摘要
Adding alloying elements is always considered as an effective method to enhance the resistance against hydrogen embrittlement in steels.Nb and V were added into 22MnB5 hot stamping steel,and then their influences on hydrogen permeation of 22MnB5 steel suffering from corrosion in 3.5%NaCl aqueous solution were investigated.The results showed that the addition of Nb/V could reduce the hydrogen permeation content due to solution corrosion.Electrochemical techniques including electrochemical impedance spectroscopy and overpotential stepping hydrogen permeation test con-firmed that compared to the original 22MnB5 steel,22MnB5-NbN steel owned a higher corrosion resistance and a higher hydrogen diffusion resistance.Furthermore,it was confirmed that Nb-V-alloyed 22MnB5 steel showed higher resistance against hydrogen embrittlement than the Nb-V-free counterpart,which should be related to the presentence of nanoscaled Nb/V-containing precipitates as the irreversible trapping sites for hydrogen detected by thermal desorption spectroscopy.Finally,the lattice diffusion coefficient of hydrogen DL was determined in steels with and without Nb and V.
基金
The authors are grateful to the financial support of the National Key R&D Program of China(No.2021YFB3702401)
National Natural Science Foundation of China(U1937601).
