摘要
本文综述了丙烯腈和脂肪族胺、芳香胺、α-β不饱和化合物的亲核加成反应研究进展及其机理,总结了胺化工艺的规律,对比了几种催化剂对胺化反应的影响。对此类胺化反应进行了展望。
Research progress and mechanism of nucleophilic addition of acrylonitrile with aliphatic amines,with aromatic amines and with α-β unsaturated compounds were reviewed.Process of amination reaction aminated by acrylonitrile were summarized.Effects of some catalysts on amination reaction were compared.Prospects of the amination reaction were looked forward.
作者
俞鸿博
孙文瑄
魏微
鄢冬茂
李书龙
何威葳
孙成明
于海
宁绍宇
YU Hongbo;SUN Wenxuan;WEI Wei;YAN Dongmao;LI Shulong;HE Weiwei;SUN Chengming;YU Hai;NING Shaoyu(Shenyang Research Institute of Chemical Industry Co.,Ltd.,Shenyang 110021,Liaoning China;Luxi Chemical Group Co.,Ltd.,Liaocheng 252211,Shandong China;Sinochem(Shenyang)Advanced Materials Technology Co.Ltd.,Shenyang 110037,Liaoning China;Chonfar Engineering and Technology Co.,Ltd.,Changsha 410083,Hunan China)
出处
《染料与染色》
CAS
2023年第6期24-30,共7页
Dyestuffs and Coloration
关键词
丙烯腈
胺化反应
亲核加成
acrylonitrile
amination reaction
nucleophilic addition
