摘要
与三维沸石相比,二维层状沸石具有更大的表面积、更短的扩散距离和更具韧性的结构,在许多领域中都具有更大优势。近年来,二维层状沸石的研究已成为新热点。本文基于前期文献调研总结,从两类合成角度(Bottom-up和Top-down法)归纳了近年来二维沸石的合成方法,重点综述了同种类型沸石的不同合成法的进展。此外,本文简述了二维沸石在催化、吸附和分离领域中的应用,并展望了二维沸石广阔的应用前景,以期为二维沸石的合成与应用提供参考。
Compared with three-dimensional zeolites,two-dimensional layered zeolites have greater advantages in many fields,with larger surface area,shorter diffusion distance and more ductile structure.In recent years,the research on two-dimensional layered zeolites has become a new hotspot.Based on previous research and summary,this article summarizes the synthesis methods of two-dimensional zeolites in the past five years from two types of synthesis perspectives(bottom-up and top-down methods),with a focus on reviewing the progress of different synthesis methods for the same topology of zeolite.In addition,this article briefly describes the applications of two-dimensional zeolites in the fields of catalysis,adsorption,and separation and looks forward to the broad application prospects of two-dimensional zeolites so as to provide theoretical guidance and reference basis for the synthesis and application of two-dimensional zeolites.
作者
胡诗雨
闫玥儿
张亚红
王振东
唐颐
Shiyu Hu;Yueer Yan;Yahong Zhang;Zhendong Wang;Yi Tang(Department of Chemistry,Fudan University,Shanghai 200438,China;Institute for Preservation and Conservation of Chinese Ancient Books,Fudan University,Shanghai 200433,China;State Key Laboratory of Green Chemical Engineering and Industrial Catalysis,SINOPEC Shanghai Research Institute of Petrochemical Technology Co.,Ltd.,Shanghai 201208)
出处
《化学进展》
SCIE
CAS
CSCD
北大核心
2024年第3期319-334,共16页
Progress in Chemistry
基金
国家重点研发计划(No.2018YFA0209402)
国家自然科学基金(No.22072028,22088101)
上海市自然科学基金(No.22ZR1407200)资助。
关键词
二维沸石
合成
酸催化
吸附
分离膜
2D zeolite
synthesis
acid catalysis
adsorption
separation membrane
