Host-guest supramolecular interactions, which exist widely between diverse metal cations and polyoxometalate(POM) anions, have always been utilized to construct metal-organic frameworks(MOF) /POMs bulk composites. Act...Host-guest supramolecular interactions, which exist widely between diverse metal cations and polyoxometalate(POM) anions, have always been utilized to construct metal-organic frameworks(MOF) /POMs bulk composites. Actually, the interactions can also be found application in realizing shape-controlled synthesis of MOF nanocrystals(NCs). In this context, simply by introducing Keggin-type POMs into MOF precursors, various uniform [Cu3(BTC)2]n(BTC = benzene-1,3,5-tricarboxylate) NCs, including(truncated) octahedrons, hollow hierarchical spheres and octahedrons, are fabricated. Besides, such reaction system can be applied to construct noble metal@MOF nanocomposite, which significantly enhances the catalytic performance of the noble metal.展开更多
基金supported by the National Natural Science Foundation of China(21431003,91127040 and 21221062)the State Key Project of Fundamental Research for Nanoscience and Nanotechnology(2011CB932402)
文摘Host-guest supramolecular interactions, which exist widely between diverse metal cations and polyoxometalate(POM) anions, have always been utilized to construct metal-organic frameworks(MOF) /POMs bulk composites. Actually, the interactions can also be found application in realizing shape-controlled synthesis of MOF nanocrystals(NCs). In this context, simply by introducing Keggin-type POMs into MOF precursors, various uniform [Cu3(BTC)2]n(BTC = benzene-1,3,5-tricarboxylate) NCs, including(truncated) octahedrons, hollow hierarchical spheres and octahedrons, are fabricated. Besides, such reaction system can be applied to construct noble metal@MOF nanocomposite, which significantly enhances the catalytic performance of the noble metal.
