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Occurrence and risks of pharmaceuticals,personal care products,and endocrine-disrupting compounds in Chinese surface waters 被引量:1
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作者 Yuhang Chen Mengyuan Li +3 位作者 Weichun Gao yinyan guan Zhineng Hao Jingfu Liu 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2024年第12期251-263,共13页
The continuous and rapid increase of chemical pollution in surface waters has become a pressing and widely recognized global concern.As emerging contaminants(ECs)in surface waters,pharmaceutical and personal care prod... The continuous and rapid increase of chemical pollution in surface waters has become a pressing and widely recognized global concern.As emerging contaminants(ECs)in surface waters,pharmaceutical and personal care products(PPCPs),and endocrine-disrupting compounds(EDCs)have attracted considerable attention due to their wide occurrence and potential threat to human health.Therefore,a comprehensive understanding of the occurrence and risks of ECs in Chinese surface waters is urgently required.This study summarizes and assesses the environmental occurrence concentrations and ecological risks of 42 pharmaceuticals,15 personal care products(PCPs),and 20 EDCs frequently detected in Chinese surface waters.The ECs were primarily detected in China’s densely populated and highly industrialized regions.Most detected PPCPs and EDCs had concentrations between ng/L toμg/L,whereas norfloxacin,caffeine,and erythromycin had relatively high contamination levels,even exceeding 2000 ng/L.Risk evaluation based on the risk quotient method revealed that 34 PPCPs and EDCs in Chinese surface waters did not pose a significant risk,whereas 4-nonylphenol,4-tert-octylphenol,17α-ethinyl estradiol,17β-estradiol,and triclocarban did.This review provides a comprehensive summary of the occurrence and associated hazards of typical PPCPs and EDCs in Chinese surface waters over the past decade,and will aid in the regulation and control of these ECs in Chinese surface waters。 展开更多
关键词 Pharmaceuticals and personal care products(PPCPs) Endocrine-disrupting compounds (EDCs) Surface waters OCCURRENCE Risk assessment PRIORITIZATION
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PhGRL2 Protein, Interacting with PhACO1, Is Involved in Flower Senescence in the Petunia 被引量:4
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作者 yinyan Tan Juanxu Liu +6 位作者 Fang Huang, Jiefu guan, Shan Zhong, Na Tang, Ji Zhao, Weiyuan Yang Yixun Yu 《Molecular Plant》 SCIE CAS CSCD 2014年第8期1384-1387,共4页
Dear Editor, The pathways of ethylene biosynthesis and signaling have been studied in detail (Ji and Guo, 2013). Arabidopsis REVERSION-TO-ETHYLENE SENSITIVITY1 (RTE1), interacting with ETR1, and its homologs toma... Dear Editor, The pathways of ethylene biosynthesis and signaling have been studied in detail (Ji and Guo, 2013). Arabidopsis REVERSION-TO-ETHYLENE SENSITIVITY1 (RTE1), interacting with ETR1, and its homologs tomato GREEN RIPE (SlGR) and SlGRL1, and rice OsRTH1 negatively regulate the ethylene signaling (Barry and Giovannoni, 2006, Resnick et al., 2006; Dong et al., 2010; Zhang et al., 2012). A newly published study suggested that a cytochrome b5 and RTE1 are functional partners in promoting ETRl-mediated repression of ethylene signaling in Arabidopsis (Chang et al., 2014). However, AtRTH, RTE1 homolog in Arabidopsis, and its closest homolog in the tomato, SlGRL2 (GR-like2), do not play a role in ethylene signaling (Dong et al., 2010), and the function of the homologs of these members is not well known. 展开更多
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Research progress on vanadium oxides for potassium-ion batteries 被引量:3
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作者 Yuhan Wu guangbo Chen +6 位作者 Xiaonan Wu Lin Li Jinyu Yue yinyan guan Juan Hou Fanian Shi Jiyan Liang 《Journal of Semiconductors》 EI CAS CSCD 2023年第4期46-59,共14页
Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium ox... Potassium-ion batteries(PIBs)have been considered as promising candidates in the post-lithium-ion battery era.Till now,a large number of materials have been used as electrode materials for PIBs,among which vanadium oxides exhibit great potentiality.Vanadium oxides can provide multiple electron transfers during electrochemical reactions because vanadium possesses a variety of oxidation states.Meanwhile,their relatively low cost and superior material,structural,and physicochemical properties endow them with strong competitiveness.Although some inspiring research results have been achieved,many issues and challenges remain to be further addressed.Herein,we systematically summarize the research progress of vanadium oxides for PIBs.Then,feasible improvement strategies for the material properties and electrochemical performance are introduced.Finally,the existing challenges and perspectives are discussed with a view to promoting the development of vanadium oxides and accelerating their practical applications. 展开更多
关键词 potassium-ion batteries vanadium oxides electrode materials electrochemical performance improvement strategies
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组分性质对电极浆料流变行为及成型的影响
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作者 明皓 关银燕 +3 位作者 高瑛俊 刘诗月 高维春 梁吉艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2024年第9期100-107,共8页
以聚合物溶液为分散剂、活性粒子为填充剂配制浆料,应用涂覆法制备电容去离子电极是常用方式。聚合物和粒子等组分对涂层微观结构有不同贡献,电极可呈现强度和性能差异。讨论涂覆成型过程中组分间相互作用有助于结构机制的识别。流变学... 以聚合物溶液为分散剂、活性粒子为填充剂配制浆料,应用涂覆法制备电容去离子电极是常用方式。聚合物和粒子等组分对涂层微观结构有不同贡献,电极可呈现强度和性能差异。讨论涂覆成型过程中组分间相互作用有助于结构机制的识别。流变学可通过宏观流动现象研究浆料内部微观相互作用。文中选用不同链长聚合物和不同粒径填充粒子制备浆料,通过流变分析讨论了剪切条件下组分性质对涂覆成型的影响。结果表明,长链聚合物分子缠结贡献了基体黏度和柔性网络,加工窗口内可容纳更多粒子;短链分子则通过桥接絮凝与粒子形成物理交联网络,相互作用力弱时结构不稳定。微米粒子对调控流变行为和成型更有利,而纳米尺度下发生类凝胶行为逾渗阈值较低,易导致脆性涂层。基于此,提出了涂层电极浆料组分和成型条件选择的流变学方法。 展开更多
关键词 电容去离子 涂层电极 涂覆 流变行为 缠结 桥接絮凝
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悬浮液流变行为对涂层电极成型的影响 被引量:1
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作者 明皓 关银燕 +4 位作者 刘诗月 高瑛俊 高维春 田雪咏 梁吉艳 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2023年第4期110-114,共5页
为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变... 为探究电容去离子电极涂覆成型过程中各组分间的相互作用和微观结构,采用流变学分析手段考察了聚合物黏结剂分子链构型对电极结构的影响,建立通过流动状态识别微观结构的机制,以引导电极成型。结果表明,聚合物链结构显著影响悬浮液流变性质和涂层状态。2种聚合物均可与粒子形成物理交联网络;对于直链聚乙烯醇(PVA),链末端较少,网络的形成依靠桥接絮凝,因此黏度调控窗口较宽,分子内及分子间氢键作用使涂层坚硬,弹性低;而支化的聚乙烯亚胺(PEI),具有丰富的末端基团,与粒子作用所形成物理网络交联密度高,因此悬浮液剪切变稀显著,低分子量时涂层脆易开裂。基于此,提出了涂层电极黏结剂和成型条件选择的流变学方法。 展开更多
关键词 涂层电极 涂覆 流变行为 链结构 黏结剂
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祁连山青海云杉中龄林混交度对细根形态特征的影响 被引量:10
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作者 邓磊 朱春云 +4 位作者 于世川 祁银燕 张文辉 杜盛 关晋宏 《林业科学》 EI CAS CSCD 北大核心 2020年第1期191-200,共10页
【目的】研究青藏高原东部祁连山地区青海云杉中龄林混交度对各土层细根生物量和形态特征的影响,以期为当地森林恢复和林分经营提供理论依据。【方法】选择混交度分别为0、0.2、0.4和0.6的青海云杉天然中龄林样地,调查混交度对0~20和20~... 【目的】研究青藏高原东部祁连山地区青海云杉中龄林混交度对各土层细根生物量和形态特征的影响,以期为当地森林恢复和林分经营提供理论依据。【方法】选择混交度分别为0、0.2、0.4和0.6的青海云杉天然中龄林样地,调查混交度对0~20和20~40 cm土层各树种细根生物量密度、比根长、比表面积、根表面积密度和根长密度的影响。【结果】混交度为0.4的青海云杉林以10~25 cm径级(63.72%)、24~32 m高度级(48.72%)和16~20 m高度级(11.18%)乔木占比最大,且均显著高于其他3个混交度的林分;青海云杉林总细根生物量密度主要分布在0~20 cm土层,占细根总量的68.31%~83.49%,其数值随混交度增大呈现先升后降趋势,混交度0.4时最大,为616.26 g·m^-3;20~40 cm土层总细根生物量密度随混交度增大而增大,在混交度0.6时最大,为227.17g·m^-3;在0~20 cm土层,细根根长密度和根表面积密度表现为混交度0.4>混交度0.2>混交度0>混交度0.6,比根长和比表面积表现为混交度0.4>混交度0.2>混交度0.6>混交度0;在20~40 cm土层,根长密度、根表面积密度和比根长均表现为混交度0.6>混交度0.4>混交度0.2>混交度0,比表面积表现为混交度0.6>混交度0.2>混交度0.4>混交度0;随混交度增大,云杉对0~40 cm土层林分细根生物量密度、比根长、比表面积、根表面积密度和根长密度的贡献逐渐减小,而白桦对0~40 cm土层林分细根生物量密度、比根长、比表面积、根表面积密度和根长密度的贡献持续增大;混交度对细根根长密度和根表面积密度的影响主要表现在0~1 mm径级细根上。【结论】与其他混交度林分相比,混交度为0.4的青海云杉中龄林具有更合理的径级结构和高度级结构,异龄、复层的林分结构可以减小相邻植株间生态位竞争重叠范围,优化林分空间利用效率,提高群落稳定性,细根生物量密度及细根形态特征如比根长、比表面积、� 展开更多
关键词 混交度 青海云杉中龄林 林分结构 细根 分布 生物量 形态特征
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