摘要
化合物[Co(bdpp)(NO3)2](bdpp=二(3,5-二甲基吡唑)丙烷)是在乙醇溶液中通过Co(NO3)2.2H2O和bdpp反应制备而成。钴离子与一个二(3,5-二甲基吡唑)丙烷和两个硝酸根离子配位形成扭曲的四面体构型。其键长和键角与同类化合物有较大差异。
The complex [Co(bdpp)(NO3)2] was obtained from a reaction of Co(NO3)2.2H2O and bdpp [bdpp=1,3-bis(3’,5’-dimethylpyrazol-10-yl)propane)] in ethanol solution.The Co(II) ion is coordinated by one bdpp and two oxygen to form a distorted tetrahedral conformation,which the bond distances and bond angles are difference obviously from the similar compounds.
出处
《井冈山大学学报（自然科学版）》
2009年第2期20-21,33,共3页
Journal of Jinggangshan University (Natural Science)
关键词
晶体结构
吡啶型氮原子
吡咯型氮原子
crystal structure
pyridine-type nitrogen
pyrrole-type nitrogen
