摘要
The highly excited vibrational states of quasi-linear tetraatomic molecule HCNO are studied in the framework of U(4) algebra. By using symmetric group with which the tetraatomic molecules satisfy, we construct the algebraic Hamiltonian that not only includes Majorana operator M 12 but also M 13 and M 23 which are very useful for getting potential energy surface and force constants in Lie algebra method. And the eigenvalue of the Hamiltonian are obtained by Lie algebra treatment.
The highly excited vibrational states of quasi-linear tetraatomic molecule HCNO are studied in the framework of U(4) algebra. By using symmetric group with which the tetraatomic molecules satisfy, we construct the algebraic Hamiltonian that not only includes Majorana operator M 12 but also M 13 and M 23 which are very useful for getting potential energy surface and force constants in Lie algebra method. And the eigenvalue of the Hamiltonian are obtained by Lie algebra treatment.
出处
《高等学校化学学报》
SCIE
EI
CAS
CSCD
北大核心
2003年第7期1299-1301,共3页
Chemical Journal of Chinese Universities
基金
国家自然科学基金 (批准号 :2 0 1730 31
2 9892 16 8)
山东省自然科学基金 (批准号 :Y99B0 4)资助
