The preparation and formation mechanism of silica/polyvinylpyrrolidone(PVP)-polyacrylonitrile(PAN) coaxial nanofibers were presented in this paper. The PVP-PAN composite nanofibers were obtained via an electrospin...The preparation and formation mechanism of silica/polyvinylpyrrolidone(PVP)-polyacrylonitrile(PAN) coaxial nanofibers were presented in this paper. The PVP-PAN composite nanofibers were obtained via an electrospinning technique, while SiO2 nanoparticles were prepared according to a Stber method. The measurements of water contact angle(WCA), the compared results of silica coating PVP-PAN composite nanofibers with PAN nanofibers indicate that much PVP resided on the composite nanofiber surface, which results in the occurrence of SiO2@polymer coaxial nanofibers due to the formation of hydrogen bonding between silica and composite nanofibers and subsequent adsorption of silica on the fiber surface.展开更多
文摘The preparation and formation mechanism of silica/polyvinylpyrrolidone(PVP)-polyacrylonitrile(PAN) coaxial nanofibers were presented in this paper. The PVP-PAN composite nanofibers were obtained via an electrospinning technique, while SiO2 nanoparticles were prepared according to a Stber method. The measurements of water contact angle(WCA), the compared results of silica coating PVP-PAN composite nanofibers with PAN nanofibers indicate that much PVP resided on the composite nanofiber surface, which results in the occurrence of SiO2@polymer coaxial nanofibers due to the formation of hydrogen bonding between silica and composite nanofibers and subsequent adsorption of silica on the fiber surface.