By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensiona...By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensional nuclear magnetic resonance (2D NMR), the Gulong shale oil in the Songliao Basin was investigated with respect to formation model, pore structure and accumulation mechanism. First, in the Gulong shale, there are a large number of pico-algae, nano-algae and dinoflagellates, which were formed in brackish water environment and constituted the hydrogen-rich oil source materials of shale. Second, most of the oil-generating materials of the Qingshankou Formation shale exist in the form of organo-clay complex. During organic matter thermal evolution, clay minerals had double effects of suppression and catalytic hydrogenation, which expanded shale oil window and increased light hydrocarbon yield. Third, the formation of storage space in the Gulong Shale was related to dissolution and hydrocarbon generation. With the diagenesis, micro-/nano-pores increased, pore diameter decreased and more bedding fractures appeared, which jointly gave rise to the unique reservoir with dual media (i.e. nano-scale pores and micro-scale bedding fractures) in the Gulong shale. Fourth, the micro-/nano-scale oil storage unit in the Gulong shale exhibits independent oil/gas occurrence phase, and shows that all-size pores contain oils, which occur in condensate state in micropores or in oil-gas two phase (or liquid) state in macropores/mesopores. The understanding about Gulong shale oil formation and accumulation mechanism has theoretical and practical significance for advancing continental shale oil exploration in China.展开更多
Cubic shaped CaCO3 particles with mean size of 30-40nm were prepared by intermittent carbonation process without any additives. It was found that the flow rate of CO2 has no distinct influence on the particle size in ...Cubic shaped CaCO3 particles with mean size of 30-40nm were prepared by intermittent carbonation process without any additives. It was found that the flow rate of CO2 has no distinct influence on the particle size in the range of 30 120ml·min^-1 under conditions of 13℃ and stirring rate of 680r·min^-1. A further increase of flow rate makes the particles larger. When CO2 flow rate is 70ml·min^-1, a high agitation rate is in favor of the reduction of the crystal size in the range of 70-680 r·min^-1. When flow rate is 120 ml·min^-1, the particles prepared at agitation rates of 680r·min^-1 and 280r·min^-1 have similar sizes, while products prepared at 90r·min^-1 have larger size.展开更多
The microminiature inertial measurement system, a new style of inertial measurement system, has many advantages compared with traditional systems, such as small size, low mass, low cost, low power consumption, high ...The microminiature inertial measurement system, a new style of inertial measurement system, has many advantages compared with traditional systems, such as small size, low mass, low cost, low power consumption, high bearing capacity, and long life. Undoubtedly, it will have wide applications in military and commercial fields. However, current micro inertial sensors do not have sufficient accuracy, so, its applications are limited to some extent. This paper describes a microminiature inertial measurement system and its design, operating theory and error control techniques. In addition, its performance and applications are evaluated. 展开更多
基金Supported by the Central Guiding Local Science and Technology Development Special Project(ZY20B13)。
文摘By conducting experimental analyses, including thermal pyrolysis, micro-/nano-CT, argon-ion polishing field emission scanning electron microscopy (FE-SEM), confocal laser scanning microscopy (CLSM), and two-dimensional nuclear magnetic resonance (2D NMR), the Gulong shale oil in the Songliao Basin was investigated with respect to formation model, pore structure and accumulation mechanism. First, in the Gulong shale, there are a large number of pico-algae, nano-algae and dinoflagellates, which were formed in brackish water environment and constituted the hydrogen-rich oil source materials of shale. Second, most of the oil-generating materials of the Qingshankou Formation shale exist in the form of organo-clay complex. During organic matter thermal evolution, clay minerals had double effects of suppression and catalytic hydrogenation, which expanded shale oil window and increased light hydrocarbon yield. Third, the formation of storage space in the Gulong Shale was related to dissolution and hydrocarbon generation. With the diagenesis, micro-/nano-pores increased, pore diameter decreased and more bedding fractures appeared, which jointly gave rise to the unique reservoir with dual media (i.e. nano-scale pores and micro-scale bedding fractures) in the Gulong shale. Fourth, the micro-/nano-scale oil storage unit in the Gulong shale exhibits independent oil/gas occurrence phase, and shows that all-size pores contain oils, which occur in condensate state in micropores or in oil-gas two phase (or liquid) state in macropores/mesopores. The understanding about Gulong shale oil formation and accumulation mechanism has theoretical and practical significance for advancing continental shale oil exploration in China.
文摘Cubic shaped CaCO3 particles with mean size of 30-40nm were prepared by intermittent carbonation process without any additives. It was found that the flow rate of CO2 has no distinct influence on the particle size in the range of 30 120ml·min^-1 under conditions of 13℃ and stirring rate of 680r·min^-1. A further increase of flow rate makes the particles larger. When CO2 flow rate is 70ml·min^-1, a high agitation rate is in favor of the reduction of the crystal size in the range of 70-680 r·min^-1. When flow rate is 120 ml·min^-1, the particles prepared at agitation rates of 680r·min^-1 and 280r·min^-1 have similar sizes, while products prepared at 90r·min^-1 have larger size.
基金the Major Research Project of the Ninth-Five Plan (1996 2 0 0 0 ) of China (No.8.7.1.9)
文摘The microminiature inertial measurement system, a new style of inertial measurement system, has many advantages compared with traditional systems, such as small size, low mass, low cost, low power consumption, high bearing capacity, and long life. Undoubtedly, it will have wide applications in military and commercial fields. However, current micro inertial sensors do not have sufficient accuracy, so, its applications are limited to some extent. This paper describes a microminiature inertial measurement system and its design, operating theory and error control techniques. In addition, its performance and applications are evaluated.
