The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and...The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and surface analysis methods. Electrochemical impedance spectroscopy （EIS） of 1Cr18Ni9Ti was measured in the solutions with and without SRB at the culture time of 2, 4, 8 d, respectively. The measurement used two test methods, the nonimmersion electrode method and the immersion electrode method. It was found that the polarization resistance （Rp） of 1Cr18Ni9Ti in the solutions without SRB is the greatest for each test method. When using the nonimmersion electrode method, Rp shifts negatively at first and then positively, and the time constant is only one. Although using the immersion electrode method, the Rp shifts positively at first and then negatively, and the time constant also changes when the biofilm forms. The biofilm observed through SEM is with pores. It was demonstrated that SRB has accelerated corrosion action on 1Cr18Ni9Ti. The protection effect of the biofilm on the electrode depends on the compact degree of the film.展开更多
In order to study the corrosion resistance of extruded magnesium alloys,the Mg-4Zn-2Gd-0.5Ca alloy was extruded at the speed of 0.01-0.1 mm/s with the temperature of 280-360℃in present study.Hot extrusion results sho...In order to study the corrosion resistance of extruded magnesium alloys,the Mg-4Zn-2Gd-0.5Ca alloy was extruded at the speed of 0.01-0.1 mm/s with the temperature of 280-360℃in present study.Hot extrusion results show that the volume fraction of precipitates(Vpre),VDRX(the dynamic recrystallization rate) and the average size of DRXed grain(dDRX) decrease with the decrease in extrusion speed,and the corrosion rate of the alloy also shows a downward trend.On the contrary,the values of Vpre,VDRX and dDRX increase with the increase in extrusion temperature,and the corrosion resistance of Mg-4Zn-2Gd-0.5Ca alloy decreases.When the extrusion speed is 0.01 mm/s and the extrusion temperature is 280℃,the alloy has the best corrosion resistance.The corrosion of extruded Mg-4Zn-2Gd-0.5Ca alloy occurs preferentially on the magnesium matrix around W and I phases in the DRXed zone.With the further corrosion,the corrosion continues to spread along the phase,and the corrosion area gradually increases.Galvanic corrosion plays a leading role in the corrosion process.Moreover,there are a large number of basal plane textures in the unDRXed region,which is conducive to improving the corrosion resistance of magnesium alloys.In addition,the decrease in grain size also makes the corrosion of magnesium alloy more uniform.展开更多
提出了一种预测油脂货架期的电化学阻抗法。在25 m L 1.0×10-3mol/L Li Cl-乙醇支持电解质中,扰动电压5 m V,频率范围5 Hz^600 k Hz,采用常规三电极系统,测量橄榄油和红花籽油的电化学阻抗谱,发现它们和过氧化值均与时间存在一定...提出了一种预测油脂货架期的电化学阻抗法。在25 m L 1.0×10-3mol/L Li Cl-乙醇支持电解质中,扰动电压5 m V,频率范围5 Hz^600 k Hz,采用常规三电极系统,测量橄榄油和红花籽油的电化学阻抗谱,发现它们和过氧化值均与时间存在一定的相互对应关系。在此基础上建立了油脂货架期的预测模型。结果表明,该模型所预测的橄榄油的预测货架期为176~188 d,红花籽油的预测货架期15~18 d。而橄榄油和红花籽油的实际货架期分别为184 d和15 d,均与预测货架期较为接近。本研究所建立的方法具有灵敏、快速、操作简便和省时省样等特点。展开更多
文摘The electrochemical characteristics of 1Cr18Ni9Ti in sulphate-reducing bacteria （SRB） solutions and the biofilm of SRB on the surface of the 1Cr18Ni9Ti electrode were studied by electrochemical, microbiological, and surface analysis methods. Electrochemical impedance spectroscopy （EIS） of 1Cr18Ni9Ti was measured in the solutions with and without SRB at the culture time of 2, 4, 8 d, respectively. The measurement used two test methods, the nonimmersion electrode method and the immersion electrode method. It was found that the polarization resistance （Rp） of 1Cr18Ni9Ti in the solutions without SRB is the greatest for each test method. When using the nonimmersion electrode method, Rp shifts negatively at first and then positively, and the time constant is only one. Although using the immersion electrode method, the Rp shifts positively at first and then negatively, and the time constant also changes when the biofilm forms. The biofilm observed through SEM is with pores. It was demonstrated that SRB has accelerated corrosion action on 1Cr18Ni9Ti. The protection effect of the biofilm on the electrode depends on the compact degree of the film.
基金financially supported by the National Natural Science Foundation of China(Nos.51771128,51771129 and 51201112)the Projects of International Cooperation in Shanxi(No.201703D421039)the Natural Science Foundation of Shanxi(No.201601D011034).
文摘In order to study the corrosion resistance of extruded magnesium alloys,the Mg-4Zn-2Gd-0.5Ca alloy was extruded at the speed of 0.01-0.1 mm/s with the temperature of 280-360℃in present study.Hot extrusion results show that the volume fraction of precipitates(Vpre),VDRX(the dynamic recrystallization rate) and the average size of DRXed grain(dDRX) decrease with the decrease in extrusion speed,and the corrosion rate of the alloy also shows a downward trend.On the contrary,the values of Vpre,VDRX and dDRX increase with the increase in extrusion temperature,and the corrosion resistance of Mg-4Zn-2Gd-0.5Ca alloy decreases.When the extrusion speed is 0.01 mm/s and the extrusion temperature is 280℃,the alloy has the best corrosion resistance.The corrosion of extruded Mg-4Zn-2Gd-0.5Ca alloy occurs preferentially on the magnesium matrix around W and I phases in the DRXed zone.With the further corrosion,the corrosion continues to spread along the phase,and the corrosion area gradually increases.Galvanic corrosion plays a leading role in the corrosion process.Moreover,there are a large number of basal plane textures in the unDRXed region,which is conducive to improving the corrosion resistance of magnesium alloys.In addition,the decrease in grain size also makes the corrosion of magnesium alloy more uniform.
文摘提出了一种预测油脂货架期的电化学阻抗法。在25 m L 1.0×10-3mol/L Li Cl-乙醇支持电解质中,扰动电压5 m V,频率范围5 Hz^600 k Hz,采用常规三电极系统,测量橄榄油和红花籽油的电化学阻抗谱,发现它们和过氧化值均与时间存在一定的相互对应关系。在此基础上建立了油脂货架期的预测模型。结果表明,该模型所预测的橄榄油的预测货架期为176~188 d,红花籽油的预测货架期15~18 d。而橄榄油和红花籽油的实际货架期分别为184 d和15 d,均与预测货架期较为接近。本研究所建立的方法具有灵敏、快速、操作简便和省时省样等特点。
