摘要
本文研究了使用色谱柱内固定液的浓度按正弦函数关系变化,使平均涂渍色谱柱程序化,从而使组分在色谱柱内热力学和动力学行为随之变化,以期达到缩短分析时间和提高柱效能等目的,并对正弦函数涂渍规律的理论和实践问题进行了初步探讨。编制了BASIC程序,用计算机求得柱结构参数。
The gradient effect on the sine-shaped gradient loaded GC column is investigated. The theoretical equation is derived and the computer programme is given. The gradient effect and corresponding configuration of a gradient column can be calculated by computer, Theoretical and practical problems concerned with the sine-shaped gradient loaded column are discussed, The practical result shows that the gradient effects of the column on retention time and column efficiency are satisfactory.
出处
《分析化学》
SCIE
EI
CAS
CSCD
北大核心
1992年第12期1382-1388,共7页
Chinese Journal of Analytical Chemistry
