摘要
反相微乳液聚合是一种新的聚合方法,其动力学和机理是许多学者研究和关注的热点。通过对比各方面研究者得出的动力学表达式及研究结论,详细介绍和分析了单体、引发剂、乳化剂、油相等因素对反相微乳液聚合反应速率、聚合物平均相对分子质量的影响;评述了各种对于反相微乳液聚合动力学及聚合机理的研究状况;介绍了反相微乳液聚合动力学数学模型的发展状况;并对今后反相微乳液聚合的研究提出了一些建议。
Inverse microemulsion polymerization is a novel polymerization process for which the kinetics and mechanisms were focused by scholars in this field.In the system of inverse microemulsion,the effect of concentration and kinds of monomer,initiator,emulsifier,oil phase and electrolyte on the polymerization rate and the average molecular weight of polymer were discussed. Through comparison of various reports on kinetic expression and their conclusion,the kinetics and mechanisms of inverse microemulsion polymerization were reviewed.Development status of mathematics model for inverse microemulsion polymerization were introduced.Some suggestions about inverse microemulsion polymerization were proposed for further study.
出处
《日用化学工业》
CAS
CSCD
北大核心
2003年第5期309-312,320,共5页
China Surfactant Detergent & Cosmetics
基金
山西省青年基金资助项目(20031018)
关键词
反相微乳液
聚合
动力学
研究进展
机理
inverse microemulsion
polymerization
mechanism
kinetic
factor
