摘要
近年来,在全球面临的资源紧缺的背景下,机械酶催化反应凭借其高效、绿色、节能、可持续的特点引起了学术界和食品行业的高度关注。有机合成反应通常使用大量化学试剂,且需要严格的反应条件和复杂的下游操作来分离纯化产品,食品中应少用或不用。机械酶学技术能够在无溶剂的体系下,通过机械能促进酶催化反应,符合当今发展的需求及理念。该文主要对机械酶学的起源、发展、影响因素、反应机理、酶的种类和应用展开综述,通过汇集已报道的实例,以期为食品化学和生物催化领域提供理论指导。
In recent years,in the context of global resource shortage,mechanoenzymatic reactions have attracted great attention from both academia and the food industry due to their efficient,green,energy-saving and sustainable characteristics.Organic synthesis reactions typically use a large amount of chemical reagents and require strict reaction conditions and complex downstream operations to separate and purify products,which should be used sparingly or not at all in foods.Mechanoenzymology,i.e.,the use of mechanical energy to promote enzyme-catalyzed reactions in a solvent-free system,is in line with the current development needs and concepts.This paper reviews the origin,development,influencing factors and mechanism of mechanoenzymology and the applications of different enzymes in mechanoenzymology in order to provide theoretical guidance for the field of food chemistry and biocatalysis.
作者
崔添玉
辛嘉英
孙立瑞
李越
刘静雪
张健雄
夏春谷
CUI Tianyu;XIN Jiaying;SUN Lirui;LI Yue;LIU Jingxue;ZHANG Jianxiong;XIA Chungu(Heilongjiang Key Laboratory of Food Science and Engineering,Harbin University of Commerce,Harbin 150028,China;State Key Laboratory for Oxo Synthesis and Selective Oxidation,Lanzhou Institute of Chemical Physics,Chinese Academy of Sciences,Lanzhou 730000,China;College of Tourism and Culinary,Harbin University of Commerce,Harbin 150000,China)
出处
《食品科学》
EI
CAS
CSCD
北大核心
2024年第23期321-328,共8页
Food Science
基金
中央支持地方高校改革发展资金人才培养项目(高水平人才)(304017)
黑龙江省自然科学基金项目(LH2020C063)
哈尔滨商业大学研究生创新科研项目(YJSCX2024-811HSD)。
关键词
机械酶催化反应
无溶剂体系
固体反应
绿色化学
酶应用
mechanoenzymatic reactions
solvent-free systems
solid-state reactions
green chemistry
enzyme applications
