摘要
A preparation method of glutaraldehyde by one step oxidation of cyclopentene with peroxyformic acid is reported. The preparation is carried out in a mild reaction condition, time saving and without catalyst. The product is identified by MS and IR measurements. The results showed that the highest yield of glutaraldehyde 56 7% is obtained at optimum molar ratio of n (hydrogen peroxide)∶ n (cyclopentene)∶ n (formic acid)=1∶3∶3, reaction temperature 35 ℃ and reaction time 1 h.
A preparation method of glutaraldehyde by one step oxidation of cyclopentene with peroxyformic acid is reported. The preparation is carried out in a mild reaction condition, time saving and without catalyst. The product is identified by MS and IR measurements. The results showed that the highest yield of glutaraldehyde 56 7% is obtained at optimum molar ratio of n (hydrogen peroxide)∶ n (cyclopentene)∶ n (formic acid)=1∶3∶3, reaction temperature 35 ℃ and reaction time 1 h.
出处
《应用化学》
CAS
CSCD
北大核心
2003年第6期600-602,共3页
Chinese Journal of Applied Chemistry
基金
中国科学院领域前沿 ( 2 0 0 2年创新基金 )资助项目
关键词
甲酸
过氧化氢
戊二醛
glutaraldehyde,cyclopentene,formic acid
