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Mortar-Pestle and Microwave Assisted Regioselective Nitration of Aromatic Compounds in Presence of Certain Group V and VI Metal Salts under Solvent Free Conditions 被引量：1

Mortar-Pestle and Microwave Assisted Regioselective Nitration of Aromatic Compounds in Presence of Certain Group V and VI Metal Salts under Solvent Free Conditions

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摘要 Solvent – free Mortar-pestle (grinding) and microwave-assisted nitration reactions (MWANR’s) underwent smoothly in the presence of group V and VI metal salts with high regio-selectivity for anilides, moderately- and non-activated aro-matic compounds. The reactions were conducted under solvent-free conditions, which afforded good to excellent yields. The observed reaction times in MW assisted conditions are in the range of only few minutes. Solvent – free Mortar-pestle (grinding) and microwave-assisted nitration reactions (MWANR’s) underwent smoothly in the presence of group V and VI metal salts with high regio-selectivity for anilides, moderately- and non-activated aro-matic compounds. The reactions were conducted under solvent-free conditions, which afforded good to excellent yields. The observed reaction times in MW assisted conditions are in the range of only few minutes.

作者 Sariah Sana Kancharla Rajendar Reddy Kamatala Chinna Rajanna Marri Venkateswarlu Mir Moazzam Ali

机构地区 Department of Chemistry

出处《International Journal of Organic Chemistry》 2012年第3期233-247,共15页 有机化学国际期刊（英文）

关键词 NITRATION Mortar-Pestle Microwave-Assisted NITRATION Ammonium MOLYBDATE Potassium CHROMATE So-dium TUNGSTATE Bismuth Nitrate Sodium BISMUTHATE Nitration Mortar-Pestle Microwave-Assisted Nitration Ammonium Molybdate Potassium Chromate So-dium Tungstate Bismuth Nitrate Sodium Bismuthate

分类号 O6 [理学—化学]

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International Journal of Organic Chemistry

2012年第3期

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