摘要
本工作以中国近现代古法制作墨锭为研究对象,采用元素分析、X-射线荧光光谱分析(XRF)、热重分析(TGA)、透射电子显微镜分析(TEM)、动态光散射分析(DLS)及接触角测试等多种表征方法,分别对墨块本体及其表面描金部分的元素组成,墨锭的烟、胶以及其他添加剂的成分配比,墨颗粒微观形貌及单分散尺寸,墨颗粒聚集状态及尺寸,墨锭表面的亲疏水性等进行了测定,系统研究了几种不同工艺的传统中国墨锭的性质、性能特点。结果表明,不同墨锭在元素组成、成分配比以及微观尺寸、墨颗粒聚集状态、表面亲疏水性上存在一定的规律性。对墨锭物理化学性质的科学检测与分析,可以为中国传统墨锭的科学检测基础数据库提供数据支持,而通过对其具体关联与差异的研究,还可与制墨工艺、墨的品质相关联,为墨的使用、保存和鉴别提供科学依据,为墨的写印效果研究提供参考。
Neoteric and modern Chinese traditional ink-sticks were used as the research objects in our work.The main body and the gold-decorated part of the ink-sticks were characterized using various methods including elemental analysis,X-ray fluorescence(XRF)spectrometry,thermogravimetric analysis(TGA),transmission electron microscopy(TEM),dynamic light scattering(DLS)analysis and static contact angle testing.The properties and performance characteristics of these traditional ink-sticks were systematically studied in terms of elemental composition,component ratio of soot,glue and other additives,microscopic morphology and monodisperse size of ink particles,aggregation state and size of ink particles,hydrophilicity and hydrophobicity of ink-stick surfaces.The results demonstrate that different ink-sticks had certain regularity in elemental composition,composition ratio,microscopic size,aggregation and dispersion state of ink particles,and surface hydrophilicity and hydrophobicity.The basic testing and analysis of physical-chemical properties of ink-sticks could provide data support for the scientific database of Chinese traditional ink-sticks.Moreover,the research on the specific correlation and differences could be related to the ink-making process and ink quality,providing not only a scientific basis for the use,preservation and identification of ink,but also a reference for the writing effect of ink.
作者
高自港
吴春芳
朱子锐
王毅
刘鹏
张宏斌
GAO Zigang;WU Chunfang;ZHU Zirui;WANG Yi;LIU Peng;ZHANG Hongbin(Institute for Preservation and Conservation of Chinese Ancient Books,Fudan University Library,Fudan University,Shanghai 200433,China)
出处
《文物保护与考古科学》
北大核心
2024年第4期57-64,共8页
Sciences of Conservation and Archaeology
基金
国家自然科学基金面上项目(22175040)资助
教育部人文社会科学研究青年基金项目(21YJCZH089)资助
上海市自然科学基金项目(21ZR1405100)资助。
关键词
传统墨锭
科学检测
成分组成
颗粒状态
烟和胶
Traditional ink-stick
Scientific testing
Composition
Particle state
Soot and glue
