摘要
报道了癸二酰异羟肟酸及其Cu( ),Co( ),Ni( )和Zn( )金属配合物的合成,利用红外光谱进行了结构推测.对配体进行量化计算的结果表明,羰基氧、羟基氧是可能的配位原子,与结构推测结果相吻合.
The ligand of sebacoyl hydroxamic acid and its Cu(Ⅱ), Co(Ⅱ), Ni(Ⅱ) and Zn(Ⅱ) complexes have been synthesized and characterized by IR spectra. The results of the quantum chemistry calculation of the ligand indicate that the carbonyl and hydroxyl oxygen atoms maybe coordinate to the metal atom, which is consistent with the conjecture by IR.
出处
《天津师范大学学报（自然科学版）》
CAS
2003年第4期16-18,26,共4页
Journal of Tianjin Normal University：Natural Science Edition
基金
天津市自然科学基金资助项目(003601711)
关键词
癸二酰异羟肟酸
金属配合物
合成
量化计算
sebacoyl hydroxamic acid
complex
synthesis
quantum chemistry calculation
