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光响应型微乳液的研究进展

Research Progress of Photo-Responsive Microemulsions
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摘要 微乳液是由水、油和表面活性剂(通常会添加助表面活性剂)组成的热力学稳定且各向同性的透明分散体系。粒径小且热力学稳定的微乳液在包括油回收、化妆品和药物配方、纳米粒子合成和化学反应媒介等领域的广泛应用引起了研究者们的兴趣。光刺激响应型微乳液是指在紫外光/可见光触发下性能和相行为发生变化的一类智能型微乳液。光刺激具有响应方式简单,可快速切换且能够实现相行为的远程和精准调控等优点,在刺激响应型微乳液中具有独特的优势。以光刺激响应型官能化合物为主线,对其参与构筑的微乳体系的光响应相行为和结构性质进行综述,分析了该领域研究中存在的主要问题,并对其发展方向进行展望。 Microemulsions are thermodynamically stable and isotropic transparent dispersion systems composed of water,oil,and surfactants(usually with the addition of co-surfactants).Microemulsions with small particle size and thermodynamic stability have a wide application in the fields of oil recovery,cosmetics and pharmaceutical formulations,nanoparticle synthesis and chemical reaction media and so on,which has attracted the interests of researchers.Photo-responsive microemulsions refers to a kind of intelligent microemulsion of whose properties and phase behavior can be changed under the trigger of UV/visible light.Light stimulation offers the advantages of simple response,fast switching,and the ability to achieve remote and precise control of phase behavior,which provides unique benefits in stimulation-responsive microemulsions.In this paper,the photo-responsive functional compounds were utilized as the main line to review the light-responsive phase behavior and structural properties of the microemulsion systems in which they were involved.In addition,this paper analyzed the primary issues within this field and provided insights into potential development directions.
作者 安鹏云 周越 张永民 AN Pengyun;ZHOU Yue;ZHANG Yongmin(School of Chemistry and Material Engineering,Jiangnan University,Wuxi 214122,Jiangsu China;Shanghai Carbon Yuan new material Co.,LTD,Shanghai,201508)
出处 《中国洗涤用品工业》 CAS 2024年第4期43-53,共11页 China Cleaning Industry
关键词 光响应 微乳液 光致异构 性能调控 photo-responsive microemulsions photo isomerization performance modulation
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