摘要
Ultra-narrow-band phosphors have gained widespread applications in lighting and displays to enhance brightness and improve color saturation.Typical phosphor designs employ UCr_(4)C_(4)-type compounds and designing new narrow-band phosphors with high color purity is a major challenge.Here,we explored a Eu^(2+)-doped Ba_(5)GeO_(4)Br_(6)phosphor,showing a narrow-band blue emission(λ_(em)=436 nm) excitation at the near-ultraviolet light with a full width at half maximum of 30.7 nm and high color purity of 96.6%.In addition,attractive cathodoluminescence characteristics were systematically analyzed by varying filament current(30-70 mA) and accelerating voltage(3-7 eV).Robust anti-degradation behavior and color point stability under continuous electron beam bombardment were confirmed.Given its excellent performance in photoluminescence and cathodoluminescence,application in wide color gamut displays appears promising.Using commercial phosphors β-SiAlON:Eu^(2+)and K_(2)SiF6:Mn^(4+)as green and red light co nverte rs respectively,and the title phosphor as the blue light converters,the fabricated w-LED exhibits a wide color gamut of 82% NTSC.
基金
Project supported by the Natural Science Foundation of Shaanxi Provincial Department of Education,China (21JK0708)
the Key Laboratory for Special Function Materials and Structure Design of the Ministry of the Education of Lanzhou University,China (lzujbky-2021-kb06)。
