摘要
目的降低原油成本及汽、柴油产量,以适应炼化行业的快速发展和能源产业结构调整造成的汽、柴油市场萎缩和炼化行业产能过剩局面。方法以巴士拉重质原油为原料,增加直馏工艺间歇式生产沥青的流程,通过调整原油、半成品及成品物料的库存数量保证蒸馏-渣油加氢-催化和蒸馏-焦化工艺的连续平稳运行。结果将质量分数为20%的巴士拉重质原油与其他劣质原油掺混后,采用直馏工艺生产出合格的AH-70(A)牌号沥青。试炼期间还掺炼了铁质量分数达到155μg/g的二次稀释原油罐底油,掺炼质量分数为24%。通过控制常压渣油外甩量,渣油加氢原料中(镍+钒)质量分数仅为71.9μg/g。结论以巴士拉重质原油为原料,通过直馏工艺可生产出性能良好的沥青产品,加工的主要难点是渣油收率高和重金属含量高。对于单套规模较大的蒸馏装置,可采取间歇性掺炼的加工方法,通过控制常压渣油外甩量的方式,降低对渣油加氢催化剂的影响。
Objective The aim is to reduce the cost of crude oil and gasoline and diesel production,in order to adapt to the rapid development of the refining industry and the shrinking of the gasoline and diesel market and the overcapacity of the refining industry caused by the adjustment of the energy industry structure.Methods Using the Basra heavy crude oil as raw material,the process of intermittent production of asphalt by straight distillation process was added.By adjusting the inventory of crude oil,semi-finished products,and finished products,the continuous and stable operation of the distillation-residual oil hydrogenation-catalysis and distillationcoking processes was ensured.Results After blending 20 wt%Basra heavy crude oil with other inferior crude oil,qualified AH-70(A)grade asphalt was produced by straight distillation process.During the trial refining,the secondary dilution tank bottom crude oil with an iron mass fraction of 155μg/g was blended,and the blending mass fraction was 24%.The mass fraction of nickel and vanadium in the residue hydrogenation raw material was only 71.9μg/g while controlling the atmospheric residue discharge.Conclusions Using Basra heavy crude oil as raw material,asphalt products with good performance can be produced by straight distillation process.The main difficulties in processing are high residue oil yield and high heavy metal content.For a single set of large-scale distillation unit,the processing method of intermittent blending can be adopted,and the influence on residue oil hydrogenation catalyst can be reduced by controlling the atmospheric residue discharge.
作者
张洪
魏文平
胡锦原
杨志和
ZHANG Hong;WEI Wenping;HU Jinyuan;YANG Zhihe(PetroChina Yunnan Petrochemical Co.,Ltd.,Kunming,Yunnan,China)
出处
《石油与天然气化工》
CAS
CSCD
北大核心
2024年第6期20-27,共8页
Chemical engineering of oil & gas
基金
中石油天然气股份有限公司D级研发项目“劣质重油选购、常温运输时序控制、调合及加工研究”(F-8822C01D)。
关键词
巴士拉重质原油
减压渣油
沥青
原油罐底油
铁含量
氯含量
Basra heavy crude oil
vacuum residue
asphalt
bottom oil of crude oil tank
iron content
chlorine content
