechanism analogous to the serine/threonine ligation, the aspartic acid ligation, which is facilitated by the γ-amino alcohol based ligation and oxidation, is developed and applied to the synthesis of cyclic peptides. The γ-hydroxyl group triggers the ring-chain tautomerization via a 6-endo-trig process,while the δ-hydroxyl group facilitates the oxidative cleavage of the vicinal diol to give carboxylic acid.展开更多
Infrared camouflage based on artificial thermal metasurfaces has recently attracted significant attention.By eliminating thermal radiation differences between the object and the background,it is possible to hide a giv...Infrared camouflage based on artificial thermal metasurfaces has recently attracted significant attention.By eliminating thermal radiation differences between the object and the background,it is possible to hide a given object from infrared detection.Infrared camouflage is an important element that increases the survivability of aircraft and missiles,by reducing target susceptibility to infrared guided threats.Herein,a simple and practicable design is theoretically presented based on a multilayer film for infrared stealth,with distinctive advantages of scalability,flexible fabrication,and structural simplicity.The multilayer medium consists of silicon substrate,carbon layer and zinc sulfide film,the optical properties of which are determined by transfer matrix method.By locally changing the thickness of the coating film,the spatial tunability and continuity in thermal emission are demonstrated.A continuous change of emissive power is further obtained and consequently implemented to achieve thermal camouflage functionality.In addition,other functionalities,like thermal illusion and thermal coding,are demonstrated by thickness-engineered multilayer films.展开更多
Park system planning has been regarded as a systematic, effi cient and rational approach that uses nature to organize and guide the social and spatial development of cities. As an important tool for city planning deve...Park system planning has been regarded as a systematic, effi cient and rational approach that uses nature to organize and guide the social and spatial development of cities. As an important tool for city planning development, it became an international phenomenon fostering international communications, in the meantime promoted individual expressions of nature, and became one of the crucial planning strategies to reshape China's modern cityscape. This paper investigates the diffusion and development of park system planning in Chinese cities during early 20^(th) century. It elucidates the theoretical origins and practical experiments, identifi es the selective and diversifi ed transfer of Western models, and further reveals the insights of transnational urbanism and national identity. The research intends to provide some reference for the planning of park and green space system in contemporary Chinese cities under the background of globalization.展开更多
Folded or nonfolded fluorophores incorporating naphthalene were synthesized and characterized by steady state fluorescence technique.Paraquat as an excellent quenching reagent quenched the fluorescence of Nel6 or nDs(...Folded or nonfolded fluorophores incorporating naphthalene were synthesized and characterized by steady state fluorescence technique.Paraquat as an excellent quenching reagent quenched the fluorescence of Nel6 or nDs(n = 1-4) driven by charge transfer.Under aggregation of nDs,α-CD did not quench the fluorescence of 1D.At lower concentration,the quenching tendency ofα-CD against nDs is 2D>3D>4D,while at higher concentration,the tendency is 2D<3D<4D.α-CD showed the selective recognition on its flu...展开更多
The non-dissociative charge-transfer processes in collisions between O^3＋ and H2 are investigated by using the quantum-mechanical molecular-orbital coupled-channel （QMOCC） method. The adiabatic potentials and radia...The non-dissociative charge-transfer processes in collisions between O^3＋ and H2 are investigated by using the quantum-mechanical molecular-orbital coupled-channel （QMOCC） method. The adiabatic potentials and radial coupling matrix elements utilized in the QMOCC calculations are obtained with the spin-coupled valence-bond approach. Electronic and vibrational state-selective differential cross sections are presented for projectile energies of 0.1, 1.0 and 10.0eV/u in the H2 orientation angles of 45° and 89°. The electronic and the vibrational state-selective differential cross sections show similar behaviours： they decrease as the scattering angle increases, and beyond a specific angle the oscillating structures appear. Moreover, it is also found that the vibrational state-selective differential cross sections are strongly orientation-dependent, which provides a possibility to determine the orientations of molecule H2 by identifying the vibrational state-selective differential scattering processes.展开更多
A transient three-dimensional powder-scale model was established for understanding the flow field and mass transfer within the molten pool during the selective laser melting(SLM)of Inconel 718 alloy by considering som...A transient three-dimensional powder-scale model was established for understanding the flow field and mass transfer within the molten pool during the selective laser melting(SLM)of Inconel 718 alloy by considering some important physical phenomena,such as,a transition from powder to solid,nonlinearities produced by temperature-dependent materials’properties,and fluid flow in the calculation.The influence of laser power or scanning speed on the flow field and cooling rate was discussed in detail.The simulation results reveal that the motion of molten pool and higher cooling rate promote the mass transfer and benefit the solute distribution by increasing laser power.However,with increasing the scanning speed,the melt flow speed and cooling rate are elevated,resulting in an agglomeration of the solute elements,which is ascribed to the shorter dwelling time of liquid.Therefore,the segregation of Nb can be effectively suppressed by increasing laser power or decreasing scanning speed,which can decrease the dwelling time of liquid.展开更多
基金the National Natural Science Foundation of China(No.22125604)Shanghai Rising-Star Program(No.22QA1403700)Chenguang Program supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.22Z00354).
