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The Standard Association Constant of Ion Pair [GaCl]^(2+)in the System of HCl+GaCl_3+H_2O

The Standard Association Constant of Ion Pair [GaCl]^(2+)in the System of HCl+GaCl_3+H_2O
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摘要 The standard association constants of ionic pair [GaCl]2+, Kas, were determined by emf(electromotive force) method at 278.15 to 318.15 K. The thermodynamic quantities for the ionic association process were calculated and it was pointed that the association entropy is driving force to form the ionic pair. The standard association constants of ionic pair [GaCl]2+, Kas, were determined by emf(electromotive force) method at 278.15 to 318.15 K. The thermodynamic quantities for the ionic association process were calculated and it was pointed that the association entropy is driving force to form the ionic pair.
出处 《Chinese Chemical Letters》 SCIE CAS CSCD 2002年第5期442-443,共2页 中国化学快报(英文版)
关键词 Ion pair association entropy EMF GaCl3. Ion pair association entropy EMF GaCl3.
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