Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and e...Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and electronic spectra.The anti-bacterium activity of the complexes were tested.展开更多
The new solid complexes [LnL2(NO3)2]NO3 (L=C18H23NO2, N-2-hydroxy-3-me thoxy-benzaldehyde-1-aminoadamanantane, Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, H o, Er, Tm, Yb, Lu, Y) of rare earth nitrates with Schiff base der...The new solid complexes [LnL2(NO3)2]NO3 (L=C18H23NO2, N-2-hydroxy-3-me thoxy-benzaldehyde-1-aminoadamanantane, Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, H o, Er, Tm, Yb, Lu, Y) of rare earth nitrates with Schiff base derived from o-van illin and adamantaneamine have been synthesized in non-aqueous system and charac terized by elemental analysis, molar conductance, infrared spectra, 1H NMR spect ra, thermal analysis. The coordination modes of the bonding in these complexes w ere discussed and the possible structure were proposed. Every central Ln(III) io n in the complexes coordinates with both two Schiff base ligands via four oxygen atoms of the phenol hydroxy groups and methoxy groups and two nitrates via thei r four oxygen atoms. Their coordination numbers are eight. In addition, the anti bacterial activity of the Schiff base ligand and the complexes were studied.展开更多
文摘Nickel(Ⅱ),Copper(Ⅱ),Zinc(Ⅱ),and Cadmium(Ⅱ)complexes derived from schiff base of N-Salicylidenelysine acid were synthesized.These complexes were characterized by elemental analysis,conductivity measurement,IR and electronic spectra.The anti-bacterium activity of the complexes were tested.
文摘The new solid complexes [LnL2(NO3)2]NO3 (L=C18H23NO2, N-2-hydroxy-3-me thoxy-benzaldehyde-1-aminoadamanantane, Ln=La, Ce, Pr, Nd, Sm, Eu, Gd, Tb, Dy, H o, Er, Tm, Yb, Lu, Y) of rare earth nitrates with Schiff base derived from o-van illin and adamantaneamine have been synthesized in non-aqueous system and charac terized by elemental analysis, molar conductance, infrared spectra, 1H NMR spect ra, thermal analysis. The coordination modes of the bonding in these complexes w ere discussed and the possible structure were proposed. Every central Ln(III) io n in the complexes coordinates with both two Schiff base ligands via four oxygen atoms of the phenol hydroxy groups and methoxy groups and two nitrates via thei r four oxygen atoms. Their coordination numbers are eight. In addition, the anti bacterial activity of the Schiff base ligand and the complexes were studied.
