The effects of quenching in different ways following solid-solution treatment on properties and precipitation behaviors of7050 alloy were investigated by transmission electron microscopy （TEM）, scanning electron mic...The effects of quenching in different ways following solid-solution treatment on properties and precipitation behaviors of7050 alloy were investigated by transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, selected areaelectron diffraction （SAED）, hardness and electrical conductivity tests. Results show that after quenching in different ways, electricalconductivity of the alloy decreases rapidly in the first 48 h of natural aging. The electrical conductivity of 7050 alloy in natural agingstate is determined by the size and density of GP zones, and the size of GP zones is the main factor. After natural aging for 70 d, thesize of GP zones is 1.8-2.6 nm in matrix of the immersion quenched sample and it is 1.4-1.8 nm in matrix of both water mist andforced air quenched samples. After natural and artificial peak aging, the hardness of the water mist quenched sample is HV 193.6 andits electrical conductivity is 30.5% （IACS） which are both higher than those of the immersion quenched sample. Therefore, watermist quenching is an ideal quenching method for 7050 alloy sheets after solid-solution treatment.展开更多
A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties wer...A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties were highly investigated through ~1H-NMR,UV and PL spectroscopy.The quenching behavior was also investigated,and the results demonstrate that incomplete quenching exists,which is consistent with the cationic poly(p-phenylene vinylene) related copolymer containing bulky phenylene substitutents,prob...展开更多
By taking 40Cr as a specific object, cold extrusion deformation behavior of medium carbon steel after quenching and tempering was studied by experimental works. The influence of deformation extent (10%-50%), cone angl...By taking 40Cr as a specific object, cold extrusion deformation behavior of medium carbon steel after quenching and tempering was studied by experimental works. The influence of deformation extent (10%-50%), cone angle of die (90 °-120 °), hardness after quenching and tempering (HRC21-29) and lubricated condition on the forming load was analyzed. The results show that there is no central bursting and micro crack in the inner of the extruded specimen, and the forming quality is good. The double-peak phenomenon takes place at the front-end of the specimen; the double-peak index increases with deformation extent, and larger deformation can avoid the double-peak phenomenon. The deformation extent is the most important influencing factor, and the lubricated condition almost has no influence, which means that the phosphate coating plus soap process is still a proper lubrication method for cold extrusion of medium carbon steel after quenching and tempering. By investigating the microscopic structure before and after deformation, the initial equiaxed grain is elongated in the extrusion direction, and this feature is more significant at the front-end of specimen.展开更多
基金Project(2016YFB0300801)supported by the National Key Research and Development Program of ChinaProject(51371045)supported by the National Natural Science Foundation of China
文摘The effects of quenching in different ways following solid-solution treatment on properties and precipitation behaviors of7050 alloy were investigated by transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, selected areaelectron diffraction （SAED）, hardness and electrical conductivity tests. Results show that after quenching in different ways, electricalconductivity of the alloy decreases rapidly in the first 48 h of natural aging. The electrical conductivity of 7050 alloy in natural agingstate is determined by the size and density of GP zones, and the size of GP zones is the main factor. After natural aging for 70 d, thesize of GP zones is 1.8-2.6 nm in matrix of the immersion quenched sample and it is 1.4-1.8 nm in matrix of both water mist andforced air quenched samples. After natural and artificial peak aging, the hardness of the water mist quenched sample is HV 193.6 andits electrical conductivity is 30.5% （IACS） which are both higher than those of the immersion quenched sample. Therefore, watermist quenching is an ideal quenching method for 7050 alloy sheets after solid-solution treatment.
基金supported by the National Natural Science Foundation of China(Nos.20774043,20874048)the Fok Ying-Tong Education Foundation(No.111051)+1 种基金the Natural Science Foundation of Jiangsu Province of China(No.BK2008453)the Scientific Research Foundation of Nanjing University of Posts and Telecommunications (NUPT)(Nos.NY207035 and NY207011)
文摘A cationic poly(p-phenylene vinylene) related copolymer without bulky phenylene substitutents attached to the conjugated backbone was prepared through Wittig reaction.The molecular structure and optical properties were highly investigated through ~1H-NMR,UV and PL spectroscopy.The quenching behavior was also investigated,and the results demonstrate that incomplete quenching exists,which is consistent with the cationic poly(p-phenylene vinylene) related copolymer containing bulky phenylene substitutents,prob...
文摘By taking 40Cr as a specific object, cold extrusion deformation behavior of medium carbon steel after quenching and tempering was studied by experimental works. The influence of deformation extent (10%-50%), cone angle of die (90 °-120 °), hardness after quenching and tempering (HRC21-29) and lubricated condition on the forming load was analyzed. The results show that there is no central bursting and micro crack in the inner of the extruded specimen, and the forming quality is good. The double-peak phenomenon takes place at the front-end of the specimen; the double-peak index increases with deformation extent, and larger deformation can avoid the double-peak phenomenon. The deformation extent is the most important influencing factor, and the lubricated condition almost has no influence, which means that the phosphate coating plus soap process is still a proper lubrication method for cold extrusion of medium carbon steel after quenching and tempering. By investigating the microscopic structure before and after deformation, the initial equiaxed grain is elongated in the extrusion direction, and this feature is more significant at the front-end of specimen.