文摘The presence of alkali metals in exhaust gas from stationary resources causes a grand challenge for the practical application of selective catalytic reduction(SCR)of NO_(x) with NH_(3).Here,alkali-resistant NO_(x) reduction has been successfully implemented via tailoring the electron transfer over Fe and V species on FeVO_(4)/TiO_(2)catalysts.The strong interaction between Fe and V induced electron transfer from V to Fe and strengthened the adsorption and activation of NH_(3)and NO over active VO_(x) sites.In the presence of K_(2)O,the strong electron withdrawing effect of Fe offset the electron donating effect of K on the VO_(x) species,thus protecting the active species VO_(x) to maintain the NO_(x) reduction ability.The enhanced adsorption and activation of NH_(3) allowed SCR reaction to proceed via E-R mechanism even after K_(2)O poisoning.This work elucidated the electronic effects on the alkali metals resistance of traditional ferric vanadate SCR catalysts and provided a promising strategy to design SCR catalysts with superior alkali resistance.
基金supported by the National Natural Science Foundation of China(no.21871206).
文摘Developing a selective hydrogenation strategy over a low-cost electrocatalyst,especially with an inexpensive and safe hydrogen source for efficient synthesis of aminoareneswith fragile functional groups,is extremely desirable.Herein,using H_(2)O as the hydrogen source,Ti mesh-supported Co_(3)S_(4)ultrathin nanosheets with sulfur vacancies(denoted as Co_(3)S_(4−x)NS)have been demonstrated to be a highly efficient cathode for selective transfer hydrogenation of nitroarenes to corresponding aminoarenes at low potential.D_(2)O-labeling experiments confirmed the hydrogen origin.Without sulfur vacancies,the products were a mixture of aminoarenes and azoxyareneswith lowselectivity.This method can deliver a variety of aminoarenes with outstanding selectivity and excellent functional group compatibility with highly reducible groups(e.g.,C–I,C–Br,C=O,C=C,C=N,C≡N,and C≡C).The experimental and theoretical results have revealed that sulfur vacancies can enhance the selective specific adsorption of the nitro group and promote intrinsic activity to form active hydrogen from water electrolysis,thus resulting in high selectivity and outstanding fragile functional groups tolerance.
基金Supported by the National Natural Science Foundation of China （21121064, 21076008） the Projects in the National Science ＆ Technology Pillar Program During the 12th Five-Year Plan Period （2011BAC06B04）
文摘This work tries to identify the relationship between geometric configuration of monolith catalysts, and transfer and reaction performances for selective catalytic reduction of N2O with CO. Monolith catalysts with five different channel shapes (circle, regular triangle, rectangle, square and hexagon), was investigated to make a comprehensive comparison of their pressure drop, heat transfer Nu number, mass transfer Sh number and N2O conversion. It was found that monolith catalysts have a much lower pressure drop than that of traditional packed bed, and for monolith catalysts with different channel shapes, pressure drop decreases in the order of regular triangle > rectangle > square > hexagon > circle. The order of Nu is in regular triangle > rectangle ≈ square > hexagon > circle, similar to that of Sh. N2O conversion follows the order of regular triangle > rectangular ≈ square ≈ circle > hexagon. The results indicate that chemical reaction including internal diffusion is the controlling step in the selective catalytic reduction of N2O removal with CO. In addition, channel size and gas velocity also have influence on N2O conversion and pressure drop.
基金supported by the National Natural Science Foundation of China(Nos.62101181,2221001,62090035,52372146,U22A20138,and U19A2090)the National Key Research and Development Program(Nos.2022YFA1204300 and 2022YFA1402501)+4 种基金Natural Science Foundation of Hunan Province(No.2023JJ20016)the Key Program of Science and Technology Department of Hunan Province(Nos.2019XK2001 and 2020XK2001)the Key Research and Development Plan of Hunan Province(No.2023GK2012)the Science and Technology Innovation Program of Hunan Province(No.2021RC3061)the Open Project Program of Key Laboratory of Nanodevices and Applications,Suzhou Institute of Nano-Tech and Nano-Bionics,Chinese Academy of Sciences(No.22ZS01).
