期刊文献+

PEMFC电催化剂利用率研究方法的探讨 被引量:1

Discussion of Research Method on Degree of Electro-Catalyst Utilization in PEMFC
下载PDF
导出
摘要 提高电催化剂的利用率以降低质子交换膜燃料电池(PEMFC)的成本,是加速其商业化的一个重要途径.文中讨论了现有的CV法在研究PEMFC电催化剂利用率时存在的一些问题,如CV法扫描速度的影响及Pt理论比表面积难于准确确定等.为了较好地解决这一问题,提出了一种以单位质量电催化剂产生电池功率或电能来表示膜电极中电催化剂利用率的方法. Reducing the cost of proton exchange membrane fuel cell (PEMFC) by increasing the utilization ratio of electro-catalyst is one of the important approaches to the acceleration of its business processes. Some problems, such as the influence of cyclic voltammeter scanning rate cyclic voltammeter, the difficulty in defining Pt theoretieal specific surface area, etc, in the research of the utilization ratio of PEMFC electro-catalyst, are discussed by using the existing CV method. In order to solve the problems, the utilization ratio of electro-catalyst in membrane electrode assembly (MEA) expressed by cell power or electric power produced by per unit mass (electro-)catalyst, is brought forward.
出处 《天津大学学报(自然科学与工程技术版)》 EI CAS CSCD 北大核心 2004年第1期19-22,共4页 Journal of Tianjin University:Science and Technology
基金 天津市重点攻关资助项目(003100911).
关键词 PEMFC电催化剂 利用率 质子交换膜燃料电池 循环伏安法 电池功率 proton exchange membrane fuel cell electro-catalyst utilization ratio cyclic voltammeter method
  • 相关文献

参考文献15

二级参考文献20

  • 1陈延禧.聚合物电解质燃料电池的研究进展[J].电源技术,1996,20(1):21-27. 被引量:37
  • 2[1] PRATER K. The renaissance of the solid polymer fuel cell [J]. J Power sources, 1990,29:239~250. 被引量:1
  • 3[2] TICIANELLI E A, DEROUIN C R, SRINIVASAN S. Loca-lization of platinum in low catalyst loading electrodes to attain high power densities in SPE fuel cell [J]. J Electroanal Chem, 1988,251:275-295. 被引量:1
  • 4[3] SRINIVASAN S, VELEV O A, PARTHASARATHY A, et al. High energy efficiency and high power density proton exchange membrane fuel cells-electrode kinetics and mass transport [J]. J Power Sources, 1991,36:299-320. 被引量:1
  • 5[4] WILSON M S, GOTTESFELD S. Thin-film catalyst layers for polymer electrolyte fuel cell electrodes [J]. J Appl Electrochem, 1992,22:1-7. 被引量:1
  • 6[5] SASI KUMAR G, RAJA M, PARTHASARATHY S. High performance electrodes with very low platinum loading for polymer electrolyte fuel cells [J]. Electrochimica Acta, 1995,40:285. 被引量:1
  • 7司永超,第二十二届全国化学与物理电源年会论文集,1996年 被引量:1
  • 8周利荣,硕士学位论文,1996年 被引量:1
  • 9Liu R,J Electrochem Soc,1992年,139卷,15页 被引量:1
  • 10陈延禧,反应工程(第2版),1999年 被引量:1

共引文献39

同被引文献12

  • 1朱科,单忠强,张继炎,陈延禧.用EIS研究PEMFC膜电极的运行条件对其性能的影响[J].天津大学学报,2006,39(5):592-596. 被引量:2
  • 2Nedjib Djilali,Dong Minglu.Influence of heat transfer on gas and water transport in fuel cells[J].International Journal of Thermal Sciences,2002,41 (1):29-40. 被引量:1
  • 3Sridhar P,Perumal R,Rajalakshmi N,et al.Humidification studies on polymer electrolyte membrane fuel cell[J].Journal of Power Sources,2001,101 (1):72-78. 被引量:1
  • 4Gamburzev Sergei,Appleby A J.Recent progress in performance improvement of the proton exchange membrane fuel cell (PEMFC)[J].Journal of Power Sources,2002,107(1):5-12. 被引量:1
  • 5Hyun Duksu,Kim Junbom.Study of external humidification method in proton exchange membrane fuel cell[J].Journal of Power Sources,2004,126 (1/2):98-103. 被引量:1
  • 6Hwang J J,Hwang H S.Parametric studies of a double-cell stack of PEMFC using GrafoilTM flow-field plates[J].Journal of Power Sources,2002,104(1):24-32. 被引量:1
  • 7Hsieh Shou-Shing,Yang Sheng-Huang,Kuo Jenn-Kun,et al.Study of operational parameters on the performance of micro PEMFCs with different flow fields[J].Energy Conversion and Management,2006,47(13/14):1868-1878. 被引量:1
  • 8Williams M V,Kunz H R,Fenton J M.Operation of Nafion(R)-based PEM fuel cells with no external humidification:Influence of operating conditions and gas diffusion layers[J].Journal of Power Sources,2004,135 (1/2):122-134. 被引量:1
  • 9Santarelli M G,Torchio M F.Experimental analysis of the effects of the operating variables on the performace of a single PEMFC[J].Energy Conversion and Management,2007,48(1):40-51. 被引量:1
  • 10Sohn Young-Jun,Park Gu-Gon,Yang Tae-Hyun,et al.Operating characteristics of an air-cooling PEMFC for portable applications[J].Journal of Power Sources,2005,145 (2):604-609. 被引量:1

引证文献1

二级引证文献20

相关作者

内容加载中请稍等...

相关机构

内容加载中请稍等...

相关主题

内容加载中请稍等...

浏览历史

内容加载中请稍等...
;
使用帮助 返回顶部