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原位自生相增强Ti-Zr-Cu-Pd-Mo非晶复合材料的制备及其力学性能

Synthesis and Mechanical Properties of Ti-Zr-Cu-Pd-Mo Amorphous Alloy Based Composites with In-situ Autogenous β-Ti Phase
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摘要 在Ti_(40)Zr_(10)Cu_(36)Pd_(14)非晶合金基体中微添加β-Ti相稳定化元素Mo,使体系在凝固过程中原位析出塑性β-Ti相,制备出原位自生β-Ti相增强Ti基非晶复合材料。在这种复合材料的变形过程中塑性β-Ti相阻碍基体中主剪切带的扩展,使其发生偏转和增殖生成多重剪切带,使其室温力学性能显著提高。其中(Ti_(0.4)Zr_(0.1)Cu_(0.36)Pd_(0.14))_(95)Mo_(5)试样的室温强度达到2630 MPa,塑性应变达到7.3%,比基体分别提高了32.0%和508%。 Ti-based amorphous alloys possess excellent properties such as low density,good biocompatibility and high corrosion resistance,which makes them one kind of promising materials used as biomedical materials.However,the room-temperature brittleness of Ti-based amorphous alloys limits their application.In order to improve the room-temperature plasticity of Ti-based amorphous alloys,the present study,a small amount of Mo(a β-Ti stabilizing element)is added to the Ti_(40)Zr_(10)Cu_(36)Pd_(14) amorphous alloy so that the plastic β-Ti phase particles may be precipitated in-situ within the alloy during the solidification process.It is expected that in the subsequent deformation process,the plastic β-Ti phase can effectively impede the rapid propagation of the main shear band in the matrix,causing deflects,branching or multiplication of it.The multiple shear bands significantly improved the room-temperature mechanical properties.Finally,the optimal room-temperature mechanical properties were obtained for the amorphous alloy(Ti_(0.4)Zr_(0.1)Cu_(0.36)Pd_(0.14))_(95)Mo_(5) which showed the fracture strength of 2630 MPa and plastic strain of 7.3%,namely 32.0% and 508% higher than that of the base alloy,respectively.
作者 余圣 郭威 吕书林 吴树森 YU Sheng;GUO Wei;LV Shulin;WU Shusen(State Key Laboratory of Material Processing and Die&Mould Technology,School of Materials Science and Engineering,Huazhong University of Science and Technology,Wuhan 430074,China;Research Institute of Huazhong University of Science and Technology in Shenzhen,Shenzhen 518057,China;State Key Laboratory for Mechanical Behavior of Materials,Xi'an Jiaotong University,Xi'an 710049,China)
出处 《材料研究学报》 EI CAS CSCD 北大核心 2024年第2期105-110,共6页 Chinese Journal of Materials Research
基金 国家自然科学基金(52101138) 深圳市科技计划(JCYJ20220530160813032) 新金属材料国家重点实验室开放基金(2020-Z01) 金属材料强度国家重点实验室开放基金(20202205) 广东省基础与应用基础研究基金(2020A1515110531)。
关键词 金属材料 非晶复合材料 室温塑性 剪切带 metallic materials amorphous alloy matrix composites room-temperature plasticity shear band
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