摘要
苄基锡化合物因其具有丰富的反应性、结构特征及抗癌活性而引起人们的兴趣[1-4],最近我们合成了一系列的卤代苄基锡化合物,并报导了它们的晶体结构[4-9].
The n-butyl alcohol solution of p-cyanobenzyl chloride and Sn was heated at reflux for 6h to yield the tri(p-cyanobenzyl) tin chloride. The crystal and molecular structures of compound was determined by X-ray diffraction. The crystal is triclinic, space group P (1) over bar with a = 0.9706(3) nm, b = 0.9882(3) nm, c = 1.3916(4) nm, V = 1.1081nm(3), Z = 1, D-x = 1.506Mg (.) m(-3), mu(MoKalpha) = 12.88cm(-1), F(000) = 500. R-1 = 0.0320, wR(2) = 0.0695. The bond lengths of Sn-C is 0.2152 similar to 0.2164nm. The Sn-Cl is 0.24088nm. The tin atom has a distorted, tetrahedral geometry. CCDC: 211279.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
2003年第10期1109-1112,共4页
Chinese Journal of Inorganic Chemistry
基金
湖南省自然科学基金(No.00JJY2010
02JJY3005)
湖南省教育厅(No.02C135
02C137)资助项目
