摘要
目的归纳分析不同类型固体酸制备缩醛化合物的方法,旨在为绿色合成工艺在包装材料领域的广泛应用提供参考。方法通过梳理催化合成缩醛化合物的固体酸种类,对比分析不同催化剂的合成机理及其利弊,包括负载型杂多酸、金属氧化物、SO_(4)^(2−)/M_(x)O_(y)固体超强酸和负载型离子液体等,总结近年来国内外关于缩醛化合物在包装材料领域应用研究的趋势。结论大量相关文献证明了利用缩醛化合物制备包装材料的可行性,采用固体酸制备缩醛的方法符合绿色可持续发展理念,为缩醛绿色化和可控制备工艺开辟了新途径,有力推动了缩醛衍生产品在包装材料领域的大规模应用。
The work aims to collate and analyze the preparation of aldehyde compounds with various types of solid acids,so as to provide a reference basis for their green synthesis processes and extensive applications in the field of packaging materials.The types of solid acids used in the catalytic synthesis of aldehyde compounds were sorted out and the synthesis mechanisms and pros and cons of different catalysts were analyzed comparatively,including supported heteropoly acids,metal oxides,SO_(4)^(2−)/M_(x)O_(y) super-strong solid acids,and supported ionic liquids.The recent trends in the research and development of aldehyde compounds in the field of packaging materials in China and abroad were summarized.Loss of relevant literature confirms the feasibility of using aldehyde compounds to prepare packaging materials,and the method of synthesizing aldehydes using solid acids aligns with the principles of green and sustainable development.This opens up new pathways for the green and controllable preparation process of aldehydes,thereby significantly advancing the large-scale application of aldehyde derivative products in packaging materials.
作者
徐仁奎
赵文豪
任亚平
黄能坤
谈继淮
朱新宝
XU Renkui;ZHAO Wenhao;REN Yaping;HUANG Nengkun;TAN Jihuai;ZHU Xinbao(College of Chemical Engineering,Nanjing Forestry University,Nanjing 210037,China)
出处
《包装工程》
CAS
北大核心
2024年第11期44-54,共11页
Packaging Engineering
关键词
缩醛
合成工艺
固体酸催化剂
包装材料
aldehyde
synthesis technology
heterogeneous catalyst
packaging material