文摘Stretchable electronics have found widespread applications in various fields such as wearable electronics,soft robots,and bioelectronics.As an important promising alternative of traditional rigid conductors,liquid metals have demonstrated immense potential to provide high conductivity and stretchability for the stretchable electronic systems.However,limited by their fluidity and high surface tension,challenges remain in achieving liquid metal patterns with low-cost,high-precision,large-scale,and complex geometry.Here,a fabrication technique was proposed based on laser-induced graphene(LIG)stamps to enable liquid metal self-selectively adhere to substrates.Liquid metal patterns could thus be achieved in different designed geometries and could be transferred onto stretchable substrates.The liquid metal patterns exhibit exceptional electrical conductivity(3.24×10^(6)S/m even under 1000%strain),high stretchability(1000%strain,maximum of 2500%),small resistance changes under significant deformations(with a quality factor of 62.5 under 1000%strain),and high resolution(down to 50μm).Utilizing the patterned liquid metals,a stretchable integrated multifunctional optoelectronic system was demonstrated,encompassing a stretchable display matrix,a pressure sensor array,a wireless powering coil,and cardiovascular sensors,which further highlight the remarkable application potential of liquid metals in optoelectronic user-interaction and advanced physiological monitoring.
基金the National Natural Science Foundation of China(51808011)the Natural Science Foundation of Chongqing(2022NSCQ-MSX5521).
文摘The secondary solar heat gain,defined as the heat flows from glazing to indoor environment through longwave radiation and convection,grows with the increasing of glazing absorption.With the rapid development and application of spectrally selective glazing,the secondary solar heat gain becomes the main way of glazing heat transfer and biggest proportion,and indicates it should not be simplified calculated conventionally.Therefore,a dynamic secondary solar heat gain model is developed with electrochromic glazing system in this study,taking into account with three key aspects,namely,optical model,heat transfer model,and outdoor radiation spectrum.Compared with the traditional K-Sc model,this new model is verified by on-site experimental measurements with dynamic outdoor spectrum and temperature.The verification results show that the root mean square errors of the interior and exterior glass surface temperature are 3.25°C and 3.33°C,respectively,and the relative error is less than 10.37%.The root mean square error of the secondary heat gain is 13.15 W/m2,and the dynamic maximum relative error is only 13.2%.The simulated and measured results have a good agreement.In addition,the new model is further extended to reveal the variation characteristics of secondary solar heat gain under different application conditions(including orientations,locations,EC film thicknesses and weather conditions).In summary,based on the outdoor spectrum and window spectral characteristics,the new model can accurately calculate the increasing secondary solar heat gain in real time,caused by spectrally selective windows,and will provide a computational basis for the evaluation and development of spectrally selective glazing materials.
基金the financial support from Australian Research Council under DECRA Scheme(No.DE210100253)merit SXR beamline from Australian Nuclear Science and Technology Organization(ANSTO,No.AS231/SXR/19680)。
文摘Nitrogen-doped carbon(N-C)materials have demonstrated exceptional performances in activating peroxymonosulfate(PMS)for environmental remediation.However,accommodating higher nitrogen contents remains challenging in N-C due to the thermodynamic instability of C-N skeleton.In this study,we proposed an innovative epitaxial growth approach to synthesize two-dimensional N-C nanosheets.Leveraging the abundant amino groups supplied by the polymer dots as growing sites,we successfully attained a high nitrogen level and spontaneously introduced abundant structural defects in the carbon framework.The resulting N-C nanosheets exhibited outstanding catalytic activity for the activation of PMS toward selective oxidation of diethyl 1,4-dihydro-2,6-dimethyl-3,5-pyridinedicarboxylate(1,4-DHP)into diethyl2,6-dimethylpyridine-3,5-dicarboxylate,which serves as a valuable intermediate in the synthesis of various pharmaceutical compounds.Comprehensive experimental and characterization investigations verified that the nitrogen sites and defects are the primary active sites for PMS activation and selective oxidation of 1,4-DHP.This work offered an efficient approach for the fabrication of high-nitrogen-loading carbon materials for catalytic oxidation reactions.
基金supported by the Research Grants Council (Nos. 17309616, C6009-15G) of Hong KongThe National Science Foundation of China (Nos. 21672180, 91753101)the Area of Excellence Scheme of the University of Grants Committee of Hong Kong (No. AoE/P-705/16)
文摘Based on a mechanism analogous to the serine/threonine ligation, the aspartic acid ligation, which is facilitated by the γ-amino alcohol based ligation and oxidation, is developed and applied to the synthesis of cyclic peptides. The γ-hydroxyl group triggers the ring-chain tautomerization via a 6-endo-trig process,while the δ-hydroxyl group facilitates the oxidative cleavage of the vicinal diol to give carboxylic acid.
