摘要
Ni-rich layered cathodes have become the promising candidates for the next-generation high-energy Liion batteries due to their high energy density and competitive cost.However,they suffer from rapidcapacity fading due to the structural and interfacial instability upon long-term operation.Herein,the Tidoped and LiYO2-coated Ni-rich layered cathode has been synthesized via a facile one-step sinteringstrategy,which significantly restrains the interfacial parasitic side reactions and enhances the structuralstability.Specifically,the trace Ti^(4+)doping greatly stabilizes the lattice oxygen and alleviates the Li/Nidisorder while the LiYO_(2) coating layer can prevent the erosion of the cathode by the electrolyte duringcycles.As a result,the Ti-NCM83@LYO delivers a high specific capacity of 135 mAh g^(-1) even at 10C andthere is almost no capacity loss at 1C for 100 cycles.This work provides a simple one-step dual-modification strategy to meet the commercial requirements of Ni-rich cathodes.
基金
This work was supported by the National Natural ScienceFoundation of China(grant No.21975074)
the Innovation Programof Shanghai Municipal Education Commission,and the Fundamental Research Funds for the Central Universities.
