摘要
The crystal and molecular structure of ·(ClO4)2 has been determine d by X-ray crystallography. It crystallizes in the monoclinic, space group P21/ c, with lattice parameters a=0.63270(9)nm, b=2.4264(2)nm, c=1.2128(1)nm, β=92.7 21(9)°, V=1.8597(3)nm3, Z=4, Dc=1.835Mg·m-3, F(000)=1032, μ=1.591mm-1. The molecule is built up of centro-symmetric dimeric entities, in which the four-m embered Ag2S2 ring is planar and the angle of S(3)-Ag(1)-S(3A) is 107.70(2)°f or symmetry requirements. The silver atoms have slightly distorted tetrahedral c oordination environment, and the sulfur atoms of the ETU group occupy four coord ination sites. The two percholate anions in general position balance the charge. In the solid state, the title compound forms three dimensional network structur es through hydrogen bonds. The intermolecular hydrogen bonds and extensive inter molecular interaction connect the 2+ion and two ClO4-anions to cont ribute to the stability of the structure. CCDC: 208731.
The crystal and molecular structure of ·(ClO4)2 has been determine d by X-ray crystallography. It crystallizes in the monoclinic, space group P21/ c, with lattice parameters a=0.63270(9)nm, b=2.4264(2)nm, c=1.2128(1)nm, β=92.7 21(9)°, V=1.8597(3)nm3, Z=4, Dc=1.835Mg·m-3, F(000)=1032, μ=1.591mm-1. The molecule is built up of centro-symmetric dimeric entities, in which the four-m embered Ag2S2 ring is planar and the angle of S(3)-Ag(1)-S(3A) is 107.70(2)°f or symmetry requirements. The silver atoms have slightly distorted tetrahedral c oordination environment, and the sulfur atoms of the ETU group occupy four coord ination sites. The two percholate anions in general position balance the charge. In the solid state, the title compound forms three dimensional network structur es through hydrogen bonds. The intermolecular hydrogen bonds and extensive inter molecular interaction connect the 2+ion and two ClO4-anions to cont ribute to the stability of the structure. CCDC: 208731.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第9期979-982,共4页
Chinese Journal of Inorganic Chemistry
基金
山东省自然科学基金资助项目(No.Y2002B06)。
