摘要
A pilot-scale apparatus for continuous supercritical and near-critical water reaction was set up. A high-pressure slurry supplying system was developed to feed the solid material-water slurries. The apparatus features temperature up to 600℃, pressure up to 40MPa, residence time from 24s to 15min, maximum amount of slurry supply of 2.4 L·h-1, maximum solid content of slurry up to 10%(by mass) for cellulose from Merck, and resistance to corrosion. Long-time runs of decomposition of cellulose were carried out and steady runs were confirmed. Kinetics of cellulose decomposition was studied. The apparent activation energy evaluated was 147kJ·mol-1. In addition, a new three-step pathway for cellulose hydrolysis was proposed. The derived kinetic equation is in good agreement with the experimental data.
A pilot-scale apparatus for continuous supercritical and near-critical water reaction was set up. A high-pressure slurry supplying system was developed to feed the solid material-water slurries. The apparatus features temperature up to 600℃, pressure up to 40MPa, residence time from 24s to 15rain, maximum amount of slurrysupply of 2.4 L·h^-1, maximum solid content of slurry up to 10%(by mass) for cellulose from Merck, and resistance to corrosion. Long-time runs of decomposition of cellulose were carried out and steady runs were confirmed. Kinetics of cellulose decomposition was studied. The apparent activation energy evaluated was 147kJ·mo1^-1. In addition,a new three-step pathway for cellulose hydrolysis was proposed. The derived kinetic equation is in good agreement with the experimental data.
基金
Partly supported by Research for Future Program"Integrated field 5,causes and effects of environmental loading and its reduction",the Japan Society for the Promotion of Science(JSPS).
