摘要
用静态增重法研究了K35镍基铸造高温合金的800℃氧化动力学·结果表明,K35合金的氧化动力学遵循抛物线规律,属于完全抗氧化级·利用X射线衍射、扫描电镜和能谱分析确定K35合金氧化膜组成以Cr2O3为主,含有NiCr2O4及TiO·TiO2·由于钛氧化物的存在,在高温氧化期间,K35合金发生了内氧化·
The oxidation kinetics and the oxidation layer of a cast Nibase superalloy K35 at 800?℃ were studied by still TGA method. The results show that oxidation kinetics of the superalloy K35 obeys the parabolic law. The oxidation stage can be divided into two parts within 100?h:the oxidation rate are 250×10-7?mg2/cm4·s in first stage and 205?×10-7?mg2/cm4·s in the other stage. Because the average oxidation velocity is 000263?mg/cm2·h for 100?h, the oxidation resistance of the superalloy K35 is the first grade. It is suggested that oxidation rate of the superalloy K35 is dependent on the growth dynamics of Cr2O3. The oxide layer was examided by Xray diffraction, scanning electron microscopy (SEM) and energy spectrum analysis (ESA). The layer is thin and consists of Cr2O3 mainly with a bit of NiCr2O4 and TiO·TiO2. During oxidation at 800?℃,the inner oxidation occures in the superalloy.
出处
《东北大学学报（自然科学版）》
EI
CAS
CSCD
北大核心
2003年第1期75-78,共4页
Journal of Northeastern University(Natural Science)
基金
国家自然科学基金资助项目(59895152).
