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Ionic Liquid Solvent Based on Cyclic Guanidinium Cation for Nucleophilic Displacement Reactions 被引量:1

Ionic Liquid Solvent Based on Cyclic Guanidinium Cation for Nucleophilic Displacement Reactions
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摘要 The nucleophilic displacement reaction of n-bromooctane and potassium iodide in ionic liquid based on cyclic guanidinium cation(2) was investigated. The kinetic reasult shows that the rate of the reaction is enhanced in ionic liquid (2). The same reaction in [bmim][PF6](1)(where bmim=1-butyl-3-methylimidazolium) was also studied. It was found that as a reaction medium ionic liquid (2) is better than (1) for nucelophilic displacement reactions. The nucleophilic displacement reaction of n-bromooctane and potassium iodide in ionic liquid based on cyclic guanidinium cation(2) was investigated. The kinetic reasult shows that the rate of the reaction is enhanced in ionic liquid (2). The same reaction in [bmim][PF6](1)(where bmim=1-butyl-3-methylimidazolium) was also studied. It was found that as a reaction medium ionic liquid (2) is better than (1) for nucelophilic displacement reactions.
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2004年第1期46-49,共4页 高等学校化学研究(英文版)
关键词 Ionic liquid Cyclic guanidinium NUCLEOPHILICITY Ionic liquid, Cyclic guanidinium, Nucleophilicity
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