基金supported by the EIPHI Graduate School(No.ANR-17-EURE-0002)the French Investissements d’Avenir program,project ISITEBFC(No.ANR-15-IDEX-03)+1 种基金the National Natural Science Foundation of China(Nos.12172102,11872160 and 11732002)the support of the Alexander von Humboldt Foundation through the Feodor Lynen Fellowship。
文摘Infrared camouflage based on artificial thermal metasurfaces has recently attracted significant attention.By eliminating thermal radiation differences between the object and the background,it is possible to hide a given object from infrared detection.Infrared camouflage is an important element that increases the survivability of aircraft and missiles,by reducing target susceptibility to infrared guided threats.Herein,a simple and practicable design is theoretically presented based on a multilayer film for infrared stealth,with distinctive advantages of scalability,flexible fabrication,and structural simplicity.The multilayer medium consists of silicon substrate,carbon layer and zinc sulfide film,the optical properties of which are determined by transfer matrix method.By locally changing the thickness of the coating film,the spatial tunability and continuity in thermal emission are demonstrated.A continuous change of emissive power is further obtained and consequently implemented to achieve thermal camouflage functionality.In addition,other functionalities,like thermal illusion and thermal coding,are demonstrated by thickness-engineered multilayer films.
基金Supported by the National Natural Science Foundation(Project No.51478299)
文摘Park system planning has been regarded as a systematic, effi cient and rational approach that uses nature to organize and guide the social and spatial development of cities. As an important tool for city planning development, it became an international phenomenon fostering international communications, in the meantime promoted individual expressions of nature, and became one of the crucial planning strategies to reshape China's modern cityscape. This paper investigates the diffusion and development of park system planning in Chinese cities during early 20^(th) century. It elucidates the theoretical origins and practical experiments, identifi es the selective and diversifi ed transfer of Western models, and further reveals the insights of transnational urbanism and national identity. The research intends to provide some reference for the planning of park and green space system in contemporary Chinese cities under the background of globalization.
基金the Natural Science Foundation of China(No.20172069) for financial support
文摘Folded or nonfolded fluorophores incorporating naphthalene were synthesized and characterized by steady state fluorescence technique.Paraquat as an excellent quenching reagent quenched the fluorescence of Nel6 or nDs(n = 1-4) driven by charge transfer.Under aggregation of nDs,α-CD did not quench the fluorescence of 1D.At lower concentration,the quenching tendency ofα-CD against nDs is 2D>3D>4D,while at higher concentration,the tendency is 2D<3D<4D.α-CD showed the selective recognition on its flu...
基金supported by the National Natural Science Foundation of China (Grant Nos 10574018 and 10574020)
文摘The non-dissociative charge-transfer processes in collisions between O^3＋ and H2 are investigated by using the quantum-mechanical molecular-orbital coupled-channel （QMOCC） method. The adiabatic potentials and radial coupling matrix elements utilized in the QMOCC calculations are obtained with the spin-coupled valence-bond approach. Electronic and vibrational state-selective differential cross sections are presented for projectile energies of 0.1, 1.0 and 10.0eV/u in the H2 orientation angles of 45° and 89°. The electronic and the vibrational state-selective differential cross sections show similar behaviours： they decrease as the scattering angle increases, and beyond a specific angle the oscillating structures appear. Moreover, it is also found that the vibrational state-selective differential cross sections are strongly orientation-dependent, which provides a possibility to determine the orientations of molecule H2 by identifying the vibrational state-selective differential scattering processes.
基金the financial support from the National Natural Science Foundation of China(Nos.51425402 and 51501048)。
文摘A transient three-dimensional powder-scale model was established for understanding the flow field and mass transfer within the molten pool during the selective laser melting(SLM)of Inconel 718 alloy by considering some important physical phenomena,such as,a transition from powder to solid,nonlinearities produced by temperature-dependent materials’properties,and fluid flow in the calculation.The influence of laser power or scanning speed on the flow field and cooling rate was discussed in detail.The simulation results reveal that the motion of molten pool and higher cooling rate promote the mass transfer and benefit the solute distribution by increasing laser power.However,with increasing the scanning speed,the melt flow speed and cooling rate are elevated,resulting in an agglomeration of the solute elements,which is ascribed to the shorter dwelling time of liquid.Therefore,the segregation of Nb can be effectively suppressed by increasing laser power or decreasing scanning speed,which can decrease the dwelling time of liquid.
